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(a)
Interpretation: The
Concept introduction: The
(b)
Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.
Concept introduction: The
(c)
Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.
Concept introduction: The
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Chapter 21 Solutions
ORGANIC CHEMISTRY-ACCESS
- How would you convert cyclohexanone into each compound using any required inorganic reagents and needed organic compounds? a. b.arrow_forwardElectron inductive effect of alkyl groups decreases the acidity in: A. acetic acid B. benzoic acid C. hydrochloric acid D nitric acidarrow_forwardDraw a stepwise mechanism for the sulfonation of an alkyl benzene such as A to form asubstituted benzenesulfonic acid B. Treatment of B with base forms a sodium salt C that canbe used as a synthetic detergent to clean away dirt.arrow_forward
- Draw a stepwise mechanism for the sulfonation of an alkyl benzene such as A to form a substituted benzenesulfonic acid B. Treatment of B with base forms a sodium salt C that can be used as a synthetic detergent to clean away dirtarrow_forwardElectrophilic Addition Soubong neblA-aleid rose 9160910 31 babeen ene singo 14.43 Draw the products formed when each compound is treated with one equivalent of HBr. a. b. C.arrow_forwardProblem 25.14 What nitro compound, nitrile, and amide are reduced to each compound? a. CH,CHCH,NH, CH,NH, b. Problem 25.15 What amine is formed by reduction of each amide? CONH, b. "NHCH Problem 25.16 Explain why isopropylamine [(CH).CHNH] can be prepared by reduction of a nitro compound, but cannot be prepared by reduction of a nitrile, even though it is a 1* amine. Problem 25.17 Which amines cannot be prepared by reduction of an amide? NH O O Darrow_forward
- d) Explain why A is less reactive than B towards a nucleophilic attack. H. A Barrow_forwardDraw a stepwise mechanism for the attached reaction that forms ether D. D can be converted to the antidepressant fluoxetine (trade name Prozac) in a single steparrow_forwardLabel each compound as aromatic, antiaromatic, or not aromatic. Assume all completely conjugated rings are planar. Å a. b. C. d.arrow_forward
- Compound that is most easily hydrolyzed by acid in water `NH A. В. F C. D.arrow_forward2. How many different ß-hydroxyaldehydes and ß-hydroxyketones, including constitutional isomers and stereoisomers, are formed upon treatment of a mixture of acetone and benzaldehyde with base? a. b. 2 c. 3 d. 4arrow_forwardQ.3 Give reason: a. Enols are considered as strong nucleophiles as compared to alkenes. b. Aldol reaction is nucleophilic addition while Claisen is substitution. C. a-protons of carbonyl compounds are acidic.arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
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