(a) Interpretation: The crossed Claisen product that is formed by the given pair of compounds is to be identified. Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α − carbon atom of an ester to form enolate. This enolate reacts with carbonyl compound of other ester that leads to the formation of a β-keto ester . The crossed Claisen condensation always takes place between the two different carbonyl compounds.

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Answer 1

Question

Chapter 24, Problem 24.17P

Interpretation Introduction

(a)

Interpretation: The crossed Claisen product that is formed by the given pair of compounds is to be identified.

Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl compound of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Interpretation Introduction

(b)

Interpretation: The crossed Claisen product that is formed by the given pair of compounds is to be identified.

Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl compound of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

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Answer 2

Question

Chapter 24, Problem 24.17P

Interpretation Introduction

(a)

Interpretation: The crossed Claisen product that is formed by the given pair of compounds is to be identified.

Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl compound of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Interpretation Introduction

(b)

Interpretation: The crossed Claisen product that is formed by the given pair of compounds is to be identified.

Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl compound of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

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Answer 3

Question

Chapter 24, Problem 24.17P

Interpretation Introduction

(a)

Interpretation: The crossed Claisen product that is formed by the given pair of compounds is to be identified.

Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl compound of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Interpretation Introduction

(b)

Interpretation: The crossed Claisen product that is formed by the given pair of compounds is to be identified.

Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl compound of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

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Answer 4

Question

Chapter 24, Problem 24.17P

Interpretation Introduction

(a)

Interpretation: The crossed Claisen product that is formed by the given pair of compounds is to be identified.

Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl compound of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Interpretation Introduction

(b)

Interpretation: The crossed Claisen product that is formed by the given pair of compounds is to be identified.

Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl compound of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

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Answer 5

Chapter 24, Problem 24.17P

Interpretation Introduction

(a)

Interpretation: The crossed Claisen product that is formed by the given pair of compounds is to be identified.

Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl compound of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Interpretation Introduction

(b)

Interpretation: The crossed Claisen product that is formed by the given pair of compounds is to be identified.

Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl compound of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Answer 6

Chapter 24, Problem 24.17P

Interpretation Introduction

(a)

Interpretation: The crossed Claisen product that is formed by the given pair of compounds is to be identified.

Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl compound of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Answer 7

Chapter 24, Problem 24.17P

Interpretation Introduction

(a)

Interpretation: The crossed Claisen product that is formed by the given pair of compounds is to be identified.

Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl compound of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Answer 8

Interpretation Introduction

(b)

Interpretation: The crossed Claisen product that is formed by the given pair of compounds is to be identified.

Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl compound of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Answer 9

Interpretation Introduction

(b)

Interpretation: The crossed Claisen product that is formed by the given pair of compounds is to be identified.

Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl compound of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 24 - Prob. 24.1P Ch. 24 - Prob. 24.2P Ch. 24 - Problem 24.3 What unsaturated carbonyl compound is...Ch. 24 - Prob. 24.4P Ch. 24 - Prob. 24.5P Ch. 24 - Prob. 24.6P Ch. 24 - Problem 24.7 Draw the products formed in each...Ch. 24 - Problem 24.8 Draw the products formed in the...Ch. 24 - Prob. 24.9P Ch. 24 - Prob. 24.10P

Solution Summary: The author explains the cross-claisen product that is formed by the given pair of compounds.

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Chapter 24 Solutions