(a) Interpretation: The product formed from the treatment of acetic acid with the given reagent is to be stated. Concept introduction: Carboxylic acids are strong organic acids. They undergo acid-base reaction with amines to yield an ammonium salt of carboxylate anion. It is a single step reaction.

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Answer 1

Question

Chapter 22, Problem 22.19P

Interpretation Introduction

(a)

Interpretation: The product formed from the treatment of acetic acid with the given reagent is to be stated.

Concept introduction: Carboxylic acids are strong organic acids. They undergo acid-base reaction with amines to yield an ammonium salt of carboxylate anion. It is a single step reaction.

Interpretation Introduction

(b)

Interpretation: The product formed from the treatment of acetic acid with the given reagent is to be stated.

Concept introduction: Carboxylic acids are strong organic acids. They undergo acid-base reaction with amines to yield an ammonium salt of carboxylate anion. Further heating at high temperature (greater than 100 °C) dehydrates the obtained ammonium salt to amide. Water is removed as the by-product.

Interpretation Introduction

(c)

Interpretation: The product formed from the treatment of acetic acid with the given reagent is to be stated.

Concept introduction: The full form of DCC is dicyclohexylcarbodiimide. It is a dehydrating agent. The treatment of carboxylic acid with an amine and DCC leads to the formation of an amide and dicyclohexylurea as the by-product, (formed when small amount of H2O is added).

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Answer 2

Question

Chapter 22, Problem 22.19P

Interpretation Introduction

(a)

Interpretation: The product formed from the treatment of acetic acid with the given reagent is to be stated.

Concept introduction: Carboxylic acids are strong organic acids. They undergo acid-base reaction with amines to yield an ammonium salt of carboxylate anion. It is a single step reaction.

Interpretation Introduction

(b)

Interpretation: The product formed from the treatment of acetic acid with the given reagent is to be stated.

Concept introduction: Carboxylic acids are strong organic acids. They undergo acid-base reaction with amines to yield an ammonium salt of carboxylate anion. Further heating at high temperature (greater than 100 °C) dehydrates the obtained ammonium salt to amide. Water is removed as the by-product.

Interpretation Introduction

(c)

Interpretation: The product formed from the treatment of acetic acid with the given reagent is to be stated.

Concept introduction: The full form of DCC is dicyclohexylcarbodiimide. It is a dehydrating agent. The treatment of carboxylic acid with an amine and DCC leads to the formation of an amide and dicyclohexylurea as the by-product, (formed when small amount of H2O is added).

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Answer 3

Question

Chapter 22, Problem 22.19P

Interpretation Introduction

(a)

Interpretation: The product formed from the treatment of acetic acid with the given reagent is to be stated.

Concept introduction: Carboxylic acids are strong organic acids. They undergo acid-base reaction with amines to yield an ammonium salt of carboxylate anion. It is a single step reaction.

Interpretation Introduction

(b)

Interpretation: The product formed from the treatment of acetic acid with the given reagent is to be stated.

Concept introduction: Carboxylic acids are strong organic acids. They undergo acid-base reaction with amines to yield an ammonium salt of carboxylate anion. Further heating at high temperature (greater than 100 °C) dehydrates the obtained ammonium salt to amide. Water is removed as the by-product.

Interpretation Introduction

(c)

Interpretation: The product formed from the treatment of acetic acid with the given reagent is to be stated.

Concept introduction: The full form of DCC is dicyclohexylcarbodiimide. It is a dehydrating agent. The treatment of carboxylic acid with an amine and DCC leads to the formation of an amide and dicyclohexylurea as the by-product, (formed when small amount of H2O is added).

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Answer 4

Question

Chapter 22, Problem 22.19P

Interpretation Introduction

(a)

Interpretation: The product formed from the treatment of acetic acid with the given reagent is to be stated.

Concept introduction: Carboxylic acids are strong organic acids. They undergo acid-base reaction with amines to yield an ammonium salt of carboxylate anion. It is a single step reaction.

Interpretation Introduction

(b)

Interpretation: The product formed from the treatment of acetic acid with the given reagent is to be stated.

Concept introduction: Carboxylic acids are strong organic acids. They undergo acid-base reaction with amines to yield an ammonium salt of carboxylate anion. Further heating at high temperature (greater than 100 °C) dehydrates the obtained ammonium salt to amide. Water is removed as the by-product.

Interpretation Introduction

(c)

Interpretation: The product formed from the treatment of acetic acid with the given reagent is to be stated.

Concept introduction: The full form of DCC is dicyclohexylcarbodiimide. It is a dehydrating agent. The treatment of carboxylic acid with an amine and DCC leads to the formation of an amide and dicyclohexylurea as the by-product, (formed when small amount of H2O is added).

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Answer 5

Chapter 22, Problem 22.19P

Interpretation Introduction

(a)

Interpretation: The product formed from the treatment of acetic acid with the given reagent is to be stated.

Concept introduction: Carboxylic acids are strong organic acids. They undergo acid-base reaction with amines to yield an ammonium salt of carboxylate anion. It is a single step reaction.

Interpretation Introduction

(b)

Interpretation: The product formed from the treatment of acetic acid with the given reagent is to be stated.

Concept introduction: Carboxylic acids are strong organic acids. They undergo acid-base reaction with amines to yield an ammonium salt of carboxylate anion. Further heating at high temperature (greater than 100 °C) dehydrates the obtained ammonium salt to amide. Water is removed as the by-product.

Interpretation Introduction

(c)

Interpretation: The product formed from the treatment of acetic acid with the given reagent is to be stated.

Concept introduction: The full form of DCC is dicyclohexylcarbodiimide. It is a dehydrating agent. The treatment of carboxylic acid with an amine and DCC leads to the formation of an amide and dicyclohexylurea as the by-product, (formed when small amount of H2O is added).

Answer 6

Chapter 22, Problem 22.19P

Interpretation Introduction

(a)

Interpretation: The product formed from the treatment of acetic acid with the given reagent is to be stated.

Concept introduction: Carboxylic acids are strong organic acids. They undergo acid-base reaction with amines to yield an ammonium salt of carboxylate anion. It is a single step reaction.

Answer 7

Chapter 22, Problem 22.19P

Interpretation Introduction

(a)

Interpretation: The product formed from the treatment of acetic acid with the given reagent is to be stated.

Concept introduction: Carboxylic acids are strong organic acids. They undergo acid-base reaction with amines to yield an ammonium salt of carboxylate anion. It is a single step reaction.

Answer 8

Interpretation Introduction

(b)

Interpretation: The product formed from the treatment of acetic acid with the given reagent is to be stated.

Concept introduction: Carboxylic acids are strong organic acids. They undergo acid-base reaction with amines to yield an ammonium salt of carboxylate anion. Further heating at high temperature (greater than 100 °C) dehydrates the obtained ammonium salt to amide. Water is removed as the by-product.

Answer 9

Interpretation Introduction

(b)

Interpretation: The product formed from the treatment of acetic acid with the given reagent is to be stated.

Concept introduction: Carboxylic acids are strong organic acids. They undergo acid-base reaction with amines to yield an ammonium salt of carboxylate anion. Further heating at high temperature (greater than 100 °C) dehydrates the obtained ammonium salt to amide. Water is removed as the by-product.

Answer 10

Interpretation Introduction

(c)

Interpretation: The product formed from the treatment of acetic acid with the given reagent is to be stated.

Concept introduction: The full form of DCC is dicyclohexylcarbodiimide. It is a dehydrating agent. The treatment of carboxylic acid with an amine and DCC leads to the formation of an amide and dicyclohexylurea as the by-product, (formed when small amount of H2O is added).

Answer 11

Interpretation Introduction

(c)

Interpretation: The product formed from the treatment of acetic acid with the given reagent is to be stated.

Concept introduction: The full form of DCC is dicyclohexylcarbodiimide. It is a dehydrating agent. The treatment of carboxylic acid with an amine and DCC leads to the formation of an amide and dicyclohexylurea as the by-product, (formed when small amount of H2O is added).

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 22 - Prob. 22.1P Ch. 22 - Draw the three possible resonance structures for...Ch. 22 - Prob. 22.3P Ch. 22 - Give an IUPAC or common name for each compound.Ch. 22 - Problem 22.5 Draw the structure corresponding to...Ch. 22 - Prob. 22.6P Ch. 22 - How would the compounds in each pair differ in...Ch. 22 - Problem 22.8 Deduce the structures of compounds ...Ch. 22 - Prob. 22.9P Ch. 22 - Rank the compounds in each group in order of...

(a) Interpretation: The product formed from the treatment of acetic acid with the given reagent is to be stated. Concept introduction: Carboxylic acids are strong organic acids. They undergo acid-base reaction with amines to yield an ammonium salt of carboxylate anion. It is a single step reaction.

Solution Summary: The author explains the product formed from the treatment of acetic acid with the given reagent.

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Chapter 22 Solutions