The stronger basic character of guanidine compared to other amines has to be found Concept Introduction : Resonance is a mental exercise and method within the Valence Bond Theory of bonding that describes the delocalization of electrons within molecules. The net sum of valid resonance structures is defined as a resonance hybrid, which represents the overall delocalization of electrons within the molecule. A molecule that has several resonance structures is more stable than one with fewer. If a compound has high resonance structures and the lone pair on any other atom is delocalized, then that compound is less basic. If a compound has no resonance structures and the lone pair on any other atom is localized, then that compound is more basic. To find: Explain the stronger basic character of guanidine compared to other amines Find the nitrogen atom which is protonated easily in guanidine

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Answer 1

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Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 22, Problem 89IP

Interpretation Introduction

Interpretation: The stronger basic character of guanidine compared to other amines has to be found

Concept Introduction:

Resonance is a mental exercise and method within the Valence Bond Theory of bonding that describes the delocalization of electrons within molecules. The net sum of valid resonance structures is defined as a resonance hybrid, which represents the overall delocalization of electrons within the molecule. A molecule that has several resonance structures is more stable than one with fewer. If a compound has high resonance structures and the lone pair on any other atom is delocalized, then that compound is less basic. If a compound has no resonance structures and the lone pair on any other atom is localized, then that compound is more basic.

To find: Explain the stronger basic character of guanidine compared to other amines

Find the nitrogen atom which is protonated easily in guanidine

Expert Solution & Answer

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See solution

Answer 2

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 22, Problem 89IP

Interpretation Introduction

Interpretation: The stronger basic character of guanidine compared to other amines has to be found

Concept Introduction:

Resonance is a mental exercise and method within the Valence Bond Theory of bonding that describes the delocalization of electrons within molecules. The net sum of valid resonance structures is defined as a resonance hybrid, which represents the overall delocalization of electrons within the molecule. A molecule that has several resonance structures is more stable than one with fewer. If a compound has high resonance structures and the lone pair on any other atom is delocalized, then that compound is less basic. If a compound has no resonance structures and the lone pair on any other atom is localized, then that compound is more basic.

To find: Explain the stronger basic character of guanidine compared to other amines

Find the nitrogen atom which is protonated easily in guanidine

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 22, Problem 89IP

Interpretation Introduction

Interpretation: The stronger basic character of guanidine compared to other amines has to be found

Concept Introduction:

Resonance is a mental exercise and method within the Valence Bond Theory of bonding that describes the delocalization of electrons within molecules. The net sum of valid resonance structures is defined as a resonance hybrid, which represents the overall delocalization of electrons within the molecule. A molecule that has several resonance structures is more stable than one with fewer. If a compound has high resonance structures and the lone pair on any other atom is delocalized, then that compound is less basic. If a compound has no resonance structures and the lone pair on any other atom is localized, then that compound is more basic.

To find: Explain the stronger basic character of guanidine compared to other amines

Find the nitrogen atom which is protonated easily in guanidine

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 22, Problem 89IP

Interpretation Introduction