Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Textbook Question
Chapter 6, Problem 6.10E
Use Hess’s law to prove that
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Chapter 6 Solutions
Physical Chemistry
Ch. 6 - Prob. 6.1ECh. 6 - Prob. 6.2ECh. 6 - Prob. 6.3ECh. 6 - Prob. 6.4ECh. 6 - Prob. 6.5ECh. 6 - Prob. 6.6ECh. 6 - Prob. 6.7ECh. 6 - Prob. 6.8ECh. 6 - 6.9. Identify and explain the sign on in equation...Ch. 6 - 6.10. Use Hess’s law to prove that .
Ch. 6 - 6.11. Calculate the amount of heat necessary to...Ch. 6 - Prob. 6.12ECh. 6 - Assume that the vapH of an evaporating liquid...Ch. 6 - 6.14. As a follow-up to the previous exercise,...Ch. 6 - Prob. 6.15ECh. 6 - 6.16. What is for isothermal conversion of liquid...Ch. 6 -
6.17. Estimate the melting point of nickel, Ni,...Ch. 6 -
6.18. Estimate the boiling point of platinum, Pt,...Ch. 6 - Prob. 6.19ECh. 6 - Prob. 6.20ECh. 6 - 6.21. What assumption is used in the integration...Ch. 6 - Prob. 6.22ECh. 6 - Sulfur, in its cyclic molecular form having the...Ch. 6 - Prob. 6.24ECh. 6 - 6.25. Phosphorus exists as several allotropes that...Ch. 6 - Prob. 6.26ECh. 6 - 6.27. What is higher for a substance: its normal...Ch. 6 - 6.28. Elemental gallium is another substance whose...Ch. 6 - Prob. 6.29ECh. 6 - Consider the sulfur solid-state phase transition...Ch. 6 - 6.31. If it takes mega bars of pressure to change...Ch. 6 - Prob. 6.32ECh. 6 - Four alcohols have the formula C4H9OH: 1-butanol,...Ch. 6 - Prob. 6.34ECh. 6 - At 20.0C, the vapor pressure of ethanol is...Ch. 6 - Prob. 6.36ECh. 6 - Prob. 6.37ECh. 6 - Ethanol has a density of 0.789g/cm3 and a vapor...Ch. 6 - Prob. 6.39ECh. 6 - Prob. 6.40ECh. 6 - Prob. 6.41ECh. 6 - 6.42. At what pressure does the boiling point of...Ch. 6 - Prob. 6.43ECh. 6 - Prob. 6.44ECh. 6 - Prob. 6.45ECh. 6 - Prob. 6.46ECh. 6 - Prob. 6.47ECh. 6 - 6.48. Explain how glaciers, huge masses of solid...Ch. 6 - Prob. 6.49ECh. 6 - Prob. 6.50ECh. 6 - Prob. 6.51ECh. 6 - Prob. 6.52ECh. 6 - Prob. 6.53ECh. 6 - Prob. 6.54ECh. 6 - Prob. 6.55ECh. 6 - Prob. 6.56ECh. 6 - Prob. 6.57ECh. 6 - Use the phase diagram of water in Figure 6.6 and...Ch. 6 - Prob. 6.59ECh. 6 - Prob. 6.60ECh. 6 - At the triple point of a substance, the vapor...Ch. 6 - Prob. 6.62ECh. 6 - Prob. 6.63ECh. 6 - Prob. 6.64ECh. 6 - Prob. 6.65ECh. 6 - Prob. 6.66ECh. 6 - The phase diagram for elemental sulfur is shown in...Ch. 6 - Consider the phase diagram of sulfur in the...Ch. 6 - Prob. 6.69ECh. 6 - Rearrange the Clausius-Clapeyron equation,...
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- Sublimation is the phase change from solid to gas without going through a liquid phase. Solid CO2, called dry ice, is an example of one substance that sublimed. Use Hesss law to show that the enthalpy of sublimation, subH, is equal to fusH vapH.arrow_forwardHow many grams of water at 0C will be melted by the condensation of 1 g of steam at 100C?arrow_forward9.46 The heat of fusion of pure silicon is 43.4 kJ/mol. How much energy would be needed to melt a 5.24-g sample of silicon at its melting point of 1693 K?arrow_forward
- Chloromethane, CH3CI, arises from microbial fermentation and is found throughout the environment. It is also produced industrially, is used in the manufacture of various chemicals, and has been used as a topical anesthetic. How much energy is required to convert 92.5 g of liquid to a vapor at its boiling point, 24.09 C? (The heat of vaporization of CH3Cl is 21.40 kJ/mol.)arrow_forwardIf you want to convert 56.0 g ice (at 0 °C) to water at 75.0 °C, calculate how many grams of propane, C3H8, you would have to bum to supply the energy to melt the ice and then warm it to the final temperature (at 1 bar).arrow_forwardLiquid butane, C4H10, is stored in cylinders to be used as a fuel. Suppose 35.5 g of butane gas is removed from a cylinder. How much heat must be provided to vaporize this much gas? The heat of vaporization of butane is 21.3 kJ/mol.arrow_forward
- Which would you expect to have the higher fusion enthalpy, N2 or I2? Explain your choice.arrow_forwardIn regions with dry climates, evaporative coolers are used to cool air. A typical electric air conditioner is rated at 1.00 104 Btu/h (1 Btu, or British thermal unit = amount of energy to raise the temperature of 1 lb water by 1F). What quantity of water must be evaporated each hour to dissipate as much heat as a typical electric air conditioner?arrow_forwardhe enthalpy (H)of vaporization of water is about seven times larger than water’s enthalpy fusion(41kJ/molvs.6kJ/mol). What does this tell us about the relative similarities among the solid, liquid, and gaseous states of water?arrow_forward
- How much heat (q) in joules (J) was involved when 52.4 g of steam was condensed (DHvapH2O = 2260 J/g) with a phase change at the boiling point of water?arrow_forwardChemistry Using a data below, calculate the molar heat of vaporization of an unknown substance (in units of KB/mol). y=-3125.3×+13.248 andR^2 =0.9375. 1/T,T in Kelvins.arrow_forwardHow much heat is gained when the temperature of 288 g of liquid water is raised by 25 oC from room temperature at 25 oC ? 30 096 J b. 60 192 J c. 15 058 J d. 20 618 J e. 0 Jarrow_forward
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