Chemical Principles: The Quest for Insight
7th Edition
ISBN: 9781464183959
Author: Peter Atkins, Loretta Jones, Leroy Laverman
Publisher: W. H. Freeman
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Question
Chapter 4, Problem 4F.8AST
Interpretation Introduction
Interpretation:
The standard entropy of fusion ofmercury at its normal freezing point has to be determined.
Concept Introduction:
The degree of randomness in a system is the measured in terms of entropy. Higher the entropy greater will be the disorder in the system. The mathematical expression for the calculation of entropy of fusion is shown below.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Calculate the standard reaction entropy at 298 K when 1 mol NH3(g) is formed from its elements in their reference states.
Provide the formal definition of enthalpy and explain all symbols used in it. Explain how the change in enthalpy is related to certain thermodynamic property (other than Gibbs energy).
What is the absolute entropy of chlorine gas at 300 K using Cp = 0.48 J/ g.K?
Chapter 4 Solutions
Chemical Principles: The Quest for Insight
Ch. 4 - Prob. 4A.1ASTCh. 4 - Prob. 4A.1BSTCh. 4 - Prob. 4A.2ASTCh. 4 - Prob. 4A.2BSTCh. 4 - Prob. 4A.3ASTCh. 4 - Prob. 4A.3BSTCh. 4 - Prob. 4A.4ASTCh. 4 - Prob. 4A.4BSTCh. 4 - Prob. 4A.1ECh. 4 - Prob. 4A.2E
Ch. 4 - Prob. 4A.3ECh. 4 - Prob. 4A.4ECh. 4 - Prob. 4A.5ECh. 4 - Prob. 4A.6ECh. 4 - Prob. 4A.7ECh. 4 - Prob. 4A.8ECh. 4 - Prob. 4A.9ECh. 4 - Prob. 4A.10ECh. 4 - Prob. 4A.11ECh. 4 - Prob. 4A.12ECh. 4 - Prob. 4A.13ECh. 4 - Prob. 4A.14ECh. 4 - Prob. 4B.1ASTCh. 4 - Prob. 4B.1BSTCh. 4 - Prob. 4B.2ASTCh. 4 - Prob. 4B.2BSTCh. 4 - Prob. 4B.3ASTCh. 4 - Prob. 4B.3BSTCh. 4 - Prob. 4B.1ECh. 4 - Prob. 4B.2ECh. 4 - Prob. 4B.3ECh. 4 - Prob. 4B.4ECh. 4 - Prob. 4B.5ECh. 4 - Prob. 4B.6ECh. 4 - Prob. 4B.7ECh. 4 - Prob. 4B.8ECh. 4 - Prob. 4B.9ECh. 4 - Prob. 4B.10ECh. 4 - Prob. 4B.11ECh. 4 - Prob. 4B.12ECh. 4 - Prob. 4B.13ECh. 4 - Prob. 4B.14ECh. 4 - Prob. 4B.15ECh. 4 - Prob. 4B.16ECh. 4 - Prob. 4C.1ASTCh. 4 - Prob. 4C.1BSTCh. 4 - Prob. 4C.2ASTCh. 4 - Prob. 4C.2BSTCh. 4 - Prob. 4C.3ASTCh. 4 - Prob. 4C.3BSTCh. 4 - Prob. 4C.4ASTCh. 4 - Prob. 4C.4BSTCh. 4 - Prob. 4C.1ECh. 4 - Prob. 4C.2ECh. 4 - Prob. 4C.3ECh. 4 - Prob. 4C.4ECh. 4 - Prob. 4C.5ECh. 4 - Prob. 4C.6ECh. 4 - Prob. 4C.7ECh. 4 - Prob. 4C.8ECh. 4 - Prob. 4C.9ECh. 4 - Prob. 4C.10ECh. 4 - Prob. 4C.11ECh. 4 - Prob. 4C.12ECh. 4 - Prob. 4C.13ECh. 4 - Prob. 4C.14ECh. 4 - Prob. 4C.15ECh. 4 - Prob. 4C.16ECh. 4 - Prob. 4D.1ASTCh. 4 - Prob. 4D.1BSTCh. 4 - Prob. 4D.2ASTCh. 4 - Prob. 4D.2BSTCh. 4 - Prob. 4D.3ASTCh. 4 - Prob. 4D.3BSTCh. 4 - Prob. 4D.4ASTCh. 4 - Prob. 4D.4BSTCh. 4 - Prob. 4D.5ASTCh. 4 - Prob. 4D.5BSTCh. 4 - Prob. 4D.6ASTCh. 4 - Prob. 4D.6BSTCh. 4 - Prob. 4D.7ASTCh. 4 - Prob. 4D.7BSTCh. 4 - Prob. 4D.1ECh. 4 - Prob. 4D.2ECh. 4 - Prob. 4D.3ECh. 4 - Prob. 4D.4ECh. 4 - Prob. 4D.5ECh. 4 - Prob. 4D.6ECh. 4 - Prob. 4D.7ECh. 4 - Prob. 4D.8ECh. 4 - Prob. 4D.10ECh. 4 - Prob. 4D.11ECh. 4 - Prob. 4D.13ECh. 4 - Prob. 4D.14ECh. 4 - Prob. 4D.15ECh. 4 - Prob. 4D.16ECh. 4 - Prob. 4D.17ECh. 4 - Prob. 4D.18ECh. 4 - Prob. 4D.19ECh. 4 - Prob. 4D.20ECh. 4 - Prob. 4D.21ECh. 4 - Prob. 4D.22ECh. 4 - Prob. 4D.23ECh. 4 - Prob. 4D.24ECh. 4 - Prob. 4D.25ECh. 4 - Prob. 4D.26ECh. 4 - Prob. 4D.29ECh. 4 - Prob. 4D.30ECh. 4 - Prob. 4E.1ASTCh. 4 - Prob. 4E.1BSTCh. 4 - Prob. 4E.2ASTCh. 4 - Prob. 4E.2BSTCh. 4 - Prob. 4E.5ECh. 4 - Prob. 4E.6ECh. 4 - Prob. 4E.7ECh. 4 - Prob. 4E.8ECh. 4 - Prob. 4E.9ECh. 4 - Prob. 4E.10ECh. 4 - Prob. 4F.1ASTCh. 4 - Prob. 4F.1BSTCh. 4 - Prob. 4F.2ASTCh. 4 - Prob. 4F.2BSTCh. 4 - Prob. 4F.3ASTCh. 4 - Prob. 4F.3BSTCh. 4 - Prob. 4F.4ASTCh. 4 - Prob. 4F.4BSTCh. 4 - Prob. 4F.5ASTCh. 4 - Prob. 4F.5BSTCh. 4 - Prob. 4F.6ASTCh. 4 - Prob. 4F.6BSTCh. 4 - Prob. 4F.7ASTCh. 4 - Prob. 4F.7BSTCh. 4 - Prob. 4F.8ASTCh. 4 - Prob. 4F.8BSTCh. 4 - Prob. 4F.9ASTCh. 4 - Prob. 4F.9BSTCh. 4 - Prob. 4F.1ECh. 4 - Prob. 4F.2ECh. 4 - Prob. 4F.3ECh. 4 - Prob. 4F.4ECh. 4 - Prob. 4F.5ECh. 4 - Prob. 4F.6ECh. 4 - Prob. 4F.7ECh. 4 - Prob. 4F.9ECh. 4 - Prob. 4F.10ECh. 4 - Prob. 4F.11ECh. 4 - Prob. 4F.12ECh. 4 - Prob. 4F.13ECh. 4 - Prob. 4F.14ECh. 4 - Prob. 4F.15ECh. 4 - Prob. 4F.16ECh. 4 - Prob. 4F.17ECh. 4 - Prob. 4G.1ASTCh. 4 - Prob. 4G.1BSTCh. 4 - Prob. 4G.2ASTCh. 4 - Prob. 4G.2BSTCh. 4 - Prob. 4G.1ECh. 4 - Prob. 4G.2ECh. 4 - Prob. 4G.3ECh. 4 - Prob. 4G.5ECh. 4 - Prob. 4G.7ECh. 4 - Prob. 4G.8ECh. 4 - Prob. 4G.9ECh. 4 - Prob. 4G.10ECh. 4 - Prob. 4H.1ASTCh. 4 - Prob. 4H.1BSTCh. 4 - Prob. 4H.2ASTCh. 4 - Prob. 4H.2BSTCh. 4 - Prob. 4H.1ECh. 4 - Prob. 4H.2ECh. 4 - Prob. 4H.3ECh. 4 - Prob. 4H.4ECh. 4 - Prob. 4H.5ECh. 4 - Prob. 4H.6ECh. 4 - Prob. 4H.7ECh. 4 - Prob. 4H.8ECh. 4 - Prob. 4H.9ECh. 4 - Prob. 4H.10ECh. 4 - Prob. 4H.11ECh. 4 - Prob. 4I.1ASTCh. 4 - Prob. 4I.1BSTCh. 4 - Prob. 4I.2ASTCh. 4 - Prob. 4I.2BSTCh. 4 - Prob. 4I.3ASTCh. 4 - Prob. 4I.3BSTCh. 4 - Prob. 4I.4ASTCh. 4 - Prob. 4I.4BSTCh. 4 - Prob. 4I.1ECh. 4 - Prob. 4I.2ECh. 4 - Prob. 4I.3ECh. 4 - Prob. 4I.4ECh. 4 - Prob. 4I.5ECh. 4 - Prob. 4I.6ECh. 4 - Prob. 4I.7ECh. 4 - Prob. 4I.8ECh. 4 - Prob. 4I.9ECh. 4 - Prob. 4I.10ECh. 4 - Prob. 4I.11ECh. 4 - Prob. 4I.12ECh. 4 - Prob. 4J.1ASTCh. 4 - Prob. 4J.1BSTCh. 4 - Prob. 4J.2ASTCh. 4 - Prob. 4J.2BSTCh. 4 - Prob. 4J.3ASTCh. 4 - Prob. 4J.3BSTCh. 4 - Prob. 4J.4ASTCh. 4 - Prob. 4J.4BSTCh. 4 - Prob. 4J.5ASTCh. 4 - Prob. 4J.5BSTCh. 4 - Prob. 4J.6ASTCh. 4 - Prob. 4J.6BSTCh. 4 - Prob. 4J.1ECh. 4 - Prob. 4J.2ECh. 4 - Prob. 4J.3ECh. 4 - Prob. 4J.4ECh. 4 - Prob. 4J.5ECh. 4 - Prob. 4J.6ECh. 4 - Prob. 4J.7ECh. 4 - Prob. 4J.8ECh. 4 - Prob. 4J.9ECh. 4 - Prob. 4J.11ECh. 4 - Prob. 4J.12ECh. 4 - Prob. 4J.13ECh. 4 - Prob. 4J.14ECh. 4 - Prob. 4J.15ECh. 4 - Prob. 4J.16ECh. 4 - Prob. 4.8ECh. 4 - Prob. 4.14ECh. 4 - Prob. 4.16ECh. 4 - Prob. 4.19ECh. 4 - Prob. 4.20ECh. 4 - Prob. 4.21ECh. 4 - Prob. 4.23ECh. 4 - Prob. 4.25ECh. 4 - Prob. 4.27ECh. 4 - Prob. 4.28ECh. 4 - Prob. 4.29ECh. 4 - Prob. 4.30ECh. 4 - Prob. 4.31ECh. 4 - Prob. 4.32ECh. 4 - Prob. 4.33ECh. 4 - Prob. 4.34ECh. 4 - Prob. 4.35ECh. 4 - Prob. 4.36ECh. 4 - Prob. 4.37ECh. 4 - Prob. 4.39ECh. 4 - Prob. 4.40ECh. 4 - Prob. 4.41ECh. 4 - Prob. 4.45ECh. 4 - Prob. 4.46ECh. 4 - Prob. 4.48ECh. 4 - Prob. 4.49ECh. 4 - Prob. 4.53ECh. 4 - Prob. 4.57ECh. 4 - Prob. 4.59E
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- What is the sign of the standard Gibbs free-energy change at low temperatures and at high temperatures for the explosive decomposition of TNT? Use your knowledge of TNT and the chemical equation, particularly the phases, to answer this question. (Thermodynamic data for TNT are not in Appendix G.) 2C7H5N3O6(s) 3N2(g) + 5H2O() + 7C(s) + 7CO(g)arrow_forwardCalculate the standard Gibbs free-energy change when SO3 forms from SO2 and O2 at 298 K. Why is sulfur trioxide an important substance to study? (Hint: What happens when it combines with water?)arrow_forwardActually, the carbon in CO2(g) is thermodynamically unstable with respect to the carbon in calcium carbonate(limestone). Verify this by determining the standardGibbs free energy change for the reaction of lime,CaO(s), with CO2(g) to make CaCO3(s).arrow_forward
- Consider planet Earth as a thermodynamic system. Is Earth thermodynamically or kinetically stable? Discuss your choice, providing as many arguments as you can tosupport it.arrow_forwardPredict whether each reaction is reactant-favored or product-favored at 298 K and 1 bar, and calculate the minimum work that would have to be done to force it to occur, or the maximum work that could be done by the reaction. (a) 2 CO2(g) 2 CO(g) + O2(g) (b) 4 Fe(s) + 3 O2(g) 2 Fe2O3(s)arrow_forwardDescribe how the standard entropy of hydrogen gas at 25C can be obtained from heat measurements.arrow_forward
- Use data from Appendix D to calculate the standardentropy change at 25°C for the reaction CH3COOH(g)+NH3(g)CH3NH2(g)+CO2(g)+H2(g) Suppose that 1.00 mol each of solid acetamide, CH3CONH2(s), and water, H2O(l), react to give thesame products. Will the standard entropy change belarger or smaller than that calculated for the reactionin part (a)?arrow_forwardDetermine the entropy change for the combustion of liquid ethanol, C2H5OH, under the standard conditions to give gaseous carbon dioxide and liquid water.arrow_forwardAnother step in the metabolism of glucose, which occurs after the formation of glucose6-phosphate, is the conversion of fructose6-phosphate to fructose1,6-bisphosphate(bis meanstwo): Fructose6-phosphate(aq) + H2PO4(aq) fructose l,6-bisphosphate(aq) + H2O() + H+(aq) (a) This reaction has a Gibbs free energy change of +16.7 kJ/mol of fructose6-phosphate. Is it endergonic or exergonic? (b) Write the equation for the formation of 1 mol ADP fromATR for which rG = 30.5 kJ/mol. (c) Couple these two reactions to get an exergonic process;write its overall chemical equation, and calculate theGibbs free energy change.arrow_forward
- Billions of pounds of acetic acid are made each year, much of it by the reaction of methanol with carbon monoxide. (AssumeT= 298 K.) CH3OH() + CO(g) CH3COOH() (a) By calculating the standard Gibbs free energy change, rG, for this reaction, show that it is product-favored. (b) Determine the standard Gibbs free energy change, rG,for the reaction of acetic acid with oxygen to form gaseous carbon dioxide and liquid water. (c) Based on this result, is acetic acid thermodynamicallystable compared with CO2(g) and H2O()? (d) Is acetic acid kinetically stable compared with CO2(g)and H2O()?arrow_forwarda Calculate K1, at 25C for sulfurous acid: H2SO3(aq)H+(aq)+HSO3(aq) b Which thermodynamic factor is the most significant in accounting for the fact that sulfurous acid is a weak acid? Why?arrow_forwardWhat is the sign of the standard Gibbs free-energy change at low temperatures and at high temperatures for the synthesis of ammonia? 3H2(g) + N2(g) 2NH3(g)arrow_forward
arrow_back_ios
arrow_forward_ios
Recommended textbooks for you
General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStax
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY