Interpretation: The transfer of an ethyl group by triethyloxonium tetrafluoroborate to a nucleophile in a
Concept introduction: The replacement or substitution of one
The nucleophilic reaction contains a substrate as well as a nucleophile as the reactants which mean a bimolecular nucleophilic reaction is termed as
The
To determine: A mechanism for the transfer of an ethyl group by triethyloxonium tetrafluoroborate to a nucleophile in a
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Chapter 6 Solutions
EP ORGANIC CHEMISTRY -MOD.MASTERING 18W
- 4. A CHEM 245 student wants to synthesize some ethylene glycol to use as antifreeze in his radiator this winter. He proposes the following reaction to his instructor, who quickly explains that this reaction won't work as proposed due to the student's choice of reagent. 1) NaH 2) H20 OH Но a) Why can't sodium hydride (NaH) be used as the nucleophile in the reaction above? b) Propose an alternate reagent that COULD be used with the ethylene oxide to successfully give the desired ethylene glycol product.arrow_forwardTopic: Reactions of benzene Starting from benzene, synthesize the following compounds. Write the complete reagent/s and intermediate product/s. The step by step mechanism (movement of arrow) is not necessary.arrow_forwardComplete the reaction scheme below. Show all reagents and intermediates. No reaction is a possible answer. Do not neglect stereochemistry. NaCN DIBAL Br в A "OCH3 (sodium cyanide)arrow_forward
- Kindly answer question a & barrow_forwardorgo chem questionsarrow_forwardHow does gold help to catalyze the reaction in the gold catalysis experiment? It deprotonates the methanol, making methanol a better nucleophile. оа. o b. It donates electron density to the alkyne, making the alkyne a better nucleophile. О с. It coordinates to the methanol, making methanol a better nucleophile. o d. It coordinates to the alkyne, making the alkyne a better electrophile.arrow_forward
- Provide the whole reaction mechanism (generation of electrophile, nucleophile, bond formation, bond breaking and movement of arrows) and the final product of the following reactions:arrow_forwardThe following flow chart connects three of the reactions we have discussed that involve carbocation intermediates. Each arrow may represent more than one elementary step in a mechanism.Arrows 1 and 2 summarize the conversion of alcohols to alkyl halides, 3 and 4 the dehydrohalogenation of an alkyl halide to an alkene by the E1 mechanism, and 1 and 4 the formation of an alkene by dehydration of an alcohol. The reaction indicated by arrow 5 constitutes a major focus of the next chapter. There we will explore reactions that give overall addition to the double bond by way of carbocation intermediates. One such process converts alkenes to alkyl halides (5 + 2), another converts alkenes to alcohols (5 + 6).What term best describes the relationship between an alkene and a carbocation? A. Isomers B. Resonance contributors C. Alkene is conjugate acid of carbocation D. Alkene is conjugate base of carbocationarrow_forwardShow how to control the stereochemistry and regiochemistry (orientation) of additions to alkenes to obtain the products we want.arrow_forward
- 2) Complete the mechanism for the following reactions. Show the formation of all products. A) B) H Br Br 1) H₂PO4 -OH 2) Nabr LOH H₂O Кон он -Br & +arrow_forwardCan sombody help me explain why there is no reaction in the following reaction please? Thank you!arrow_forwardSelect the reagent that you would use to convert an alkene to an epoxide. mCPBA 03, then DMS BH3-THF, then H2O2, H2O, NaOH Hg(OAc)2, H2O, then NaBH4arrow_forward
- EBK A SMALL SCALE APPROACH TO ORGANIC LChemistryISBN:9781305446021Author:LampmanPublisher:CENGAGE LEARNING - CONSIGNMENT