(a)
To determine: The structure of the substitution product that is obtained by the reaction of
Interpretation: The structure of the substitution product that is obtained by the reaction of
Concept introduction: The replacement or substitution of one
(b)
To determine: The structure of the substitution product that is obtained by the reaction of
Interpretation: The structure of the substitution product that is obtained by the reaction of
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction. First one is electrophilic substitution reaction in which electrophile is present as a reagent and second one is nucleophilic substitution reaction in which nucleophile is present as a reagent.
(c)
To determine: The structure of the substitution product that is obtained by the reaction of
Interpretation: The structure of the substitution product that is obtained by the reaction of
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction. First one is electrophilic substitution reaction in which electrophile is present as a reagent and second one is nucleophilic substitution reaction in which nucleophile is present as a reagent.
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Chapter 6 Solutions
EP ORGANIC CHEMISTRY -MOD.MASTERING 18W
- Cis-but-2-ene has a different set of properties compared to trans-but-2-ene. the melting points of these two compounds is influence primarily by what factor? a. Dipole moment b. Hydrogen Bonding c. Symmetry of molecule d. Van de Waals interaction Which electrophilic aromatic substitution reaction is described when aniline is transformed into para-aminotolouene? a. Halogenation b. Nitration c. Oxidation d. Friedel Crafts alkylation The following hydrocarbons will exhibit electrophilic reactions (addition or substitution) involving halogens except: a. ethyne b. ethene c. ethane d. benzenearrow_forwardThe synthesis of cyclohexanone oxime from cyclohexanone is a net? a. elimination b. substitution C. addition d. rearrangement The synthesis of cyclohexanone oxime from cyclohexanone is a net of carbon? a. reduction b. oxidation C. not a redox of carbon Balancing the equation of all the starting reagents going to final products in the synthesis of cyclohexanone oxime from cyclohexanone (see the first question), what is the coefficient of water if the coefficient of cyclohexanone is one? Give your answer in decimal form with no units. Answer: Select all the effects that you should see in an infrared going from cyclohexanone to cyclohexanone oxime. Selecting wrong answers may give you a negative score. a. a peak should disappear from above 3000 cm -1 b. a new peak should appear above 3000 cm -1 c. the frequency of the infrared absorption should go down in the double bond region d. the frequency of the infrared absorption should go up in the double bond regionarrow_forwardDraw the structure(s) of the major organic product(s) of the following reaction. 1. KMnO4/ aq. NaOH 2. aqueous H₂SO4arrow_forward
- The reaction of 4-methylcyclohexanone with CH3MgBr followed by neutralization gives two alcohols. These two alcohols are A. enantiomers formed in equal amounts. B. diastereomers. C. constitutional isomers. D. enantiomers formed in unequal amounts.arrow_forwardWhich of the following compounds does not contain alkynes in its chemical structure? а. CH, b. H,C - CH3 C. d.arrow_forwardOxidation of 1-butanol and 2-butanol yields (respectively) a. butanal exclusively b. 2-butanone exclusively c. butanal and 2-butanone d. butanal and 2-butanone if PCC is the oxidizing agent e. butanal and 2-butanone if the Jones reagent is the oxidizing agentarrow_forward
- 1. An alkene reacts with water with an acid catalyst results into a formation of: A. Aldehyde B. Ketone C. Alcohol D. Ester 2. 3-Methylhexanal with K2Cr2O7 will yield: A. 3-Methyl-1-hexanol B. 3-Methylhexanoic acid C. 3-Methyl-1-hexanone D. 3-Methyl-1-hexanethiol 3. This is a reverse process of Hydration reaction: A. Oxidation reaction B. Reduction reaction C. Dehydration reaction D. Hydration reaction 4. Acetic acid reacts with a strong base forms: A. Salt B. Water C. Salt and Water D. No reaction 5. Ketones can be further oxidized with benedict's solution into: A. Alcohol B. Aldehyde C. Catalysts D. No reactionarrow_forward1. What reaction happened when wine become sour, turning it to acetic acid? A. cracking B. oxidation C. hydrolysis D. nitration 2. Which of the following is not a possible combination of products when heptadecane undergoes cracking? a. octane + pentene + butene b. heptane + butane + butene + ethene c. heptane + propene + pentene + ethene d. octane + butene + propene + ethenearrow_forwardname and draw the product/s formed from the reaction of 3-methylpent-2-ene: 1. with HBr 2. with Cl2 3. H2O in the presence of H2SO4 4. ethanol in the presence of H2SO4 5. Br2, H2O 6. [1] 9-BBN; [2] H2O2, OH-arrow_forward
- Draw structural formulas for the alkene that gives each alcohol upon hydroborationoxidation. OH HO, b. a.arrow_forwarda. Draw the structures and give the common and systematic names for alkynes with molecular formula C7H12. Ignore stereosiomers. (Hint: There are 14.) b. How many would there be if stereoisomers are included?arrow_forwardReagents a. C6H5CHO b. NaOH, ethanol h. BrCH2CH=CH2 i. Na* OEt, ethanol j. Br2, H* k. K* t-BuO c. Pyrrolidine, cat. H* d. H2C=CHCN e. H3O* f. I. CH2(CO2ET)2 -CH2CH2CN LDA m. heat g. ELOC(=0)CO2ET Select reagents from the table to synthesize this compound from cyclopentanone. Enter the letters of the chosen reagents, in the order that you wish to use them, without spaces or punctuation (i.e. geda).arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
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