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Determine the value of the derivative
(Hint: See exercise
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Physical Chemistry
- Predict whether each reaction is reactant-favored or product-favored at 298 K and 1 bar, and calculate the minimum work that would have to be done to force it to occur, or the maximum work that could be done by the reaction. (a) 2 CO2(g) 2 CO(g) + O2(g) (b) 4 Fe(s) + 3 O2(g) 2 Fe2O3(s)arrow_forwardWhich of the following quantities can be taken to be independent of temperature? independent of pressure? (a) H for a reaction (b) S for a reaction (c) G for a reaction (d) S for a substancearrow_forwardUse the molar constant volume heat capacities for gases given in Topic 4C (as multiples for R) to estimate the change in reaction enthalpy of N2 (g) + 3 H2 (g) ---> 2 NH3 (g) when the temperture is increased from 300. K to 500. K. Ignore the vibrational contributions to heat capacity. Is the reaction more or less exothermic at the higher temperature? Atoms Linear Molecules Nonlinear Molecules Cv,m 3/2 R 5/2 R 3 R Cp,m 5/2 R 7/2 R 4 Rarrow_forward
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- In the expression, S = k ln W, W is called the number of microstates. Explain clearly the meaning of the word "microstate", and why a system under a given set of conditions normally has many microstates.arrow_forwardGiven ΔHrxn∘= −135 kJ, ΔS∘rxn= −263 J/K, & T= 299 K, will the reaction be spontaneous?arrow_forwardUse the data given in the table to calculate the value of Δ?∘rxn at 25∘ C for the reaction described by the equation A+B↽−−⇀C Compound Δ?∘f (kJ/mol) A +387.7 B –660.6 C +402.0arrow_forward
- https://chem.libretexts.org/Ancillary_Materials/Reference/Reference_Tables/Thermodynamics_Tables/T1%3A_Standard_Thermodynamic_Quantitiesarrow_forwardIn the calibration step of a thermochemistry experiment, a current of 124 mA, from a 24.0 V source was allowed to flow through the electrical heater for 219 s and was found to result in an increase in the temperature of the calorimeter and its contents of +1.39 K. Given that the energy supplied by an electrical circuit is the voltage multiplied by the current, multiplied by the time, what is the heat capacity of the calorimeter and its contents? Answer: 469 J K-1arrow_forwardProvide the formal definition of enthalpy and explain all symbols used in it. Explain how the change in enthalpy is related to certain thermodynamic property (other than Gibbs energy).arrow_forward
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