Organic Chemistry - Standalone book
Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 24.12, Problem 14P
Interpretation Introduction

Interpretation:

The reasons for the classifications in the structural formula for N-acetylneuraminic acid described as a ketose is to be explained and carbon atoms in the nine-carbon chain are to be numbered and the configuration of the highest numbered chirality center is to be determined.

Concept introduction:

In carbohydrates, if one of hydroxyl groups is replaced by an amino group, then the sugar is called amino sugar.

The sugar is a ketose sugar in which the anomeric carbon of a pyranose ring bears both, the hydroxyl group and a carbon substituent.

In carbohydrates, there is a possibility of replacement of one or more hydroxyl substituents by some other atoms.

The carbon atom with the highest oxidation state is given number one.

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Part 1  Show the complete steps and products of the Haworth Projection structure of the following saccharides. The males have to answer the structure of D-fructose and the females are the structure of D-galactose. Expanded structure of the given molecule Fischer Projection Haworth's structure [show the complete steps]         Step 1   Step 2   Step 3     Part 2 Show the synthesis of disaccharide lactose. Give the expanded structure of the reactants.       Give the expanded structure of the products.         Part 3. Show the chemical reaction of  D-ribose. Name the chemical reaction. Show here the chemical equation and name the products. Use the expanded structure. 1.     2.     3.
Ignoring chirality, draw the Haworth structure of allose. The open-chain Fischer projection for the monosaccharide is given here.  Include only the hydrogen atoms attached to the oxygen atoms in the OH groups when drawing the cyclic form.
Using fructose and glucose as examples explain the concept of chirality?
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