An Introduction to Thermal Physics
An Introduction to Thermal Physics
1st Edition
ISBN: 9780201380279
Author: Daniel V. Schroeder
Publisher: Addison Wesley
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Chapter 6.7, Problem 53P
To determine

The value of equilibrium constant K .

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P2D.8 Use the fact that (∂U/∂V)T = a/Vm2for a van der Waals gas (Topic 1C)to show that μCp,m ≈ (2a/RT) − b by using the definition of μ and appropriaterelations between partial derivatives. Hint: Use the approximation pVm ≈ RTwhen it is justifiable to do so.
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