How the compound shown can be prepared using acetoacetic ester synthesis is to be stated. Concept introduction: Acetoacetic ester synthesis converts an alkyl halide in to a methyl ketone having three more carbons. The methyl ketone part comes from acetoacetic eater while the remaining carbon comes from the primary alkyl halide. The reaction occurs in three steps 1) enolate ion formation ii) S N 2 attack of the enolate anion on the alkyl halide iii) hydrolysis and decarboxylation. To state: How to prepare the compound shown using acetoacetic ester synthesis.

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Answer 1

Question

Chapter 22.7, Problem 15P

Interpretation Introduction

Interpretation:

How the compound shown can be prepared using acetoacetic ester synthesis is to be stated.

Concept introduction:

Acetoacetic ester synthesis converts an alkyl halide in to a methyl ketone having three more carbons. The methyl ketone part comes from acetoacetic eater while the remaining carbon comes from the primary alkyl halide. The reaction occurs in three steps 1) enolate ion formation ii) ^SN² attack of the enolate anion on the alkyl halide iii) hydrolysis and decarboxylation.

To state:

How to prepare the compound shown using acetoacetic ester synthesis.

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How would you prepare the following ketones using an acetoacetic ester synthesis?

How would you prepare the following esters

Show how to synthesize the following compound using either the malonic ester synthesis or the acetoacetic ester synthesis. Q.) 3-Ethyl-2-pentanone

Answer 2

Question

Chapter 22.7, Problem 15P

Interpretation Introduction

Interpretation:

How the compound shown can be prepared using acetoacetic ester synthesis is to be stated.

Concept introduction:

Acetoacetic ester synthesis converts an alkyl halide in to a methyl ketone having three more carbons. The methyl ketone part comes from acetoacetic eater while the remaining carbon comes from the primary alkyl halide. The reaction occurs in three steps 1) enolate ion formation ii) ^SN² attack of the enolate anion on the alkyl halide iii) hydrolysis and decarboxylation.

To state:

How to prepare the compound shown using acetoacetic ester synthesis.

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Answer 3

Question

Chapter 22.7, Problem 15P

Interpretation Introduction

Interpretation:

How the compound shown can be prepared using acetoacetic ester synthesis is to be stated.

Concept introduction:

Acetoacetic ester synthesis converts an alkyl halide in to a methyl ketone having three more carbons. The methyl ketone part comes from acetoacetic eater while the remaining carbon comes from the primary alkyl halide. The reaction occurs in three steps 1) enolate ion formation ii) ^SN² attack of the enolate anion on the alkyl halide iii) hydrolysis and decarboxylation.

To state:

How to prepare the compound shown using acetoacetic ester synthesis.

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Answer 4

Question

Chapter 22.7, Problem 15P

Interpretation Introduction

Interpretation:

How the compound shown can be prepared using acetoacetic ester synthesis is to be stated.

Concept introduction:

Acetoacetic ester synthesis converts an alkyl halide in to a methyl ketone having three more carbons. The methyl ketone part comes from acetoacetic eater while the remaining carbon comes from the primary alkyl halide. The reaction occurs in three steps 1) enolate ion formation ii) ^SN² attack of the enolate anion on the alkyl halide iii) hydrolysis and decarboxylation.

To state:

How to prepare the compound shown using acetoacetic ester synthesis.

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Answer 5

Chapter 22.7, Problem 15P

Interpretation Introduction

Interpretation:

How the compound shown can be prepared using acetoacetic ester synthesis is to be stated.

Concept introduction:

Acetoacetic ester synthesis converts an alkyl halide in to a methyl ketone having three more carbons. The methyl ketone part comes from acetoacetic eater while the remaining carbon comes from the primary alkyl halide. The reaction occurs in three steps 1) enolate ion formation ii) ^SN² attack of the enolate anion on the alkyl halide iii) hydrolysis and decarboxylation.

To state:

How to prepare the compound shown using acetoacetic ester synthesis.

Answer 6

Chapter 22.7, Problem 15P

Interpretation Introduction

Interpretation:

How the compound shown can be prepared using acetoacetic ester synthesis is to be stated.

Concept introduction:

Acetoacetic ester synthesis converts an alkyl halide in to a methyl ketone having three more carbons. The methyl ketone part comes from acetoacetic eater while the remaining carbon comes from the primary alkyl halide. The reaction occurs in three steps 1) enolate ion formation ii) ^SN² attack of the enolate anion on the alkyl halide iii) hydrolysis and decarboxylation.

To state:

How to prepare the compound shown using acetoacetic ester synthesis.

Answer 7

Chapter 22.7, Problem 15P

Interpretation Introduction

Interpretation:

How the compound shown can be prepared using acetoacetic ester synthesis is to be stated.

Concept introduction:

Acetoacetic ester synthesis converts an alkyl halide in to a methyl ketone having three more carbons. The methyl ketone part comes from acetoacetic eater while the remaining carbon comes from the primary alkyl halide. The reaction occurs in three steps 1) enolate ion formation ii) ^SN² attack of the enolate anion on the alkyl halide iii) hydrolysis and decarboxylation.

To state:

How to prepare the compound shown using acetoacetic ester synthesis.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 22.1 - Prob. 1P Ch. 22.1 - How many acidic hydrogens does each of the...Ch. 22.1 - Prob. 3P Ch. 22.3 - Write the complete mechanism for the deuteration...Ch. 22.3 - Prob. 5P Ch. 22.4 - If methanol rather than water is added at the end...Ch. 22.5 - Prob. 7P Ch. 22.5 - Draw a resonance structure of the acetonitrile...Ch. 22.6 - If methanol rather than water is added at the end...Ch. 22.7 - Prob. 10P

Solution Summary: The author explains how the compound shown can be prepared using acetoacetic ester synthesis. The base ethoxide ion abstracts a proton from the active methylene group to form an

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Chapter 22 Solutions