The synthesis of N-butylpiperidine from piperidine by acylation-reduction is to be stated. Concept introduction: Piperidine is an organic compound. It contains nitrogen containing heterocyclic ring. N-butylpiperidine is a derivative of piperidine. Therefore, it is synthesised from piperidine compound.

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Answer 1

Question

Chapter 19.19, Problem 19.27P

(a)

Interpretation Introduction

Interpretation:

The synthesis of N-butylpiperidine from piperidine by acylation-reduction is to be stated.

Concept introduction:

Piperidine is an organic compound. It contains nitrogen containing heterocyclic ring. N-butylpiperidine is a derivative of piperidine. Therefore, it is synthesised from piperidine compound.

(b)

Interpretation Introduction

Interpretation:

The synthesis of N-benzylaniline from aniline by acylation-reduction is to be stated.

Concept introduction:

Aniline is an organic compound which is alkaline in nature. It contains an amino group attached to benzene ring. N-benzylaniline is a derivative of aniline. Therefore, it is synthesised from aniline compound.

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Show how to synthesize the following amines from the indicated starting materials byacylation–reduction. b) N-benzylaniline from aniline

Show how to synthesize the following amines from the indicated starting materials byacylation–reduction.(a) N-butylpiperidine from piperidine

Show how to prepare the following aromatic amines by aromatic nitration, followed by reduction. You may use benzene andtoluene as your aromatic starting materials. (c) m-bromoaniline (d) m-aminobenzoic acid

Answer 2

Question

Chapter 19.19, Problem 19.27P

(a)

Interpretation Introduction

Interpretation:

The synthesis of N-butylpiperidine from piperidine by acylation-reduction is to be stated.

Concept introduction:

Piperidine is an organic compound. It contains nitrogen containing heterocyclic ring. N-butylpiperidine is a derivative of piperidine. Therefore, it is synthesised from piperidine compound.

(b)

Interpretation Introduction

Interpretation:

The synthesis of N-benzylaniline from aniline by acylation-reduction is to be stated.

Concept introduction:

Aniline is an organic compound which is alkaline in nature. It contains an amino group attached to benzene ring. N-benzylaniline is a derivative of aniline. Therefore, it is synthesised from aniline compound.

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Answer 3

Question

Chapter 19.19, Problem 19.27P

(a)

Interpretation Introduction

Interpretation:

The synthesis of N-butylpiperidine from piperidine by acylation-reduction is to be stated.

Concept introduction:

Piperidine is an organic compound. It contains nitrogen containing heterocyclic ring. N-butylpiperidine is a derivative of piperidine. Therefore, it is synthesised from piperidine compound.

(b)

Interpretation Introduction

Interpretation:

The synthesis of N-benzylaniline from aniline by acylation-reduction is to be stated.

Concept introduction:

Aniline is an organic compound which is alkaline in nature. It contains an amino group attached to benzene ring. N-benzylaniline is a derivative of aniline. Therefore, it is synthesised from aniline compound.

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Answer 4

Question

Chapter 19.19, Problem 19.27P

(a)

Interpretation Introduction

Interpretation:

The synthesis of N-butylpiperidine from piperidine by acylation-reduction is to be stated.

Concept introduction:

Piperidine is an organic compound. It contains nitrogen containing heterocyclic ring. N-butylpiperidine is a derivative of piperidine. Therefore, it is synthesised from piperidine compound.

(b)

Interpretation Introduction

Interpretation:

The synthesis of N-benzylaniline from aniline by acylation-reduction is to be stated.

Concept introduction:

Aniline is an organic compound which is alkaline in nature. It contains an amino group attached to benzene ring. N-benzylaniline is a derivative of aniline. Therefore, it is synthesised from aniline compound.

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Answer 5

Chapter 19.19, Problem 19.27P

(a)

Interpretation Introduction

Interpretation:

The synthesis of N-butylpiperidine from piperidine by acylation-reduction is to be stated.

Concept introduction:

Piperidine is an organic compound. It contains nitrogen containing heterocyclic ring. N-butylpiperidine is a derivative of piperidine. Therefore, it is synthesised from piperidine compound.

(b)

Interpretation Introduction

Interpretation:

The synthesis of N-benzylaniline from aniline by acylation-reduction is to be stated.

Concept introduction:

Aniline is an organic compound which is alkaline in nature. It contains an amino group attached to benzene ring. N-benzylaniline is a derivative of aniline. Therefore, it is synthesised from aniline compound.

Answer 6

Chapter 19.19, Problem 19.27P

(a)

Interpretation Introduction

Interpretation:

The synthesis of N-butylpiperidine from piperidine by acylation-reduction is to be stated.

Concept introduction:

Piperidine is an organic compound. It contains nitrogen containing heterocyclic ring. N-butylpiperidine is a derivative of piperidine. Therefore, it is synthesised from piperidine compound.

Answer 7

Chapter 19.19, Problem 19.27P

(a)

Interpretation Introduction

Interpretation:

The synthesis of N-butylpiperidine from piperidine by acylation-reduction is to be stated.

Concept introduction:

Piperidine is an organic compound. It contains nitrogen containing heterocyclic ring. N-butylpiperidine is a derivative of piperidine. Therefore, it is synthesised from piperidine compound.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The synthesis of N-benzylaniline from aniline by acylation-reduction is to be stated.

Concept introduction:

Aniline is an organic compound which is alkaline in nature. It contains an amino group attached to benzene ring. N-benzylaniline is a derivative of aniline. Therefore, it is synthesised from aniline compound.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The synthesis of N-benzylaniline from aniline by acylation-reduction is to be stated.

Concept introduction:

Aniline is an organic compound which is alkaline in nature. It contains an amino group attached to benzene ring. N-benzylaniline is a derivative of aniline. Therefore, it is synthesised from aniline compound.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 19.2A - Prob. 19.1P Ch. 19.2B - Prob. 19.2P Ch. 19.2B - Give correct names for the following amines:Ch. 19.3 - Prob. 19.4P Ch. 19.4 - Prob. 19.5P Ch. 19.6 - Rank each set of compounds in order of increasing...Ch. 19.8A - Prob. 19.7P Ch. 19.8C - Prob. 19.8P Ch. 19.8C - Prob. 19.9P Ch. 19.8D - a. Show how fragmentation occurs to give the base...

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Chapter 19 Solutions