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Concept explainers
(a)
Interpretation:
The cyclic form of monosaccharide given should be converted to an acyclic monosaccharide.
Concept Introduction:
When an
(b)
Interpretation:
The cyclic form of monosaccharide given should be converted to an acyclic monosaccharide.
Concept Introduction:
When an aldehyde or a ketone is reacted with one equivalent of alcohol, a hemiacetal is formed. The aldoses and ketoses contain both hydroxyl groups and aldehyde or ketone functional group. Therefore, aldoses and ketoses undergo intramolecular cyclization to form stable cyclic hemiacetals. The O atom on the chirality center farthest from the carbonyl is involved in the cyclization.
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Chapter 20 Solutions
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
- Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub CoGeneral, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage LearningOrganic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,
- Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
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