Organic Chemistry: Principles and Mechanisms (Second Edition)
Organic Chemistry: Principles and Mechanisms (Second Edition)
2nd Edition
ISBN: 9780393663556
Author: Joel Karty
Publisher: W. W. Norton & Company
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Chapter 22, Problem 22.10YT
Interpretation Introduction

Interpretation:

The mechanism for the desulfonation in equation 22-28 is to be drawn.

Concept introduction:

Treating benzene with concentrated sulfuric acid yields benzenesulfonic acid, whereby a sulfo group, SO3H, has been incorporated onto the ring. This kind of substitution reaction is called sulfonation. SO3H+ is believed to be the electrophile involved in the electrophilic addition step of electrophilic aromatic substitution. The reverse of sulfonation reaction is called desulfonation.

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Organic Chemistry: Principles and Mechanisms (Second Edition)

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