Physics for Scientists and Engineers with Modern Physics
Physics for Scientists and Engineers with Modern Physics
10th Edition
ISBN: 9781337671729
Author: SERWAY
Publisher: Cengage
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Chapter 41, Problem 51CP

(a)

To determine

The frequency of emitted light.

(b)

To determine

How classical frequency is obtained from quantum frequency.

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(a) Use Bohr's model of the hydrogen atom to show that when the electron moves from the n state to the n – 1 state, the frequency of the emitted light is 2n – 1 e f = п?(п — 1)2 (b) Bohr's correspondence principle claims that quantum results should reduce to classical results in the limit of large quantum numbers. Show that as n→ 0, this expres- sion varies as 1/n³ and reduces to the classical frequency one expects the atom to emit. Suggestion: To calculate the classical frequency, note that the frequency of revolution is v/2Tr, where vis the speed of the electron and ris given by Equation 41.10.
(a) Using Bohr’s second postulate of quantization of orbital angular momentum show that the circumference of the electron in the n,h orbital state in hydrogen atom is n times the de-Broglie wavelength associated with it. (b) The electron in hydrogen atom is initially in the third excited state. What is the maximum number of spectral lines which can be emitted when it finally moves to the ground state?
The wave function for the Is state of an electron in the hydrogen atom is VIs(P) = e-p/ao where ao is the Bohr radius. The probability of finding the electron in a region W of R³ is equal to J, P(x, y, 2) dV where, in spherical coordinates, p(p) = |V1s(P)² Use integration in spherical coordinates to show that the probability of finding the electron at a distance greater than the Bohr radius is equal to 5/e = 0.677. (The Bohr radius is ao =5.3 x 10-1" m, but this value is not needed.)
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