Inorganic Chemistry
5th Edition
ISBN: 9781292134147
Author: Housecroft, Catherine E.
Publisher: Pearson,
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Textbook Question
Chapter 3, Problem 7P
Using the answer to problem 3.6 to help you, deduce which symmetry elements are lost on going from (a)
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Give the ground state electron configurations of(a) Li2 (b) Be2 (c) C2 .Use the symmetry-specific nomenclature appropriate for homonuclear diatomics. Example, Sg would stand for σg. Enclose each MO in parenthesis followed by the number of electrons in that MO, e.g., the entry (1Sg)2 would represent 1σg2. Letter P then is used to represent a pair of π MO's.
Define the term symmetry operations.
How to determine symmetry elements, σh and σν and how to differentiate between both. Also , how is σh related to E.
Chapter 3 Solutions
Inorganic Chemistry
Ch. 3 - 3.1 Give the structures of the following...Ch. 3 - 3.2 In the group theory, what is meant by the...Ch. 3 - For each of the following 2-dimensional shapes,...Ch. 3 - Draw the structure of SO2 and identify its...Ch. 3 - 3.5 The structure of was shown in Fig. 2.1. Apart...Ch. 3 - By drawing appropriate diagrams, illustrate the...Ch. 3 - Using the answer to problem 3.6 to help you,...Ch. 3 - 3.8 Which of the following species or ions contain...Ch. 3 - Which of the following species contain C4 axis and...Ch. 3 - 3.10 How many mirror planes each do each of the...
Ch. 3 - (a) What structure would you expect Si2H6 to...Ch. 3 - Prob. 12PCh. 3 - Explain what is meant by an -fold axis of...Ch. 3 - 3.14 To which point group to does belong?
Ch. 3 - 3.15 The point group of is . What shape is this...Ch. 3 - 3.16 Determine the point group of .
Ch. 3 - 3.17 The point group of is . Draw the structure...Ch. 3 - 3.18 In worked example 2.7, the structure of the ...Ch. 3 - 3.19 Assign a point group to each member in the...Ch. 3 - (a) Deduce the point group of SF4. (b) Is SOF4 in...Ch. 3 - 3.21 Which of the point groups possess the highest...Ch. 3 - Prob. 22PCh. 3 - Prob. 23PCh. 3 - Prob. 24PCh. 3 - 3.25 By considering the effect of each symmetry...Ch. 3 - To what point group does CBr4 belong? Using the...Ch. 3 - Prob. 27PCh. 3 - Al2Cl6 belongs to the D2h point group: How many...Ch. 3 - Prob. 29PCh. 3 - Determine how many CO stretching modes are...Ch. 3 - 3.31 In 1993, the ion was reported for the first...Ch. 3 - Prob. 32PCh. 3 - (a) To which point group does a trigonal...Ch. 3 - Prob. 34PCh. 3 - Confirm the symmetry operations of (a) inversion...Ch. 3 - Prob. 42PCh. 3 - Prob. 43P
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- Linearly polarized light can be assigned a specific irreducible representation of a symmetry point group. If the electronic ground state of benzene has A1g symmetry and y- polarized light has the label E1u, what are the symmetry labels of allowed excited electronic states? Use the D6h character table in Appendix 3.arrow_forwardLinearly polarized light can be assigned a specific irreducible representation of a symmetry point group. If the electronic ground state of methane has A1g symmetry and x- polarized light has the label T2, what are the symmetry labels of allowed excited electronic states? Use the Td character table in Appendix 3.arrow_forwardAssume that x- polarized light can be assigned an E symmetry species in a system that has C4v symmetry. Can a transition from E state to a B2 state occur? Why or why not?arrow_forward
- (b) Using appropriate diagram(s), show which of the symmetry operation(s) does the [SO4]2- ion have: (i) C4 (ii) σh (iii) S4arrow_forward1. Below are two views of the triflate anion, CF3SO3−. a. Using the conventions learned in class, draw the following: i. A cartesian coordinate system. Indicate which view your coordinate system corresponds to. ii. The principal axis of rotation. Give the axis using the proper notation for symmetry elements. iii. One of the mirror planes. Name the mirror axis, including the name of the cartesian plane. b. List ALL unique symmetry operations present for triflate. You do not need to include redundant ones (e.g. since, C33 = E, you do not need to include C33). c. What is the point group of triflate?arrow_forwardFor the Acetone molecule, using each of the symmetry operations of the C2v molecule (E, C2, σx,z, σy,z), confirm that this deformation does have the same symmetry as the B1representation in the character table. Do each symmetry operation and write down the sequence of 1s and -1s.arrow_forward
- Make sketches of the following showing approximately correct geometry and all valence shell electrons. Identify all symmetry elements present and determine the point group for the species (d) SO32-. (e)SF6 (f) IF5 (g) CIF3 (h) SO3 (i) CIO2- j) NSF this is the next sub part, A B and C is already answered.arrow_forwarddefine the ground term for the configuration d8 (Oh symmetry). Please provide solution. Thank you.arrow_forwardAbove is the structure for 1,5-dibromonaphthalene. a) list all the symmetry elements b) identify the point group c) based on the point group, determine if they are chiral or achiral d) based on the point group, determine if they may be polar or nonpolar Please answer very soon will give rating surelyarrow_forward
- determine the ground state term symbol for 4d75d1(ignore spin orbit coupling)arrow_forward9- Write all symmetry elements and point group of PCI5 molecule. (Draw the shape)arrow_forwardDraw the Lewis structure of the following compounds and identify the point group. Indicate the symmetry operations you performed in determining the point groups.a. 1,8-Dichloronaphthaleneb. Eclipsed dibenzenechromium (Hint: The Cr atom is sandwiched between the two-benzene ring in eclipsed conformation.)c. Borazine (B3H6N3) (Hint: The structure looks like benzene, but instead of C, B and N are the atoms in alternating order.)arrow_forward
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