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Concept explainers
(a)
Interpretation:
For the given monosaccharide, acetal/hemiacetal carbon, anomeric carbon &α or **beta; anomeric nature should be decided.
Concept introduction:
When an alcohol and ether group is attached to the same carbon, it is called the hemiacetal carbon. When 2 ether groups are attached to the same carbon, it is called as the acetal carbon.
Two anomers exist as alpha (α) ** beta (β), depending on the configuration differences in the anomeric carbon of a monosaccharide.
(b)
Interpretation:
For the given monosaccharide, acetal / hemiacetal carbon, anomeric carbon & α or **beta; anomeric nature should be decided.
Concept introduction:
When an alcohol and ether group is attached to the same carbon, it is called the hemiacetal carbon. When 2 ether groups are attached to the same carbon, it is called as the acetal carbon.
Two anomers exists as alpha (α) ** beta (β), depending on the configuration differences in the anomeric Carbon of a monosaccharide.
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Chapter 20 Solutions
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
- Organic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
- Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage LearningIntroduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage LearningOrganic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
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