(a) Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomers, diastereomers, or identical is to be identified. Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R , S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

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Answer 1

Question

Chapter 5, Problem 5.60P

Interpretation Introduction

(a)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(b)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(c)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomer, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

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a) Draw Haworth projections of both - and -anomers of D-fructose. Indicate which carbon is the anomeric carbon.b) Sucrose is a disaccharide made up of a molecule of D-fructose and D-glucose. Draw the structure of sucrose clearly indicating the linkage between the two monosaccharides and its biological significance.c) Tollen’s reagent is a very mild oxidizing agent which normally oxidize aldehydes but not ketones. However, both glucose and fructose give positive results with Tollen’s reagent and are classified as reducing sugars. Explain how fructose can also give positive results with Tollen’s reagent (illustrate using structures).

The following trisaccharide derivative is important to human health.The A ring is ?-deoxy?

a. Draw the Fischer projection of monosaccharide A below. Hint: Place the carbonyl group close to the top of the drawing. Name monosaccharide A. b. Use the given template to draw the most stable conformation of monosaccharide A.

Answer 2

Question

Chapter 5, Problem 5.60P

Interpretation Introduction

(a)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(b)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(c)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomer, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

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Answer 3

Question

Chapter 5, Problem 5.60P

Interpretation Introduction

(a)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(b)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(c)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomer, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

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Answer 4

Question

Chapter 5, Problem 5.60P

Interpretation Introduction

(a)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(b)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(c)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomer, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

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Answer 5

Chapter 5, Problem 5.60P

Interpretation Introduction

(a)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(b)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(c)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomer, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 6

Chapter 5, Problem 5.60P

Interpretation Introduction

(a)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 7

Chapter 5, Problem 5.60P

Interpretation Introduction

(a)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 8

Interpretation Introduction

(b)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 9

Interpretation Introduction

(b)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 10

Interpretation Introduction

(c)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomer, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 11

Interpretation Introduction

(c)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomer, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 12

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Answer 13

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Answer 15

Ch. 5 - Prob. 5.1P Ch. 5 - Prob. 5.2P Ch. 5 - Draw the mirror image of each compound. Label each...Ch. 5 - Prob. 5.4P Ch. 5 - A molecule is achiral if it has a plane of...Ch. 5 - Problem 5.6 Locate the stereogenic centers in each...Ch. 5 - The facts in section 5.4A can be used to locate...Ch. 5 - Prob. 5.8P Ch. 5 - Prob. 5.9P Ch. 5 - Prob. 5.10P

Solution Summary: The author explains the relationship between simple sugar D-erythrose and the given compound as enantiomers, diastereomer, or identical.

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