How the given set of compounds can be prepared starting from diethyl malonate and other reagents Concept introduction: When a diketone is deprotonated to form a doubly stabilized enolate ion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α , β -unsaturated compound (Michael acceptor) is known as Michael reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

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Answer 1

Question

Chapter 22.6, Problem 46CC

(a)

Interpretation Introduction

Interpretation:

How the given set of compounds can be prepared starting from diethyl malonate and other reagents

Concept introduction:

When a diketone is deprotonated to form a doubly stabilized enolate ion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

(b)

Interpretation Introduction

Interpretation:

How the given set of compounds can be prepared starting from diethyl malonate and other reagents

Concept introduction:

When a diketone is deprotonated to form a doubly stabilized enolate ion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

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Answer 2

Question

Chapter 22.6, Problem 46CC

(a)

Interpretation Introduction

Interpretation:

How the given set of compounds can be prepared starting from diethyl malonate and other reagents

Concept introduction:

When a diketone is deprotonated to form a doubly stabilized enolate ion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

(b)

Interpretation Introduction

Interpretation:

How the given set of compounds can be prepared starting from diethyl malonate and other reagents

Concept introduction:

When a diketone is deprotonated to form a doubly stabilized enolate ion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

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Answer 3

Question

Chapter 22.6, Problem 46CC

(a)

Interpretation Introduction

Interpretation:

How the given set of compounds can be prepared starting from diethyl malonate and other reagents

Concept introduction:

When a diketone is deprotonated to form a doubly stabilized enolate ion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

(b)

Interpretation Introduction

Interpretation:

How the given set of compounds can be prepared starting from diethyl malonate and other reagents

Concept introduction:

When a diketone is deprotonated to form a doubly stabilized enolate ion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

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Answer 4

Question

Chapter 22.6, Problem 46CC

(a)

Interpretation Introduction

Interpretation:

How the given set of compounds can be prepared starting from diethyl malonate and other reagents

Concept introduction:

When a diketone is deprotonated to form a doubly stabilized enolate ion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

(b)

Interpretation Introduction

Interpretation:

How the given set of compounds can be prepared starting from diethyl malonate and other reagents

Concept introduction:

When a diketone is deprotonated to form a doubly stabilized enolate ion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

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Answer 5

Chapter 22.6, Problem 46CC

(a)

Interpretation Introduction

Interpretation:

How the given set of compounds can be prepared starting from diethyl malonate and other reagents

Concept introduction:

When a diketone is deprotonated to form a doubly stabilized enolate ion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

(b)

Interpretation Introduction

Interpretation:

How the given set of compounds can be prepared starting from diethyl malonate and other reagents

Concept introduction:

When a diketone is deprotonated to form a doubly stabilized enolate ion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Answer 6

Chapter 22.6, Problem 46CC

(a)

Interpretation Introduction

Interpretation:

How the given set of compounds can be prepared starting from diethyl malonate and other reagents

Concept introduction:

When a diketone is deprotonated to form a doubly stabilized enolate ion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Answer 7

Chapter 22.6, Problem 46CC

(a)

Interpretation Introduction

Interpretation:

How the given set of compounds can be prepared starting from diethyl malonate and other reagents

Concept introduction:

When a diketone is deprotonated to form a doubly stabilized enolate ion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Answer 8

(b)

Interpretation Introduction

Interpretation:

How the given set of compounds can be prepared starting from diethyl malonate and other reagents

Concept introduction:

When a diketone is deprotonated to form a doubly stabilized enolate ion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Answer 9

(b)

Interpretation Introduction

Interpretation:

How the given set of compounds can be prepared starting from diethyl malonate and other reagents

Concept introduction:

When a diketone is deprotonated to form a doubly stabilized enolate ion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 22.1 - Prob. 1CC Ch. 22.1 - Prob. 2CC Ch. 22.1 - Prob. 3CC Ch. 22.1 - Prob. 1LTS Ch. 22.1 - Prob. 4PTS Ch. 22.1 - Prob. 5ATS Ch. 22.1 - Prob. 6CC Ch. 22.1 - Prob. 7CC Ch. 22.1 - Prob. 8CC Ch. 22.2 - Prob. 9CC

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Chapter 22 Solutions