EP ORGANIC CHEMISTRY -MOD.MASTERING 18W
9th Edition
ISBN: 9780136781776
Author: Wade
Publisher: PEARSON CO
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Question
Chapter 6, Problem 6.37SP
(a)
Interpretation Introduction
To determine: The reaction rate if the concentration of ethyl bromide is doubled.
Interpretation: If the concentration of ethyl bromide is doubled, then its effect on reaction rate is to be stated.
Concept introduction:
(b)
Interpretation Introduction
To determine: The reaction rate if the concentration of ethyl bromide is doubled and the concentration of potassium tert-butoxide is tripled.
Interpretation: If the concentration of ethyl bromide is doubled and the concentration of potassium tert-butoxide is tripled, then its effect on reaction rate is to be stated.
Concept introduction:
(c)
Interpretation Introduction
To determine: The effect of temperature increase on reaction rate.
Interpretation: The effect of temperature increase on reaction rate is to be stated.
Concept introduction:
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Students have asked these similar questions
Complete the reaction by providing the starting material/reagent/products.
Match each item to a choice:
HO
OH
NO₂
Cl₂
FeCl3
HO
SO3
conc. H₂SO4
KMnO4
H₂O
NO₂
NO₂
CI
Which reagent(s) will complete the following reaction?
NH2
1. NaNO2, H2S04
2. D3PO2
1. HNO3
2. D20
1. NaNO2, D2SO4
2. H3PO2
1. NaNO2, H2SO4
2. LIAID4
D30*
II
II
IV
V
O a. I
O b. II
О с. Ш
O d. IV
О е. V
4. Which of the following reactions is NOT a method of preparation of alkylhalide?
A. addition of halogens to alkenes
B. replacement of the -OH in alcohol by a halide
C. dehydrohalogenation
of hydrocarbon
D. addition of hydrogen halide to alkene
5. In SN₂ reaction of alkylhalide(substrate) with NaOH(nucleophile), the rate of the reaction is tripled if the
concentration of:
A. Substrate and nucleophile are both doubled
B. Nucleophile is decreased by 1/3 and substrate doubled
C. Substrate is tripled and nucleophile doubled
D. Nucleophile is tripled
6. Arrange the following alkylhalide in order of decreasing reactivity in an SN₁ reaction:
I. CH3CH(Br)CH₂CH3
A. I>II>III>IV
II. CH3CH(C1)CH₂CH3 III. CICH₂CH₂CH₂CH3 IV. (CH3)2C(Br)CHCH3
D. IV>II>I>III
B. IV>III>II>I C. IV>I>II>III
Chapter 6 Solutions
EP ORGANIC CHEMISTRY -MOD.MASTERING 18W
Ch. 6.1 - Classify each compound as an alkyl halide, a vinyl...Ch. 6.2 - Give the structures of the following compounds. a....Ch. 6.2 - For each of the following compounds, A. give the...Ch. 6.3E - Prob. 6.4PCh. 6.4 - Prob. 6.5PCh. 6.5A - For each pair of compounds, predict which compound...Ch. 6.5B - Prob. 6.7PCh. 6.6B - Prob. 6.8PCh. 6.6B - The light-initiated reaction of...Ch. 6.6B - Show how free-radical halogenation might be used...
Ch. 6.7 - Prob. 6.11PCh. 6.7 - Prob. 6.12PCh. 6.8 - Prob. 6.13PCh. 6.9 - Predict the major products of the following...Ch. 6.9 - Prob. 6.15PCh. 6.10A - Prob. 6.16PCh. 6.11A - When diethyl ether (CH3CH2OCH2CH3) is treated with...Ch. 6.11B - Prob. 6.18PCh. 6.11B - For each pair of compounds, state which compound...Ch. 6.12 - Prob. 6.20PCh. 6.12 - Under appropriate conditions...Ch. 6.13 - Propose an SN1 mechanism for the solvolysis of...Ch. 6.13B - Prob. 6.23PCh. 6.13B - 3-Bromocyclohexene is a secondary halide, and...Ch. 6.15 - Prob. 6.25PCh. 6.15 - Prob. 6.26PCh. 6.16 - For each reaction, give the expected substitution...Ch. 6.16 - Prob. 6.28PCh. 6.16 - Prob. 6.29PCh. 6 - Prob. 6.30SPCh. 6 - Draw the structures of the following compounds. a....Ch. 6 - Give systematic (IUPAC) names for the following...Ch. 6 - Prob. 6.33SPCh. 6 - Predict the compound in each pair that will...Ch. 6 - Prob. 6.35SPCh. 6 - Give two syntheses for (CH3)2CHOCH2CH3, and...Ch. 6 - Prob. 6.37SPCh. 6 - Prob. 6.38SPCh. 6 - Chlorocyclohexane reacts with sodium cyanide...Ch. 6 - Give the substitution products expected from...Ch. 6 - Prob. 6.41SPCh. 6 - Prob. 6.42SPCh. 6 - Two of the carbocations in Problem6-42 are prone...Ch. 6 - Prob. 6.44SPCh. 6 - Predict the products of the following SN2...Ch. 6 - Prob. 6.46SPCh. 6 - Strawberry growers have used large quantities of...Ch. 6 - A solution of pure (S)-2-iodobutane ([]=+15.90) in...Ch. 6 - Prob. 6.49SPCh. 6 - Give a mechanism to explain the two products...Ch. 6 - Prob. 6.51SPCh. 6 - Because the SN1 reaction goes through a flat...Ch. 6 - Prob. 6.53SPCh. 6 - Furfuryl chloride can undergo substitution by both...Ch. 6 - Prob. 6.55SPCh. 6 - The following reaction takes place under...Ch. 6 - Propose mechanisms to account for the observed...Ch. 6 - Prob. 6.58SPCh. 6 - Prob. 6.59SP
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