![EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM](https://www.bartleby.com/isbn_cover_images/9781259298424/9781259298424_largeCoverImage.gif)
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
3rd Edition
ISBN: 9781259298424
Author: SMITH
Publisher: VST
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 18.7, Problem 18.21P
Interpretation Introduction
Interpretation:
The reason should be explained for no similar reaction of quaternary ammonium salt like Bitex with NaOH as that of Benadryl with NaOH which forms free amine, diphenhydramine.
Concept Introduction:
Some
Expert Solution & Answer
![Check Mark](/static/check-mark.png)
Want to see the full answer?
Check out a sample textbook solution![Blurred answer](/static/blurred-answer.jpg)
Students have asked these similar questions
When reacting an acid halide with amines, it is necessary to use at least two moles of the amine because:
A) Acid halides are so unreactive that two moles of the attacking nucleophile are needed
B) Using one mole of the amine leads to a neutralization reaction between the two reactants
C) Excess amine is needed to react with the hydrohalic acid produced
D) The second mole of amine is needed for deprotonation.
Why is methylamine more basic than aniline?
Which chloramine out of monochloramine, dichloramine and trichloramine is the strongest oxidant. Please explain why?
Chapter 18 Solutions
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
Ch. 18.1 - Prob. 18.1PCh. 18.1 - Prob. 18.2PCh. 18.1 - Prob. 18.3PCh. 18.1 - Prob. 18.4PCh. 18.2 - Prob. 18.5PCh. 18.2 - Prob. 18.6PCh. 18.2 - Prob. 18.7PCh. 18.3 - Prob. 18.8PCh. 18.4 - Decaffeinated coffee is produced by extracting the...Ch. 18.4 - Prob. 18.10P
Ch. 18.5 - Prob. 18.11PCh. 18.5 - Prob. 18.12PCh. 18.5 - Prob. 18.13PCh. 18.6 - Prob. 18.14PCh. 18.6 - Prob. 18.15PCh. 18.6 - Prob. 18.16PCh. 18.6 - Name each ammonium salt. a. ( CH3 NH3)+Cl b. [( CH...Ch. 18.6 - Prob. 18.18PCh. 18.6 - Prob. 18.19PCh. 18.7 - Prob. 18.20PCh. 18.7 - Prob. 18.21PCh. 18.8 - Prob. 18.22PCh. 18.8 - Prob. 18.23PCh. 18.8 - Prob. 18.24PCh. 18.9 - Prob. 18.25PCh. 18.9 - Prob. 18.26PCh. 18.9 - Prob. 18.27PCh. 18.10 - Prob. 18.28PCh. 18 - Prob. 18.29PCh. 18 - Prob. 18.30PCh. 18 - Prob. 18.31PCh. 18 - Prob. 18.32PCh. 18 - Prob. 18.33PCh. 18 - Prob. 18.34PCh. 18 - Prob. 18.35PCh. 18 - Prob. 18.36PCh. 18 - Prob. 18.37PCh. 18 - Prob. 18.38PCh. 18 - Give an acceptable name for each amine. a. b.Ch. 18 - Give an acceptable name for each amine. a. b.Ch. 18 - Give an acceptable name for each amine. a. b. c....Ch. 18 - Give an acceptable name for each amine. a. CH3(...Ch. 18 - Prob. 18.43PCh. 18 - Prob. 18.44PCh. 18 - Prob. 18.45PCh. 18 - Prob. 18.46PCh. 18 - Prob. 18.47PCh. 18 - Prob. 18.48PCh. 18 - Prob. 18.49PCh. 18 - Prob. 18.50PCh. 18 - Which compound in each pair has the higher boiling...Ch. 18 - Which compound in each pair has the higher boiling...Ch. 18 - Draw the hydrogen-bonding interactions that occur...Ch. 18 - Prob. 18.54PCh. 18 - Prob. 18.55PCh. 18 - Which compound has the higher water solubility:...Ch. 18 - Prob. 18.57PCh. 18 - Prob. 18.58PCh. 18 - Draw the products of each acid-base reaction. a....Ch. 18 - Draw the products of each acid-base reaction. a....Ch. 18 - Prob. 18.61PCh. 18 - Prob. 18.62PCh. 18 - What type of nitrogen heterocycle occurs in both...Ch. 18 - Only one of the N atoms in nicotine has a trigonal...Ch. 18 - Prob. 18.65PCh. 18 - Prob. 18.66PCh. 18 - Why are aqueous solutions of an alkaloid slightly...Ch. 18 - Prob. 18.68PCh. 18 - Prob. 18.69PCh. 18 - Explain why patients with Parkinson’s disease...Ch. 18 - Prob. 18.71PCh. 18 - Prob. 18.72PCh. 18 - Prob. 18.73PCh. 18 - Prob. 18.74PCh. 18 - Prob. 18.75PCh. 18 - Prob. 18.76PCh. 18 - Prob. 18.77PCh. 18 - Prob. 18.78PCh. 18 - Prob. 18.79PCh. 18 - Prob. 18.80PCh. 18 - Prob. 18.81PCh. 18 - Prob. 18.82PCh. 18 - Prob. 18.83PCh. 18 - Prob. 18.84PCh. 18 - Prob. 18.85PCh. 18 - Prob. 18.86PCh. 18 - Prob. 18.87PCh. 18 - Why do some antihistamines cause drowsiness while...Ch. 18 - Prob. 18.89PCh. 18 - Prob. 18.90PCh. 18 - Compare the structures of morphine and heroin....Ch. 18 - Prob. 18.92CP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Reductive amination of carbonyl compounds produces the same kinds of products as does the reaction of amines and alkyl halides True or Falsearrow_forwardWhy is the water solubility of a carboxylate salt greater than that of its parent carboxylic acid? A) A carboxylate salt is an ionic compound which is soluble in water. B) A carboxylate salt is less polar than its parent carboxylic acid. C) A carboxylate salt has a lower boiling point than its parent carboxylic acid. D) A carboxylate salt is more readily reduced to an aldehyde than its parent carboxylic acid.arrow_forwardExplain the effect of acid on the solubility of the water-insoluble amines.arrow_forward
- How acid chlorides, anhydrides, esters, and amides are prepared ?arrow_forwardThe hydrolysis of an amide in acidic conditions forms A. a carboxylate salt and an alcohol B. a carboxylate salt and an amine C. an alcohol and an amine salt (an ammonium ion) D. a carboxylic acid and an amine salt (an ammonium ion)arrow_forwardChapter 1 (Carbonyl compounds I) Explain how the class I carbonyl compound reacts? What will be the product when ethylamine and propyl amine reacts with acetyl chloride? Why only one amide obtained after the reaction of acetyl chloride with a mixture of ethylamine and trimethylamine? Excess amine is required in the reaction of acetyl chloride with amine whereas excess alcohol is not required in the reaction of acetyl chloride and alcohol. Why? List the following ester in order of decreasing reactivities towards hydrolysis with reason: Methyl benzoate, p-nitro methyl benzoate and p-methoxy methyl benzoate The reaction of an ester with an amine is not as slow as the reaction of an ester with water or an alcohol. Explain with reason. Explain why the rate of aminolysis of an ester cannot be increased by H+, OH- or OR-. How can you activate the carboxylic acid? Is acid catalyzed hydrolysis of acetamide a reversible or an irreversible reaction. Explain. Chapter 2 (Carbonyl compounds II)…arrow_forward
- Draw a scheme separating an amine of p-bromoaniline from p-dimethoxybenzenearrow_forwardWhy can formaldehyde (CH2O) be prepared in the form of a 37 solution in water, whereas decanal (C10H20O) cannot?arrow_forwardWrite the structure of benzylamine hydrochloride in two different ways, and name the hydrochloride as an ammonium salt.arrow_forward
- why is pentafluorophenyl ester more reactive (with primary amine) than ethyl ester?arrow_forwardDraw several molecules of methanamide and show the intermolecular hydrogen bonding that account for the amide’s very high boiling point.arrow_forwardN-Methylpyrrolidine has a boiling point of 81 °C, and piperidine has a boiling point of 106 °C. Tetrahydropyran has a boiling point of 88 °C, and cyclopentanone has a boiling point of 141 °C. These two isomershave a boiling point difference of 53 °C. Explain why the two oxygen-containing isomers have a much larger boilingpoint difference than the two amine isomersarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningChemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage LearningGeneral, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage LearningOrganic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305580350/9781305580350_smallCoverImage.gif)
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305960060/9781305960060_smallCoverImage.gif)
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
![Text book image](https://www.bartleby.com/isbn_cover_images/9781285199047/9781285199047_smallCoverImage.gif)
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
![Text book image](https://www.bartleby.com/isbn_cover_images/9780618974122/9780618974122_smallCoverImage.gif)
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning
![Text book image](https://www.bartleby.com/isbn_cover_images/9781285853918/9781285853918_smallCoverImage.gif)
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305081079/9781305081079_smallCoverImage.gif)
Organic And Biological Chemistry
Chemistry
ISBN:9781305081079
Author:STOKER, H. Stephen (howard Stephen)
Publisher:Cengage Learning,