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- Rank the following substances in order of increasing acidity: (a) (CH3)2CHOH, HC≡CH, (CF3)2CHOH, CH3OH (b) Phenol, p-methylphenol, p-[trifluoromethyl) phenol (c) Benzyl alcohol, phenol, p-hydroxybenzonic acidarrow_forwardWhy are terminal alkynes a lot more acidic than alkanes? - More hydrogen atoms on a sp^3 Carbon - C-C triple bond is stronger than a single bond - Sp1 Carbon in terminal alkynes stabilize conjugate bases. - none of the abovearrow_forwardComplete the chemical reaction Identify the conjugate pairs H2SO4 + H2O === CH3COOH + H2O === NH3 + H2O === NH4+ + H2O === HClO4 + H2O === KOH ====arrow_forward
- Draw all constitutional isomers with molecular formula C2H6S, and rank them in terms of increasing acidity. Draw the less acidic isomer as "Isomer 1", and the more acidic as "Isomer 2". Include lone pairs and formal charges.arrow_forwardBriefly, but clearly, explain why the –OH hydrogen in acetic acid (CH3CO2H) is more acidic than in ethanol (C2H5OH).arrow_forwardHow does resonance affect the acidity of a compound? Why is phenol more acidic in some alcohols and why is carboxylic acid more acidic?arrow_forward
- Why is H3C-O-SiH3 ether a weaker base than (CH3)3O?arrow_forwardA carboxylic acid has two oxygen atoms, each with two nonbonding pairs of electrons.(a) Draw the resonance forms of a carboxylic acid that is protonated on the hydroxyoxygen atom.arrow_forwardExplain why the pH of a 0.25 M solution of formic acid (HCO2H) has a lower pH than a solution that is 0.25 M in both formic acid and sodium formate (NaCO2H). Please include chemical reactions.arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningOrganic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning