(a)
Interpretation: The amide(s) that can be used to prepare the given amine by reduction is to be stated.
Concept introduction:
(b)
Interpretation: The amide(s) that can be used to prepare the given amine by reduction is to be stated.
Concept introduction: Amines are the derivatives of ammonia consisting of a nitrogen atom with the lone pair of electrons. They are basic compounds. The synthesis of the products relies upon the type of reactants and reagents that are used during the reactions. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.
(c)
Interpretation: The amide(s) that can be used to prepare the given amine by reduction is to be stated.
Concept introduction: Amines are the derivatives of ammonia consisting of a nitrogen atom with the lone pair of electrons. They are basic compounds. The synthesis of the products relies upon the type of reactants and reagents that are used during the reactions. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.
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ORGANIC CHEMISTRY-W/ACCESS
- Identify compound A, B, C, and Darrow_forwardSafrole, which is isolated from sassafras, can be converted to the illegal stimulant MDMA (3,4- methylenedioxymethamphetamine, “Ecstasy”) by a variety of methods. (a) Devise a synthesis that begins with safrole and uses a nucleophilic substitution reaction to introduce the amine. (b) Devise a synthesis that begins with safrole and uses reductive amination to introduce the amine.arrow_forwardWhat amine is formed by reduction of each amide?arrow_forward
- Safrole, which is isolated from sassafras (Problem 21.33), can be converted to the illegal stimulant MDMA (3,4- methylenedioxymethamphetamine, “Ecstasy”) by a variety of methods. (a) Devise a synthesis that begins with safrole and uses a nucleophilic substitution reaction to introduce the amine. (b) Devise a synthesis that begins with safrole and uses reductive amination to introduce the amine.arrow_forwardDraw structures for compounds A–F.arrow_forwardShow how to convert amines to other functional groups, and devise multistepsyntheses using amines as starting materials and intermediatesarrow_forward
- explain the following observations a. propanol is more water soluble than propane b. propanol is more water soluble than propanonearrow_forwardSynthadotin is a promising anticancer drug in clinical trials. a.Identify the functional groups. b.Classify any amine or amide as 1°, 2°, or 3°. c.At which sites can synthadotin hydrogen bond to another molecule like itself? d. Label two nucleophilic sites. e. Label two electrophilic sites. f. What product is formed when synthadotin is treated with HCl?arrow_forwardRank the following amines based on basicity.arrow_forward
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