PHYSICS F/SCIEN.+ENGRS. W/SAPLING >IC<
6th Edition
ISBN: 9781319336127
Author: Tipler
Publisher: MAC HIGHER
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Chapter 36, Problem 52P
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Angular momentum and Spin. An electron in an H-atom has orbital angular momentum magnitude
and z-component given by
L² = 1(1+1)ħ²,
Lz = m₁h,
1 = 0,1,2,..., n 1
-
m₁ = 0, ±1, ±2, ..., ±l
3
S² = s(s+1) h² = =h²₁
4
Consider an excited electron (n > 1) on an H-atom.
The total angular momentum ] = L + Š, whose magnitude and z-component follow a similar
dependence to some quantum numbers j and m; as
J² = j(j + 1)ħ², Jz = mjħ
1
S₂ = m₂h = ± = h
Where j and m; are quantum numbers which assume values that jumps in steps of one such
that j is non-negative and −j ≤ m¡ ≤ j. For a given quantum number 1, what are the (two)
possible values for j?
Clue: we can use the vector sum relation of angular momenta, then consider the z-component only.
Which of the following is a permissable set of quantum numbers for an electron in a hydrogen atom? The atom may be in an excited state (ie. the electron need not be in its ground state).
a) n = 6, l = -5, ml = +4, ms = +1/2
b) n = 4, l = -2, ml = +2, ms = -1/2
c) n = 2, l = 2, ml = +1, ms = -1/2
d) n = 5, l = 1, ml = -1, ms = +1/2
e) n = 3, l = 2, ml = -2, ms = -1
Angular momentum and Spin. An electron in an H-atom has orbital angular momentum magnitude and
z-component given by
L² = 1(1+1)ħ², 1 = 0,1,2,..., n-1
Lz = m₂ħ,
m₁ = 0, ±1, ±2,..., ±l
3
S² = s(s+1)h² = h²,
4
Consider an excited electron (n > 1) on an H-atom.
Sz = msh
1
=+=ħ
Show that the minimum angle that the I can have with the z-axis is given by
n-1
n
L.min = cos
Clue: the angle a vector with magnitude V from the z-axis can be computed from cos 0 = V²/V
Chapter 36 Solutions
PHYSICS F/SCIEN.+ENGRS. W/SAPLING >IC<
Ch. 36 - Prob. 1PCh. 36 - Prob. 2PCh. 36 - Prob. 3PCh. 36 - Prob. 4PCh. 36 - Prob. 5PCh. 36 - Prob. 6PCh. 36 - Prob. 7PCh. 36 - Prob. 8PCh. 36 - Prob. 9PCh. 36 - Prob. 10P
Ch. 36 - Prob. 11PCh. 36 - Prob. 12PCh. 36 - Prob. 13PCh. 36 - Prob. 14PCh. 36 - Prob. 15PCh. 36 - Prob. 16PCh. 36 - Prob. 17PCh. 36 - Prob. 18PCh. 36 - Prob. 19PCh. 36 - Prob. 20PCh. 36 - Prob. 21PCh. 36 - Prob. 22PCh. 36 - Prob. 23PCh. 36 - Prob. 24PCh. 36 - Prob. 25PCh. 36 - Prob. 26PCh. 36 - Prob. 27PCh. 36 - Prob. 28PCh. 36 - Prob. 29PCh. 36 - Prob. 30PCh. 36 - Prob. 31PCh. 36 - Prob. 32PCh. 36 - Prob. 33PCh. 36 - Prob. 34PCh. 36 - Prob. 35PCh. 36 - Prob. 36PCh. 36 - Prob. 37PCh. 36 - Prob. 38PCh. 36 - Prob. 39PCh. 36 - Prob. 40PCh. 36 - Prob. 41PCh. 36 - Prob. 42PCh. 36 - Prob. 43PCh. 36 - Prob. 44PCh. 36 - Prob. 45PCh. 36 - Prob. 46PCh. 36 - Prob. 47PCh. 36 - Prob. 48PCh. 36 - Prob. 49PCh. 36 - Prob. 50PCh. 36 - Prob. 51PCh. 36 - Prob. 52PCh. 36 - Prob. 53PCh. 36 - Prob. 54PCh. 36 - Prob. 55PCh. 36 - Prob. 56PCh. 36 - Prob. 57PCh. 36 - Prob. 58PCh. 36 - Prob. 59PCh. 36 - Prob. 60PCh. 36 - Prob. 61PCh. 36 - Prob. 62PCh. 36 - Prob. 63PCh. 36 - Prob. 64PCh. 36 - Prob. 65PCh. 36 - Prob. 66PCh. 36 - Prob. 67PCh. 36 - Prob. 68PCh. 36 - Prob. 69PCh. 36 - Prob. 70PCh. 36 - Prob. 71PCh. 36 - Prob. 72PCh. 36 - Prob. 73PCh. 36 - Prob. 74PCh. 36 - Prob. 75P
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