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ISBN: 9780077574260
Author: Burdge
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Chapter 22.3, Problem 2CP
Interpretation Introduction
Interpretation:
The metal ionsthatcan form both low and high spin complexes from the given metal ionsareto be determined.
Concept introduction:
Ligands that cause a high degree of splitting among the
The unpaired spin number in
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Instructions:
Complex: [Fe(S2CNMe2)3], wherein Me stands for methyl group (-CH3).
Give the full name of the complex.
If we were to replace one of the (S2CNMe2) ligands with two CN- ligands, what will be the new chemical formula?
What is the percent yeild of nickel(II) coordination?
[Ni(H2O)6]Cl2 used = 5.736 g
[Ni(NH3)6]Cl2 produced = 5.410 g
Which ion would represent the pink complex?
Question 1 options:
Co(H2O7)-3
Co(H3O)
H2O
None of these
Chapter 22 Solutions
Chemistry-Connect Plus Access
Ch. 22.1 - Prob. 1PPACh. 22.1 - Prob. 1PPBCh. 22.1 - Prob. 1PPCCh. 22.1 - Prob. 1CPCh. 22.1 - Prob. 2CPCh. 22.1 - Prob. 3CPCh. 22.1 - Prob. 4CPCh. 22.2 - Prob. 1PPACh. 22.2 - Prob. 1PPBCh. 22.2 - Prob. 1PPC
Ch. 22.3 - Prob. 1PPACh. 22.3 - Prob. 1PPBCh. 22.3 - Prob. 1PPCCh. 22.3 - Prob. 1CPCh. 22.3 - Prob. 2CPCh. 22.4 - Prob. 1PPACh. 22.4 - Practice Problem BUILD
Transition metal ions can...Ch. 22.4 - Prob. 1PPCCh. 22 - Prob. 1QPCh. 22 - Prob. 2QPCh. 22 - 22.3 Explain why atomic radii decrease very...Ch. 22 - Prob. 4QPCh. 22 - Write the electron configurations of the following...Ch. 22 - Prob. 6QPCh. 22 - Prob. 7QPCh. 22 - Prob. 8QPCh. 22 - Describe the interaction between a donor atom and...Ch. 22 - Prob. 10QPCh. 22 - Complete the following statements for the complex...Ch. 22 - Prob. 12QPCh. 22 - Prob. 13QPCh. 22 - Prob. 14QPCh. 22 - Prob. 15QPCh. 22 - Prob. 16QPCh. 22 - Prob. 17QPCh. 22 - Prob. 18QPCh. 22 - Prob. 19QPCh. 22 - Prob. 20QPCh. 22 - Prob. 21QPCh. 22 - The complex ion [Ni ( CN ) 2 Br 2 ] 2- has a...Ch. 22 - Prob. 23QPCh. 22 - Prob. 24QPCh. 22 - Prob. 25QPCh. 22 - Prob. 26QPCh. 22 - Prob. 27QPCh. 22 - Prob. 28QPCh. 22 - Prob. 29QPCh. 22 - Prob. 30QPCh. 22 - Prob. 31QPCh. 22 - Prob. 32QPCh. 22 - Prob. 33QPCh. 22 - Prob. 34QPCh. 22 - Prob. 35QPCh. 22 - Prob. 36QPCh. 22 - Prob. 37QPCh. 22 - Prob. 38QPCh. 22 - Prob. 39QPCh. 22 - Prob. 40QPCh. 22 - Prob. 41QPCh. 22 - A concentrated aqueous copper(II) chloride...Ch. 22 - Prob. 43QPCh. 22 - Prob. 44QPCh. 22 - Prob. 45APCh. 22 - Prob. 46APCh. 22 - Prob. 47APCh. 22 - Prob. 48APCh. 22 - Prob. 49APCh. 22 - Draw qualitative diagrams for the crystal held...Ch. 22 - Prob. 51APCh. 22 - Prob. 52APCh. 22 - Prob. 53APCh. 22 - Prob. 54APCh. 22 - Prob. 55APCh. 22 - Prob. 56APCh. 22 - Prob. 57APCh. 22 - Prob. 58APCh. 22 - 22.59 The -porphyrin complex is more stable than...Ch. 22 - Prob. 60APCh. 22 - Prob. 61APCh. 22 - Prob. 62APCh. 22 - Prob. 63APCh. 22 - Prob. 64APCh. 22 - Prob. 65APCh. 22 - Prob. 66APCh. 22 - Prob. 67APCh. 22 - Prob. 68APCh. 22 - Locate the transition metal atoms and ions in the...Ch. 22 - Prob. 70APCh. 22 - Prob. 71APCh. 22 - Copper is known to exist in the +3 oxidation...Ch. 22 - 22.73 Chemical analysis shows that hemoglobin...Ch. 22 - Prob. 74APCh. 22 - Prob. 75APCh. 22 - Prob. 76APCh. 22 - 22.77 Commercial silver-plating operations...Ch. 22 - Prob. 78APCh. 22 - 22.79 (a) The free Cu(I) ion is unstable in...Ch. 22 - Prob. 1SEPPCh. 22 - Prob. 2SEPPCh. 22 - Prob. 3SEPPCh. 22 - Prob. 4SEPP
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- Consider the coordination compound [Ni(NH3)6]Cl2 and select all of the statements that are TRUE below. 1. The chloride ion is the ligand. 2. [Ni(NH3)6]2+ is the complex ion. 3. The oxidation state of nickel is +4. 4. Nickel and ammonia are covalently bonded. 5. Ammonia is a molecule, not an ion.arrow_forwardWhich of the following metal d orbitals overlap the most with ligands in octahedral complexes? (Check ALL correct answers.) Group of answer choices dyz dx2-y2 dxy dz2 dxzarrow_forwardWhich one of the following is the correct formula for the coordination compound triamminebromoplatinum(II) chloride? A. [Pt(NH3)3Br]Cl B. [Pt2NH3Br3]Cl2 C. [Pt(NH3)3Br2]Cl D. [Pt(NH4)3Br]Cl2 E. [Pt2(NH3)3Br]Clarrow_forward
- For which of the following complexes is it possible to react with [Ru(NH3)6]2+ via an inner-sphere redox mechanism? Group of answer choices [Cr(NH3)5(CN)]2+ [Cr(NH3)5(NO2)]2+ [Cr(NH3)5(OH)]2+ [Cr(NH3)5(H2O)]3+arrow_forwardWhich of the following complexes can exhibit cis and trans isomers? (Check ALL correct answers.) Group of answer choices [Pt(H2O)2(ox)] [Ni(NH3)3Cl3]- [Mn(NH3)3(H2O)2Cl]2+ [Co(phen)3]3+ [Ir(CO)2Cl2]- (hint: This complex has a square-planar geometry.)arrow_forwardInformation: LFSE for octahedral complexes of d7 ions: LFSE = D(0.4 nt2g - 0.6 neg)-P If the energy of Δ for the Ni(III) complex [Ni(9-aneN3)2]3+ is 23,200 cm-1, and the spin pairing energy P is 11,200 cm-1, what is the LFSE (Ligand field stabilization energy) for the complex what would be expected about the structure of the complex: a) 10,560 cm-1 b) 30,560 cm-1 c) 20160 cm-1 d) 26880 cm-1 9-ane-n3arrow_forward
- Which of the following transition metal complexes obey the 18-electron rule? (Check ALL correct answers.) [Pd(CO)2(NH3)(ox)] [Os(bipy)(NO)2Cl2]3+ [Mn(en)2(NH3)(H2O)(CN)]2+ [Fe(H2O)2Cl2(OH)2]2- [ZrCl8]4- [Cu(NH3)2(H2O)2(SCN)]arrow_forwardWhich of the following ligands does not interact with a transition metal center in a π fashion? Group of answer choices CO Cl- H2O bipyarrow_forwardQuestion: Although both nitrogen and phosphorous take place in Group VA, in complex formation ammonia acts as sigma-donor while PR3 is both sigma–donor and pi-acceptor. In the light of this explanation, show the sigma and pi interactions in [Co(PR3)6]2+ according to MO theory. What makes PR3 a different ligand than ammonia? Do I need to replace t2g orbitals in my diagram? How can I show PR3 ligands using d orbitals?arrow_forward
- Part A Which of the three complexes can have geometric isomers? Check all that apply. [Co(NH3)4Br2]Cl [Pd(NH3)2(ONO)2] [V(en)2Cl2]+ None of the complexes. Part B Which of the three complexes can have linkage isomers? [Co(NH3)4Br2]Cl [Pd(NH3)2(ONO)2] [V(en)2Cl2]+ None of the complexes. Part C Which of the three complexes can have optical isomers? Check all that apply. cis-[Co(NH3)4Br2]Cl trans-[Co(NH3)4Br2]Cl cis-[Pd(NH3)2(ONO)2] trans-[Pd(NH3)2(ONO)2] cis-[V(en)2Cl2]+ trans-[V(en)2Cl2]+ None of these Part D Which of the three complexes can have coordination-sphere isomers? Check all that apply. [Co(NH3)4Br2]Cl [Pd(NH3)2(ONO)2] [V(en)2Cl2]+ None of the complexes.arrow_forwardWhat is the d electron configuration of [Mn(NH3)6]Cl2 complex? (t2g)3(eg)2 (I tried this and seemed wrong) (t2g)2(eg)3 (t2g)5(eg)0 (t2g)3(eg)0 (t2g)6(eg)1arrow_forwardFor the [Fe (SCN)2 (o − fen)2 ]ClO4 complex answer: A. If the length of maximum absorption of the complex is 420 nm, what is the color of the complex B. Calculate the doubling of the crystalline field in kJ/mol and in cm-1.arrow_forward
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