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Concept explainers
(a)
Interpretation:
The hemiacetal carbon of the given monosaccharide should be identified.
Concept introduction:
When an alcohol and ether group is attached to the same carbon, it is called the hemiacetal carbon.
(b)
Interpretation:
By identifying the unique features in the anomeric carbon, α or β nature should be decided.
Concept introduction:
Two anomers can be constructed as alpha (α) ** beta (β), depending on the configuration difference in the anomeric Carbon.
(c)
Interpretation:
By applying necessary amendments to the anomeric carbon of the given structure, β anomer should be derived.
Concept introduction:
In a cyclic simple sugar 2 anomers exists depending on the bond arrangement on anomeric carbon.
(d)
Interpretation:
A stereoisomer should be derived by making necessary changes to the C3position of the given monosaccharide.
Concept introduction:
When a carbon atom has 4 different entities bound to it, it is called as a stereocenter.
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Chapter 20 Solutions
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
- Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningOrganic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
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