An Introduction to Thermal Physics
1st Edition
ISBN: 9780201380279
Author: Daniel V. Schroeder
Publisher: Addison Wesley
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Chapter 6.2, Problem 25P
The analysis of this section applies also to linear polyatomic molecules, for which no rotation about the axis of symmetry is possible. An example is
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When are the rotational degrees of freedom of a diatomic molecule expected to contribute R to the molar constant volume heat capacity? When will a vibrational degree of freedom contribute R to the molar heat capacity?
Although an ordinary H2 molecule consists of two identical atoms, this is not the case for the molecule HD, with one atom of deuterium (Le., heavy hydrogen, 2H). Because of its small moment of inertia, the HD molecule has a relatively large value of E: 0.0057 eV. At approximately what temperature would you expect the rotational heat capacity of a gas of HD molecules to "freeze out," that is, to fall significantly below the constant value predicted by the equipartition theorem?
Consider a CO molecule that is initially in the ground state of n = 0, l = 0. If the energy of a vibrational transition from the n = 0 state to the n = 1 state in CO could instead be absorbed in a rotational transition, what would be the value of l for the final state?
Chapter 6 Solutions
An Introduction to Thermal Physics
Ch. 6.1 - Prob. 2PCh. 6.1 - Prob. 4PCh. 6.1 - Prob. 5PCh. 6.1 - Prob. 6PCh. 6.1 - Prob. 7PCh. 6.1 - Prob. 8PCh. 6.1 - Prob. 9PCh. 6.1 - Prob. 10PCh. 6.1 - Prob. 11PCh. 6.1 - Prob. 12P
Ch. 6.1 - Prob. 13PCh. 6.1 - Prob. 14PCh. 6.2 - Prob. 15PCh. 6.2 - Prob. 16PCh. 6.2 - Prob. 17PCh. 6.2 - Prob. 18PCh. 6.2 - Prob. 19PCh. 6.2 - Prob. 20PCh. 6.2 - For an O2 molecule the constant is approximately...Ch. 6.2 - The analysis of this section applies also to...Ch. 6.3 - Prob. 31PCh. 6.4 - Calculate the most probable speed, average speed,...Ch. 6.4 - Prob. 35PCh. 6.4 - Prob. 36PCh. 6.4 - Prob. 37PCh. 6.4 - Prob. 39PCh. 6.4 - Prob. 40PCh. 6.5 - Prob. 42PCh. 6.5 - Some advanced textbooks define entropy by the...Ch. 6.6 - Prob. 44PCh. 6.7 - Prob. 45PCh. 6.7 - Equations 6.92 and 6.93 for the entropy and...Ch. 6.7 - Prob. 47PCh. 6.7 - For a diatomic gas near room temperature, the...Ch. 6.7 - Prob. 49PCh. 6.7 - Prob. 50PCh. 6.7 - Prob. 51PCh. 6.7 - Prob. 52PCh. 6.7 - Prob. 53P
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- Consider the HCl molecule, which consists of a hydrogen atom of mass 1 u bound to a chlorine atom of mass 35 u. The equilibrium separation between the atoms is 0.128 nm, and it requires 0.15 eV of work to increase or decrease this separation by 0.01 nm. (a) Calculate the four lowest rotational energies (in eV) that are possible, assuming the molecule rotates rigidly. (b) Find the molecules spring constant and its classical frequency of vibration. (Hint: Recall that U=12Kx2.) (c) Find the two lowest vibrational energies and the classical amplitude of oscillation corresponding to each of these energies. (d) Determine the longest wavelength radiation that the molecule can emit in a pure rotational transition and in a pure vibrational transition.arrow_forwardCompare the effective force constant for the CO molecule deduced here with that of an ordinary laboratory spring that stretches 0.5 m when a 1.0 kg mass is suspended from it.arrow_forwardFind the number of vibrational degrees of freedom of a CO2 molecule,if the average kinetic energy of it is 4 kT.arrow_forward
- Show that the moment of inertia of a diatomic molecule composed of atoms of masses mA and mB and bond length R is equal to meffR2, where meff = mAmB/(mA + mB).arrow_forwardA gas phase H19F molecule has a bond length of 91.68 pm and a vibrational force constant,k = 966 N/m. For the v = 0, J = 10 and v = 1, J = 10 rovibrational levels, calculate the period of rotation andvibration. How many times does the molecule rotate during one vibrational period?arrow_forwardThe figure above shows the absorption spectrum of the molecule HBr. Following the basic procedures of Section 9.6, find:(a) the energy of the “missing” transition;(b) the effective force constant k;(c) the rotational spacing 2B. Estimate the value of the rotational spacing expected for HBr and compare with the value deduced from the spectrum. Why are there only single lines and not double lines as in the case of HCl?arrow_forward
- What is the probability that, at a temperature of T = 300 K, an electron will jump across the energy gap Eg (= 5.5 eV) in a diamond that has a mass equal to the mass of Earth? Use the molar mass of carbon in Appendix F; assume that in diamond there is one valence electron per carbon atom.arrow_forwardLet's consider the three atoms composing the molecule now have different masses and coordinate, while the axis of rotation is still z axis that is perpendicular to the xy plane. The first atom has a mass of 142.54 kg, with x coordinate at 3 m and y coordinate at 6 m. The second atom has a mass of 82.55 kg, with x coordinate at 1 m and y coordinate at 6 m. The third atom has a mass of 8 kg, with x coordinate at 5 m and y coordinate at 9 m. What is the moment of inertia in unit of kg m2 with respect to the x axis?arrow_forwardConsider a free Fermi gas in two dimensions, confined to a squarearea A = L2. Find the Fermi energy (in terms of N and A), and show that the average energy of the particles is €F /2.arrow_forward
- The equilibrium separation between the two ions in the KCl molecule is 0.267 nm. (a) Assuming that the K+ and Cl- ions are point particles, compute the electric dipole moment of the molecule. (b) Compute the ratio of your result in (a) to the measured electric dipole moment of 5.41 x 10-29 C*m. This ratio is known as the fractional ionic character of the molecular bond.arrow_forwardSuppose that the wavenumber of the J = 1 ← 0 rotational transition of 1H81Br considered as a rigid rotor was measured to be 18.20 cm-1, what is (a) the moment of inertia of the molecule? _____________kg-m2 (b) the bond length? ________________Angstroms (Given the isotopic masses:(m(79Br) = 78.9183 amu, m(81Br) = 80.9163 amuarrow_forwardTo obtain a more clearly defined picture of the FermiDirac distribution, consider a system of 20 FermiDirac particles sharing 94 units of energy. By drawing diagrams like Figure P10.11, show that there are nine different microstates. Using Equation 10.2, calculate and plot the average number of particles in each energy level from 0 to 14E. Locate the Fermi energy at 0 K on your plot from the fact that electrons at 0 K fill all the levels consecutively up to the Fermi energy. (At 0 K the system no longer has 94 units of energy, but has the minimum amount of 90E.) 1 Microstate8 others? One of the nine equally probable microstates for 20 FD particles with a total energy of 94E.arrow_forward
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