Inorganic Chemistry
5th Edition
ISBN: 9781292134147
Author: Housecroft, Catherine E.
Publisher: Pearson,
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Chapter 3, Problem 30P
Determine how many CO stretching modes are possible for trans-
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What are the conditions for a molecule to be Raman active, IR active.
Using group theory and the stretching mode of CO, predict how many IR active vibrational modes you should have for
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Chapter 3 Solutions
Inorganic Chemistry
Ch. 3 - 3.1 Give the structures of the following...Ch. 3 - 3.2 In the group theory, what is meant by the...Ch. 3 - For each of the following 2-dimensional shapes,...Ch. 3 - Draw the structure of SO2 and identify its...Ch. 3 - 3.5 The structure of was shown in Fig. 2.1. Apart...Ch. 3 - By drawing appropriate diagrams, illustrate the...Ch. 3 - Using the answer to problem 3.6 to help you,...Ch. 3 - 3.8 Which of the following species or ions contain...Ch. 3 - Which of the following species contain C4 axis and...Ch. 3 - 3.10 How many mirror planes each do each of the...
Ch. 3 - (a) What structure would you expect Si2H6 to...Ch. 3 - Prob. 12PCh. 3 - Explain what is meant by an -fold axis of...Ch. 3 - 3.14 To which point group to does belong?
Ch. 3 - 3.15 The point group of is . What shape is this...Ch. 3 - 3.16 Determine the point group of .
Ch. 3 - 3.17 The point group of is . Draw the structure...Ch. 3 - 3.18 In worked example 2.7, the structure of the ...Ch. 3 - 3.19 Assign a point group to each member in the...Ch. 3 - (a) Deduce the point group of SF4. (b) Is SOF4 in...Ch. 3 - 3.21 Which of the point groups possess the highest...Ch. 3 - Prob. 22PCh. 3 - Prob. 23PCh. 3 - Prob. 24PCh. 3 - 3.25 By considering the effect of each symmetry...Ch. 3 - To what point group does CBr4 belong? Using the...Ch. 3 - Prob. 27PCh. 3 - Al2Cl6 belongs to the D2h point group: How many...Ch. 3 - Prob. 29PCh. 3 - Determine how many CO stretching modes are...Ch. 3 - 3.31 In 1993, the ion was reported for the first...Ch. 3 - Prob. 32PCh. 3 - (a) To which point group does a trigonal...Ch. 3 - Prob. 34PCh. 3 - Confirm the symmetry operations of (a) inversion...Ch. 3 - Prob. 42PCh. 3 - Prob. 43P
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Practice Problem ATTEMPT
Write the rate expressions for each of the following reactions:
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(b)
(c)
Chemistry
Draw a Lewis structure for each covalent molecule. a. HBr b. CH3F c. H2O2 d. N2H4 e. C2H6 f. CH2Cl2
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- How many degrees of vibrational freedom does Al2Cl6 possess? Use the D2h character table to determine the symmetries of the IR active stretching modes of vibration.arrow_forwardConsider a trigonal bipyramidal molecule XY5. (i) To which point group does this molecule belong? (ii) How many normal modes and how many stretching vibrations will this molecule exhibit? (iii) Determine the irreducible representations of stretching vibrations of this molecule. Clearly show all your work. (iv) Which of these vibrations stretching are IR and which are Raman active? Justify your choice How many normal modes and how many stretching vibrations will this molecule exhibitarrow_forwardDetermine the number (and relative intensity) of IR-active C–O stretching vibrations for fac-[Mo(CO)3(NCMe)3]: Proceed as follows... Determine the point group of the molecule. Do not descend in symmetry. Construct a reducible representation for the CO vibrations (ΓCO) -- [please explain how to determine the number of unshifted atoms] Decompose ΓCO into its irreducible representation ΓCO,i.r. Determine which are IR active (number of IR active modes) Double degenerate modes (i.r. with E symmetry) are ≈ twice as intense as other modes, and triply degenerate modes (i.r. with T symmetry) are ≈ three times as intense.arrow_forward
- Find the reducible for S=O stretching frequencies in SO2Cl2. How many are IR vs Raman active?arrow_forwardThe stretching frequencies for H2, HD, and D2 are 4395, 3817, and 3118 cm-1 respectively. Why? Explain.arrow_forwardHow do the rotation axes and planes of symmetry in cis- and trans-N2F2 differ? Why do CO2 and SO2 have different number of degrees of vibrational mode? Calculate the no of vibration modes of CO2. Which of these are IR or Raman Active?arrow_forward
- determine:(i) the point group to which thiophene (C 4 H 4 S) belongs;(ii) the number of internal degrees of freedom for thiophene;(iii) the irreducible representation for thiophene;(iv) the number of IR active C-H stretching modes for thiophene;(v) the number of Raman active C-H stretching modes for thiophene.arrow_forwardFor a Mn3+ ion in its ground electronic state: How many electrons are there in the 4s orbital?arrow_forwardWhat can you conclude about the symmetry of the C3H5+ ion as it actually exists, as regards the bond lengths and the distribution of the positive charge?arrow_forward
- What are the symmetry (irreducible representation) of the bending and asymmetric stretching vibration of C-Cl in COCl2 ? Are they IR or Raman or Both active??arrow_forwardwhat is the absolute energy (wavenumbers) for hydrogn from n=6 to n=1arrow_forwardIn which point group are the letters A, F, N respectively?arrow_forward
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