The order of given compounds in increasing rate of nucleophilic attack at C = O by a strong nucleophile is to be predicted. Concept introduction: The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will be its stability.

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Answer 1

Question

Chapter 21, Problem 21.59SP

(a)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will be its stability.

(b)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

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Rank the set of compounds in order of reactivity (fastest to slowest) in a nucleophilic addition-elimination reaction with a nucleophile such as CH3NH2.

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For each of the reactions indicate which reactant is the nucleophile and which is the electrophile.

Answer 2

Question

Chapter 21, Problem 21.59SP

(a)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will be its stability.

(b)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

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Answer 3

Question

Chapter 21, Problem 21.59SP

(a)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will be its stability.

(b)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

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Answer 4

Question

Chapter 21, Problem 21.59SP

(a)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will be its stability.

(b)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

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Answer 5

Chapter 21, Problem 21.59SP

(a)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will be its stability.

(b)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

Answer 6

Chapter 21, Problem 21.59SP

(a)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will be its stability.

Answer 7

Chapter 21, Problem 21.59SP

(a)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will be its stability.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

Answer 10

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Answer 13

Ch. 21.2F - Name the following carboxylic acid derivatives,...Ch. 21.4A - Prob. 21.2P Ch. 21.4A - Prob. 21.3P Ch. 21.4A - Prob. 21.4P Ch. 21.5C - Prob. 21.7P Ch. 21.6 - When ethyl 4-hydroxybutyrate is heated in the...Ch. 21.6 - Propose a mechanism for the following ring-opening...Ch. 21.6 - Prob. 21.15P Ch. 21.7B - Prob. 21.16P Ch. 21.7C - Prob. 21.19P

Solution Summary: The author explains that the rate of nucleophilic attack on compound is determined by the stability of the compound.

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