Chapter 2, Problem 2.54E

(a)

Interpretation Introduction

Interpretation:

Lewis structure of ${\text{N}}_{\text{2}}{\text{O}}_{\text{3}}$ has to be drawn.

Concept Introduction:

Lewis structures represent covalent bonds and describe valence electrons configuration of atoms. The covalent bonds are depicted by lines and unshared electron pairs by pairs of dots. The sequence to write Lewis structure of some molecule is given as follows:

• The central atom is identified and various other atoms are arranged around it. This central atom so chosen is often the least electronegative.
• Total valence electrons are estimated for each atom.
• single bond is first placed between each atom pair.
• The electrons left can be allocated as unshared electron pairs or as multiple bonds around the symbol of the element to satisfy the octet (or duplet) for each atom.
• Add charge on the overall structure in case of polyatomic cation or anion.

(a)

Interpretation Introduction

Interpretation:

Bond order of $\text{N}-\text{N}$ bond in ${\text{N}}_{\text{2}}{\text{O}}_{\text{3}}$ has to be given.

Concept Introduction:

Bond order is defined as number of bonds involved in certain overlap of atoms.

(c)

Interpretation Introduction

Interpretation:

The reason behind existence of ${\text{N}}_{\text{2}}{\text{O}}_{\text{3}}$ as unlike the analogous structure ${\text{P}}_4{\text{O}}_6$ has to be explained.

Concept Introduction:

Refer to part (a).