The accomplishment of given synthetic transformation is to be shown. Concept introduction: Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

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Answer 1

Question

Chapter 21.13, Problem 21.36P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

(d)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

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Upon completion of a chemical reaction, you find you have a mixture of benzoic acid and ethyl benzoate. Propose a procedure to separate the ethyl benzoate from the mixture. You should look up the structures of benzoic acid and ethyl benzoate.

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1.Write the name of different product formed when primary (aniline), secondary (N-methylaniline) and tertiary aromatic amine (N,N-dimethylaniline) reacts with nitrous acid (NaNO2 + HCl) Explain in brief what factor governs the formation of trisubstituted benzene from disubstituted benzene?

Answer 2

Question

Chapter 21.13, Problem 21.36P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

(d)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

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Answer 3

Question

Chapter 21.13, Problem 21.36P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

(d)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

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Answer 4

Question

Chapter 21.13, Problem 21.36P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

(d)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

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Answer 5

Chapter 21.13, Problem 21.36P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

(d)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

Answer 6

Chapter 21.13, Problem 21.36P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

Answer 7

Chapter 21.13, Problem 21.36P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The accomplishment of given synthetic transformation is to be shown.

Concept introduction:

Amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine. Amides are produced when esters react with amines and ammonia. It is also produced by the partial hydrolysis of nitriles.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 21.2F - Name the following carboxylic acid derivatives,...Ch. 21.4A - Prob. 21.2P Ch. 21.4A - Prob. 21.3P Ch. 21.4A - Prob. 21.4P Ch. 21.5C - Prob. 21.7P Ch. 21.6 - When ethyl 4-hydroxybutyrate is heated in the...Ch. 21.6 - Propose a mechanism for the following ring-opening...Ch. 21.6 - Prob. 21.15P Ch. 21.7B - Prob. 21.16P Ch. 21.7C - Prob. 21.19P

Solution Summary: The author explains that amides are the acid derivatives that are less reactive and are synthesized by the reaction of an acid chloride with an amine.

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Chapter 21 Solutions