Inorganic Chemistry
5th Edition
ISBN: 9780321811059
Author: Gary L. Miessler, Paul J. Fischer, Donald A. Tarr
Publisher: Prentice Hall
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Chapter 5, Problem 5.21P
The ion
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The existence of compounds of the noble gases was once a great surprise and stimulated a great deal of theoretical work. Sketch the molecular orbital energy level diagram for XeF and deduce its ground-state electron configurations. Is XeF likely to have a shorter or longer bond than XeF+?
The existence of compounds of the noble gases was once a great surprise and stimulated a great deal of theoretical work. Sketch the molecular orbital energy level diagram for XeF and deduce its ground state electron configurations. Is XeF likely to have a shorter bond length than XeF+?
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Chapter 5 Solutions
Inorganic Chemistry
Ch. 5.1 - Repeat the process in the preceding example for...Ch. 5.2 - Prob. 5.2ECh. 5.3 - Use a similar approach to the discussion of HF to...Ch. 5.4 - Sketch the energy levels and the molecular...Ch. 5.4 - Using the D2h character table shown, verify that...Ch. 5.4 - Using orbital potential energies, show that group...Ch. 5.4 - Prob. 5.7ECh. 5.4 - Prob. 5.8ECh. 5.4 - Prob. 5.9ECh. 5.4 - Use the projection operator method to derive...
Ch. 5.4 - Determine the types of hybrid orbitals that are...Ch. 5.4 - Determine the reducible representation for all the...Ch. 5 - Expand the list of orbitais considered in Figures...Ch. 5 - On the basis of molecular orbitals, predict the...Ch. 5 - On the basis of molecular orbitals, predict the...Ch. 5 - Compare the bonding in O22,O2 and O2 Include Lewis...Ch. 5 - Although the peroxide ion, O22 and the acetylide...Ch. 5 - High-resolution photoelectron spectroscopy has...Ch. 5 - a. Prepare a molecular orbital energy-level...Ch. 5 - a. Prepare a molecular orbital energy-level...Ch. 5 - NF is a known molecule a. Construct a molecular...Ch. 5 - The hypofluorite ion, OF can be observed only with...Ch. 5 - Prob. 5.11PCh. 5 - Although KrF+ and XeF+ have been studied, KrBr+...Ch. 5 - Prepare a molecular orbital energy level diagram...Ch. 5 - Methylene, CH2 plays an important role in many...Ch. 5 - Beryllium hydride, BeH2 is linear in the gas...Ch. 5 - In the gas phase, BeF2 forms linear monomeric...Ch. 5 - For the compound XeF2 do the following: a. Sketch...Ch. 5 - TaH5 has been predicted to have C4v symmetry, with...Ch. 5 - Describe the bonding in ozone, o3 on the basis of...Ch. 5 - Describe the bonding in SO3 by using group theory...Ch. 5 - The ion H3+ has been observed, but its structure...Ch. 5 - Use molecular orbital arguments to explain the...Ch. 5 - Prob. 5.23PCh. 5 - Prob. 5.24PCh. 5 - The isomenc ions NSO (thiazate) and SNO...Ch. 5 - Apply the projection operator method to derive the...Ch. 5 - Apply the projection operator method to derive the...Ch. 5 - A set of four group orbitals derived from four 3s...Ch. 5 - The projection operator method has applications...Ch. 5 - Although the cl2+ ion has not been isolated, it...Ch. 5 - BF3 is often described as a molecule in which...Ch. 5 - SF4 has C2v symmetry. Predict the possible...Ch. 5 - Consider a square pyramidal AB5 molecule. Using...Ch. 5 - Prob. 5.34PCh. 5 - For the molecule PCl5 : a. Using the character...Ch. 5 - Molecular modeling software is typically capable...Ch. 5 - Prob. 5.39PCh. 5 - Calculate and display the orbitals for the linear...Ch. 5 - Prob. 5.41PCh. 5 - Prob. 5.42PCh. 5 - Prob. 5.43PCh. 5 - Diborane, B2H6 , has the structure shown. a. Using...
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- Estimate the orbital energies to use in a calculation of the molecular orbitals of HBr. For data, see Tables 8B.4 and 8B.5. Take β = −1.00 eVarrow_forwardUsing the molecular orbital method and its qualitative explanations, justify that the bond formation energy in the B2 molecule is equal to -297 kJ mol-1, while in the ionized N2+ molecule it is equal to -842 kJ mol-1. Explain whether these molecules are diamagnetic or paramagnetic.arrow_forwardSketch the frontier orbitals of N2 and CO molecules and highlight the differences between them.arrow_forward
- Sketch the molecular orbital energy level diagram for XeF and deduce its ground-state electron configuration. Is XeF likely to have a shorter bond length than XeF+?arrow_forwardSketch the molecular orbital diagrams for B2 snd for F2. Using these diagrams, provide the bond order for each of the molecules and state if they are diamagnetic or paramagnetic. Describe the effect on the bond order and on the magnetic properties when B2 and F2 are reduced by 1 electron. Describe the effect on the bond order and on the magnetic properties when B2 and F2 are reduced by 2 electrons.arrow_forwardThe diatomic molecule OH exists in the gas phase. OH playsan important part in combustion reactions and is a reactiveoxidizing agent in polluted air. The bond length and bondenergy have been measured to be 97.06 pm and 424.7 kJ/mol,respectively. Assume that the OH molecule is analogous to theHF molecule discussed in the chapter and that the MOs resultfrom the overlap of a pz orbital from oxygen and the 1s orbitalof hydrogen (the OOH bond lies along the z axis).arrow_forward
- In reference to the following figure, which of the following statements is not true? a. An incorrect structure for BeH2 is predicted if 2s and 2p orbitals of beryllium are overlapped with the 1s orbitals of H. b. The bonds in the beryllium hydride molecule are formed by the overlap of 1s atomic orbitals on H and sp hybrid orbitals on Be. c. The two Be–H bonds are of not equal length and energy. d. Beryllium undergoes hybridization prior to bonding with hydrogen atoms. e. A correct structure for BeH2 is predicted if 2s and 2p orbitals of beryllium are overlapped with the 1s orbitals of H.arrow_forwardWhich hybridisation is presumed for P in PF5 and S in SF6? Give reasons for your answer ?arrow_forwardPrepare a molecular orbital diagram for SH-. Use only the valence electrons for your diagram. The H 1s orbital only interacts with the p orbitals of the S atom.arrow_forward
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