Chemical Principles: The Quest for Insight
7th Edition
ISBN: 9781464183959
Author: Peter Atkins, Loretta Jones, Leroy Laverman
Publisher: W. H. Freeman
expand_more
expand_more
format_list_bulleted
Question
Chapter 4, Problem 4J.3E
(a)
Interpretation Introduction
Interpretation:
The molar Gibbs free energy for the vaporization of liquid ammonia at
Concept Introduction:
The importance of Gibbs energy is that it gives information about the spontaneity of the reaction or a process at constant temperature and pressure. A compound is considered
(b)
Interpretation Introduction
Interpretation:
The molar Gibbs free energy for the vaporization of liquid ammonia at
Concept Introduction:
Same as part (a).
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionChapter 4 Solutions
Chemical Principles: The Quest for Insight
Ch. 4 - Prob. 4A.1ASTCh. 4 - Prob. 4A.1BSTCh. 4 - Prob. 4A.2ASTCh. 4 - Prob. 4A.2BSTCh. 4 - Prob. 4A.3ASTCh. 4 - Prob. 4A.3BSTCh. 4 - Prob. 4A.4ASTCh. 4 - Prob. 4A.4BSTCh. 4 - Prob. 4A.1ECh. 4 - Prob. 4A.2E
Ch. 4 - Prob. 4A.3ECh. 4 - Prob. 4A.4ECh. 4 - Prob. 4A.5ECh. 4 - Prob. 4A.6ECh. 4 - Prob. 4A.7ECh. 4 - Prob. 4A.8ECh. 4 - Prob. 4A.9ECh. 4 - Prob. 4A.10ECh. 4 - Prob. 4A.11ECh. 4 - Prob. 4A.12ECh. 4 - Prob. 4A.13ECh. 4 - Prob. 4A.14ECh. 4 - Prob. 4B.1ASTCh. 4 - Prob. 4B.1BSTCh. 4 - Prob. 4B.2ASTCh. 4 - Prob. 4B.2BSTCh. 4 - Prob. 4B.3ASTCh. 4 - Prob. 4B.3BSTCh. 4 - Prob. 4B.1ECh. 4 - Prob. 4B.2ECh. 4 - Prob. 4B.3ECh. 4 - Prob. 4B.4ECh. 4 - Prob. 4B.5ECh. 4 - Prob. 4B.6ECh. 4 - Prob. 4B.7ECh. 4 - Prob. 4B.8ECh. 4 - Prob. 4B.9ECh. 4 - Prob. 4B.10ECh. 4 - Prob. 4B.11ECh. 4 - Prob. 4B.12ECh. 4 - Prob. 4B.13ECh. 4 - Prob. 4B.14ECh. 4 - Prob. 4B.15ECh. 4 - Prob. 4B.16ECh. 4 - Prob. 4C.1ASTCh. 4 - Prob. 4C.1BSTCh. 4 - Prob. 4C.2ASTCh. 4 - Prob. 4C.2BSTCh. 4 - Prob. 4C.3ASTCh. 4 - Prob. 4C.3BSTCh. 4 - Prob. 4C.4ASTCh. 4 - Prob. 4C.4BSTCh. 4 - Prob. 4C.1ECh. 4 - Prob. 4C.2ECh. 4 - Prob. 4C.3ECh. 4 - Prob. 4C.4ECh. 4 - Prob. 4C.5ECh. 4 - Prob. 4C.6ECh. 4 - Prob. 4C.7ECh. 4 - Prob. 4C.8ECh. 4 - Prob. 4C.9ECh. 4 - Prob. 4C.10ECh. 4 - Prob. 4C.11ECh. 4 - Prob. 4C.12ECh. 4 - Prob. 4C.13ECh. 4 - Prob. 4C.14ECh. 4 - Prob. 4C.15ECh. 4 - Prob. 4C.16ECh. 4 - Prob. 4D.1ASTCh. 4 - Prob. 4D.1BSTCh. 4 - Prob. 4D.2ASTCh. 4 - Prob. 4D.2BSTCh. 4 - Prob. 4D.3ASTCh. 4 - Prob. 4D.3BSTCh. 4 - Prob. 4D.4ASTCh. 4 - Prob. 4D.4BSTCh. 4 - Prob. 4D.5ASTCh. 4 - Prob. 4D.5BSTCh. 4 - Prob. 4D.6ASTCh. 4 - Prob. 4D.6BSTCh. 4 - Prob. 4D.7ASTCh. 4 - Prob. 4D.7BSTCh. 4 - Prob. 4D.1ECh. 4 - Prob. 4D.2ECh. 4 - Prob. 4D.3ECh. 4 - Prob. 4D.4ECh. 4 - Prob. 4D.5ECh. 4 - Prob. 4D.6ECh. 4 - Prob. 4D.7ECh. 4 - Prob. 4D.8ECh. 4 - Prob. 4D.10ECh. 4 - Prob. 4D.11ECh. 4 - Prob. 4D.13ECh. 4 - Prob. 4D.14ECh. 4 - Prob. 4D.15ECh. 4 - Prob. 4D.16ECh. 4 - Prob. 4D.17ECh. 4 - Prob. 4D.18ECh. 4 - Prob. 4D.19ECh. 4 - Prob. 4D.20ECh. 4 - Prob. 4D.21ECh. 4 - Prob. 4D.22ECh. 4 - Prob. 4D.23ECh. 4 - Prob. 4D.24ECh. 4 - Prob. 4D.25ECh. 4 - Prob. 4D.26ECh. 4 - Prob. 4D.29ECh. 4 - Prob. 4D.30ECh. 4 - Prob. 4E.1ASTCh. 4 - Prob. 4E.1BSTCh. 4 - Prob. 4E.2ASTCh. 4 - Prob. 4E.2BSTCh. 4 - Prob. 4E.5ECh. 4 - Prob. 4E.6ECh. 4 - Prob. 4E.7ECh. 4 - Prob. 4E.8ECh. 4 - Prob. 4E.9ECh. 4 - Prob. 4E.10ECh. 4 - Prob. 4F.1ASTCh. 4 - Prob. 4F.1BSTCh. 4 - Prob. 4F.2ASTCh. 4 - Prob. 4F.2BSTCh. 4 - Prob. 4F.3ASTCh. 4 - Prob. 4F.3BSTCh. 4 - Prob. 4F.4ASTCh. 4 - Prob. 4F.4BSTCh. 4 - Prob. 4F.5ASTCh. 4 - Prob. 4F.5BSTCh. 4 - Prob. 4F.6ASTCh. 4 - Prob. 4F.6BSTCh. 4 - Prob. 4F.7ASTCh. 4 - Prob. 4F.7BSTCh. 4 - Prob. 4F.8ASTCh. 4 - Prob. 4F.8BSTCh. 4 - Prob. 4F.9ASTCh. 4 - Prob. 4F.9BSTCh. 4 - Prob. 4F.1ECh. 4 - Prob. 4F.2ECh. 4 - Prob. 4F.3ECh. 4 - Prob. 4F.4ECh. 4 - Prob. 4F.5ECh. 4 - Prob. 4F.6ECh. 4 - Prob. 4F.7ECh. 4 - Prob. 4F.9ECh. 4 - Prob. 4F.10ECh. 4 - Prob. 4F.11ECh. 4 - Prob. 4F.12ECh. 4 - Prob. 4F.13ECh. 4 - Prob. 4F.14ECh. 4 - Prob. 4F.15ECh. 4 - Prob. 4F.16ECh. 4 - Prob. 4F.17ECh. 4 - Prob. 4G.1ASTCh. 4 - Prob. 4G.1BSTCh. 4 - Prob. 4G.2ASTCh. 4 - Prob. 4G.2BSTCh. 4 - Prob. 4G.1ECh. 4 - Prob. 4G.2ECh. 4 - Prob. 4G.3ECh. 4 - Prob. 4G.5ECh. 4 - Prob. 4G.7ECh. 4 - Prob. 4G.8ECh. 4 - Prob. 4G.9ECh. 4 - Prob. 4G.10ECh. 4 - Prob. 4H.1ASTCh. 4 - Prob. 4H.1BSTCh. 4 - Prob. 4H.2ASTCh. 4 - Prob. 4H.2BSTCh. 4 - Prob. 4H.1ECh. 4 - Prob. 4H.2ECh. 4 - Prob. 4H.3ECh. 4 - Prob. 4H.4ECh. 4 - Prob. 4H.5ECh. 4 - Prob. 4H.6ECh. 4 - Prob. 4H.7ECh. 4 - Prob. 4H.8ECh. 4 - Prob. 4H.9ECh. 4 - Prob. 4H.10ECh. 4 - Prob. 4H.11ECh. 4 - Prob. 4I.1ASTCh. 4 - Prob. 4I.1BSTCh. 4 - Prob. 4I.2ASTCh. 4 - Prob. 4I.2BSTCh. 4 - Prob. 4I.3ASTCh. 4 - Prob. 4I.3BSTCh. 4 - Prob. 4I.4ASTCh. 4 - Prob. 4I.4BSTCh. 4 - Prob. 4I.1ECh. 4 - Prob. 4I.2ECh. 4 - Prob. 4I.3ECh. 4 - Prob. 4I.4ECh. 4 - Prob. 4I.5ECh. 4 - Prob. 4I.6ECh. 4 - Prob. 4I.7ECh. 4 - Prob. 4I.8ECh. 4 - Prob. 4I.9ECh. 4 - Prob. 4I.10ECh. 4 - Prob. 4I.11ECh. 4 - Prob. 4I.12ECh. 4 - Prob. 4J.1ASTCh. 4 - Prob. 4J.1BSTCh. 4 - Prob. 4J.2ASTCh. 4 - Prob. 4J.2BSTCh. 4 - Prob. 4J.3ASTCh. 4 - Prob. 4J.3BSTCh. 4 - Prob. 4J.4ASTCh. 4 - Prob. 4J.4BSTCh. 4 - Prob. 4J.5ASTCh. 4 - Prob. 4J.5BSTCh. 4 - Prob. 4J.6ASTCh. 4 - Prob. 4J.6BSTCh. 4 - Prob. 4J.1ECh. 4 - Prob. 4J.2ECh. 4 - Prob. 4J.3ECh. 4 - Prob. 4J.4ECh. 4 - Prob. 4J.5ECh. 4 - Prob. 4J.6ECh. 4 - Prob. 4J.7ECh. 4 - Prob. 4J.8ECh. 4 - Prob. 4J.9ECh. 4 - Prob. 4J.11ECh. 4 - Prob. 4J.12ECh. 4 - Prob. 4J.13ECh. 4 - Prob. 4J.14ECh. 4 - Prob. 4J.15ECh. 4 - Prob. 4J.16ECh. 4 - Prob. 4.8ECh. 4 - Prob. 4.14ECh. 4 - Prob. 4.16ECh. 4 - Prob. 4.19ECh. 4 - Prob. 4.20ECh. 4 - Prob. 4.21ECh. 4 - Prob. 4.23ECh. 4 - Prob. 4.25ECh. 4 - Prob. 4.27ECh. 4 - Prob. 4.28ECh. 4 - Prob. 4.29ECh. 4 - Prob. 4.30ECh. 4 - Prob. 4.31ECh. 4 - Prob. 4.32ECh. 4 - Prob. 4.33ECh. 4 - Prob. 4.34ECh. 4 - Prob. 4.35ECh. 4 - Prob. 4.36ECh. 4 - Prob. 4.37ECh. 4 - Prob. 4.39ECh. 4 - Prob. 4.40ECh. 4 - Prob. 4.41ECh. 4 - Prob. 4.45ECh. 4 - Prob. 4.46ECh. 4 - Prob. 4.48ECh. 4 - Prob. 4.49ECh. 4 - Prob. 4.53ECh. 4 - Prob. 4.57ECh. 4 - Prob. 4.59E
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Calculate the standard Gibbs free-energy change when SO3 forms from SO2 and O2 at 298 K. Why is sulfur trioxide an important substance to study? (Hint: What happens when it combines with water?)arrow_forwardWhat is the sign of the standard Gibbs free-energy change at low temperatures and at high temperatures for the explosive decomposition of TNT? Use your knowledge of TNT and the chemical equation, particularly the phases, to answer this question. (Thermodynamic data for TNT are not in Appendix G.) 2C7H5N3O6(s) 3N2(g) + 5H2O() + 7C(s) + 7CO(g)arrow_forwardBillions of pounds of acetic acid are made each year, much of it by the reaction of methanol with carbon monoxide. (AssumeT= 298 K.) CH3OH() + CO(g) CH3COOH() (a) By calculating the standard Gibbs free energy change, rG, for this reaction, show that it is product-favored. (b) Determine the standard Gibbs free energy change, rG,for the reaction of acetic acid with oxygen to form gaseous carbon dioxide and liquid water. (c) Based on this result, is acetic acid thermodynamicallystable compared with CO2(g) and H2O()? (d) Is acetic acid kinetically stable compared with CO2(g)and H2O()?arrow_forward
- Another step in the metabolism of glucose, which occurs after the formation of glucose6-phosphate, is the conversion of fructose6-phosphate to fructose1,6-bisphosphate(bis meanstwo): Fructose6-phosphate(aq) + H2PO4(aq) fructose l,6-bisphosphate(aq) + H2O() + H+(aq) (a) This reaction has a Gibbs free energy change of +16.7 kJ/mol of fructose6-phosphate. Is it endergonic or exergonic? (b) Write the equation for the formation of 1 mol ADP fromATR for which rG = 30.5 kJ/mol. (c) Couple these two reactions to get an exergonic process;write its overall chemical equation, and calculate theGibbs free energy change.arrow_forwardWhich of the following quantities can be taken to be independent of temperature? independent of pressure? (a) H for a reaction (b) S for a reaction (c) G for a reaction (d) S for a substancearrow_forwardWhat is the sign of the standard Gibbs free-energy change at low temperatures and at high temperatures for the synthesis of ammonia? 3H2(g) + N2(g) 2NH3(g)arrow_forward
- Consider planet Earth as a thermodynamic system. Is Earth thermodynamically or kinetically stable? Discuss your choice, providing as many arguments as you can tosupport it.arrow_forwardConsider the reaction NH4+(aq) H+(aq)+NH3(aq) Use G f for NH3(aq) at 25C=26.7 kJ/mol and the appropriate tables to calculate (a) G at 25C (b) Ka at 25Carrow_forwardUse data from Appendix D to calculate the standardentropy change at 25°C for the reaction CH3COOH(g)+NH3(g)CH3NH2(g)+CO2(g)+H2(g) Suppose that 1.00 mol each of solid acetamide, CH3CONH2(s), and water, H2O(l), react to give thesame products. Will the standard entropy change belarger or smaller than that calculated for the reactionin part (a)?arrow_forward
- What is the sign of the standard Gibbs free-energy change at low temperatures and at high temperatures for the combustion of acetaldehyde? CH3CHO(l)+52O2(g)2CO2+2H2O(l)arrow_forwardFrom data in Appendix J, estimate (a) the boiling point of titanium(IV) chloride. (b) the boiling point of carbon disulfide, CS2, which is a liquid at 25 C and 1 bar.arrow_forwardPredict whether each reaction is reactant-favored or product-favored at 298 K and 1 bar, and calculate the minimum work that would have to be done to force it to occur, or the maximum work that could be done by the reaction. (a) 2 CO2(g) 2 CO(g) + O2(g) (b) 4 Fe(s) + 3 O2(g) 2 Fe2O3(s)arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningPrinciples of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
- General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
The Laws of Thermodynamics, Entropy, and Gibbs Free Energy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=8N1BxHgsoOw;License: Standard YouTube License, CC-BY