ORGANIC CHEMISTRY-EBOOK>I<
9th Edition
ISBN: 9781305084414
Author: McMurry
Publisher: INTER CENG
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Chapter 23.11, Problem 20P
Show how you might use an enamine reaction to prepare each of the following compounds:
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ⒸN-cthyl-N-methyl-2-propyl-N-cyclohexanamine
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Write the reactions for the preparation and properties of the following compounds
Chapter 23 Solutions
ORGANIC CHEMISTRY-EBOOK>I<
Ch. 23.1 - Prob. 1PCh. 23.1 - Prob. 2PCh. 23.3 - Prob. 3PCh. 23.3 - Prob. 4PCh. 23.4 - Prob. 5PCh. 23.4 - 1-Butanol is prepared commercially by a route that...Ch. 23.4 - Prob. 7PCh. 23.5 - Prob. 8PCh. 23.6 - Prob. 9PCh. 23.6 - What product would you Expect to obtain from base...
Ch. 23.7 - Show the products you would expect to obtain by...Ch. 23.7 - Prob. 12PCh. 23.8 - What product would you expect from the following...Ch. 23.9 - What product would you expect From the following...Ch. 23.9 - Prob. 15PCh. 23.10 - Prob. 16PCh. 23.10 - Prob. 17PCh. 23.10 - Prob. 18PCh. 23.11 - Prob. 19PCh. 23.11 - Show how you might use an enamine reaction to...Ch. 23.12 - Prob. 21PCh. 23.12 - How would you prepare the following compound using...Ch. 23.SE - Prob. 23VCCh. 23.SE - Prob. 24VCCh. 23.SE - Prob. 25VCCh. 23.SE - The following molecule was formed by a Robinson...Ch. 23.SE - Prob. 27MPCh. 23.SE - Prob. 28MPCh. 23.SE - Predict the product(s) and provide the mechanism...Ch. 23.SE - Predict the product(s) and provide the mechanism...Ch. 23.SE - Predict the product(s) and provide the mechanism...Ch. 23.SE - Knoevenagel condensation is a reaction involving...Ch. 23.SE - Azlactones are important starting materials used...Ch. 23.SE - Prob. 34MPCh. 23.SE - Isoleucine, another of the twenty amino acids...Ch. 23.SE - The first step in the citric acid cycle of food...Ch. 23.SE - Prob. 37MPCh. 23.SE - The Knoevenagel reaction is a carbonyl...Ch. 23.SE - The Darzens reaction invoIves a two-step,...Ch. 23.SE - The following reaction involves a hydrolysis...Ch. 23.SE - Prob. 41MPCh. 23.SE - Prob. 42MPCh. 23.SE - Prob. 43MPCh. 23.SE - Propose a mechanism for the following...Ch. 23.SE - Prob. 45MPCh. 23.SE - Prob. 46MPCh. 23.SE - Prob. 47MPCh. 23.SE - Prob. 48APCh. 23.SE - Prob. 49APCh. 23.SE - Prob. 50APCh. 23.SE - Prob. 51APCh. 23.SE - Prob. 52APCh. 23.SE - Prob. 53APCh. 23.SE - Prob. 54APCh. 23.SE - Prob. 55APCh. 23.SE - Prob. 56APCh. 23.SE - Prob. 57APCh. 23.SE - Prob. 58APCh. 23.SE - In the mixed Claisen reaction of cyclopentanone...Ch. 23.SE - Ethyl dimethylacetoacetate reacts instantly at...Ch. 23.SE - Prob. 61APCh. 23.SE - Prob. 62APCh. 23.SE - The so-called Wieland-Miescher ketone is a...Ch. 23.SE - Prob. 64APCh. 23.SE - Prob. 65APCh. 23.SE - Prob. 66APCh. 23.SE - What condensation products would you expect to...Ch. 23.SE - The following reactions are unlikely to provide...Ch. 23.SE - Fill in the missing reagents a-h in the following...Ch. 23.SE - Prob. 70APCh. 23.SE - Prob. 71APCh. 23.SE - Prob. 72APCh. 23.SE - Prob. 73AP
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- Rank the compounds in each group in order of increasing basicity.arrow_forwardDraw the structures for the carbonyl compound and amine required to synthesize benzyl methylamine via reductive amination. Lone pairs do not need to be included.arrow_forwardDetermine the hybridization around the N atom in each amine, andexplain why cyclohexanamine is 106 times more basic than aniline.arrow_forward
- Draw the structure for the following compounds It organic 1: 2,2 diiodo-3-pentenoic acid 2: N,N-diethylpropanamide 3: 2-pentanone 4: phenoxy benzene 5: N,N-diethylpropanamidearrow_forwardAnnotate the H-NMR spectra of Benzophenonearrow_forwardWhat is the name of this compound? CH3 H3C NH2 CH3 O ethylmethylbutylammonium O cthylmethyl-sec-butyl-ammoium ON-ethyl-N-methyl-3-butamine ON-ethyl-N-methyl-2-butanamine Z-arrow_forward
- What products are formed by acidic hydrolysis of the following compound? benzaldehyde and butan-1-d benzeie acid and butan-2-d 2-methylbutanoic acid and phenol benzoic acid and methyl ethyl ketonearrow_forwardName the following compound: O Butyl cyclohexanoate O Butanoic cyclohexanecarboxylic anhydride O Cyclohexyl butanoate O Cyclohexanoic butanoate O Butyl cyclohexyl anhydridearrow_forwardProvide the steps to convert the following aldehyde to the given amine product.arrow_forward
- Starting from benzylamine, draw the structure of the major products upon reaction with the following reagents Starting material Reagents Major Product HBr Acetic Acid "I Acetyl chloride Ethylene oxide 3 moles of methyl iodidearrow_forwardShow how to synthesize the following amines from the indicated starting materials below. Each of the final products may require several sequential steps. Draw the structure for each of the steps and show the reagents required. Starting material Final product h) 4-ethyl-3-methylhexan-1-ol 4-ethyl-3-methylhexan-1-amine i) 2-phenylacetyl chloride N-N-dimethyl-2-phenylethan-1-amine j) ethyl acetate N-ethylpropan-2-aminearrow_forwardWhich of the following compounds would react together at room temperature to form the following compound? hexanoic acid and 2-propanamine 2-propanamine and hexanoic anhydride O hexanamide and 2-propanol pentanoic acid and 2-propanaminearrow_forward
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