Physics for Scientists and Engineers
6th Edition
ISBN: 9781429281843
Author: Tipler
Publisher: MAC HIGHER
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Chapter 37, Problem 25P
To determine
The vibrational quantum number that corresponds to
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The CO molecule has a dipole moment of 0.480x10-30 C m. Given that its equilibrium bond distance is 212 pm, what is the magnitude of the effective charge that causes this dipole moment? Give your answer in units of the charge of an electron
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However, the molecule we can encounter everyday continuously vibrates and interact with the surrounding causing its bond vector to vary slightly. According to a new spectroscopy analysis, the adjacent bond vectors was found to be
A = 0.82i + 0.99j + 0.84k
B = 1.09i + -1.01j + -0.97k
What is the angle (in degrees) between the bonds based on this new data?
Chapter 37 Solutions
Physics for Scientists and Engineers
Ch. 37 - Prob. 1PCh. 37 - Prob. 2PCh. 37 - Prob. 3PCh. 37 - Prob. 4PCh. 37 - Prob. 5PCh. 37 - Prob. 6PCh. 37 - Prob. 7PCh. 37 - Prob. 8PCh. 37 - Prob. 9PCh. 37 - Prob. 10P
Ch. 37 - Prob. 11PCh. 37 - Prob. 12PCh. 37 - Prob. 13PCh. 37 - Prob. 14PCh. 37 - Prob. 15PCh. 37 - Prob. 16PCh. 37 - Prob. 17PCh. 37 - Prob. 18PCh. 37 - Prob. 19PCh. 37 - Prob. 20PCh. 37 - Prob. 21PCh. 37 - Prob. 22PCh. 37 - Prob. 23PCh. 37 - Prob. 24PCh. 37 - Prob. 25PCh. 37 - Prob. 26PCh. 37 - Prob. 27PCh. 37 - Prob. 28PCh. 37 - Prob. 29PCh. 37 - Prob. 30PCh. 37 - Prob. 31PCh. 37 - Prob. 32PCh. 37 - Prob. 33PCh. 37 - Prob. 34PCh. 37 - Prob. 35PCh. 37 - Prob. 36PCh. 37 - Prob. 37PCh. 37 - Prob. 38PCh. 37 - Prob. 39PCh. 37 - Prob. 40PCh. 37 - Prob. 41PCh. 37 - Prob. 42PCh. 37 - Prob. 43P
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- The Madelung constant for the NaCl structure may be found by summing an infinite alternating series of terms giving the electrostatic potential energy between an Na+ ion and its 6 nearest Cl neighbors, its 12 next-nearest N+ neighbors, and so on (see Fig. 12.1a). (a) From this expression, show that the first three terms of the infinite series for the Madelung constant for the NaCl structure yield = 2.13. (b) Does this infinite series converge rapidly? Calculate the fourth term as a check.arrow_forwardCompare the effective force constant for the CO molecule deduced here with that of an ordinary laboratory spring that stretches 0.5 m when a 1.0 kg mass is suspended from it.arrow_forwardAssume that the H2 molecule behaves exactly like a harmonic oscillator with a force constant of 573N/m. (a) Find the energy (in eV) of its ground and first excited vibrational states. (b) Find the vibrational quantum number that approximately corresponds to its 4.5-eV dissociation energy.arrow_forward
- Suppose that the wavenumber of the J = 1 ← 0 rotational transition of 1H81Br considered as a rigid rotor was measured to be 18.20 cm-1, what is (a) the moment of inertia of the molecule? _____________kg-m2 (b) the bond length? ________________Angstroms (Given the isotopic masses:(m(79Br) = 78.9183 amu, m(81Br) = 80.9163 amuarrow_forwardWrite the electron configuration for Fl (atomic number 114). How many valence electrons does it have?arrow_forwardFind the amplitude of the ground-state vibrations of the CO molecule. What percentage of the bond length is this? Assume the molecule vibrates like a harmonic oscillator.arrow_forward
- When an OH molecule undergoes a transition from the n = 0 to the n = 1 vibrational level, its internal vibrational energy increases by 0.463 eV. Calculate the frequency of vibration and the force constant for the interatomic force. (The mass of an oxygen atom is 2.66 * 10-26 kg, and the mass of a hydrogen atom is 1.67 * 10-27 kg.)arrow_forwardThe equilibrium dissociation energy of O2 is De = 4.314 ev. The basic vibration frequency of O2 is f = 1620.0 cm -1. So how much energy is actually needed to dissociate O2 molecules at n = 3 vibrational level? Give your answer in EV.arrow_forwardThe first three absorption lines in the pure rotational spectrum of gaseous 12C16O are found to have the frequencies 1.15 × 1011, 2.30 × 1011, and 3.46 × 1011 s21. Calculate:(a) The moment of inertia I of CO (in kg m2)(b) The energies of the J 5 1, J 5 2, and J 5 3 rotational levels of CO, measured from the J 5 0 state (in joules)(c) The CUO bond length (in angstroms)arrow_forward
- How could you make compensated silicon that has twice as many acceptors as donors?arrow_forwardThe figure above shows the absorption spectrum of the molecule HBr. Following the basic procedures of Section 9.6, find:(a) the energy of the “missing” transition;(b) the effective force constant k;(c) the rotational spacing 2B. Estimate the value of the rotational spacing expected for HBr and compare with the value deduced from the spectrum. Why are there only single lines and not double lines as in the case of HCl?arrow_forwardA CO molecule is initially in the n = 2 vibrational level. If this molecule loses both vibrational and rotational energy and emits a photon, what are the photon wavelength and frequency if the initial angular momentum quantum number is l = 3?arrow_forward
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