Concept explainers
(a)
Interpretation: The better leaving group from the given pair is to be identified.
Concept introduction: The replacement or substitution of one functional group with another different functional group in any
(b)
Interpretation: The better leaving group from the given pair is to be identified.
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low
(c)
Interpretation: The better leaving group from the given pair is to be identified.
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low
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Chapter 7 Solutions
ORGANIC CHEMISTRY-STUDY GDE...-W/ACCESS
- Which member in each pair is a better leaving group? a. H2O or HO- b. NH3 or H2O c. H2O or H2S d. HO- or HS- e. I- or Br-. f. Cl- or Brarrow_forwardOptions for each: blank 1: A B blank 2: it has a better leaving group it is a polar aprotic solvent it has a stronger nucleophile blank 3: A B blank 4: it forms a more stable carbocation it has a better solvent it has a better leaving group blank 5: A B blank 6: it has a better solvent it has a better leaving group it has a stronger nucleophilearrow_forwardWhich side of the equilibrium is favored in this acid/base rxn? pka of product: 6.9arrow_forward
- Put the following leaving groups in order from best leaving group to worst leaving group: I Br Cl Farrow_forwardWhich reaction corresponds to the Kb for HSO4− ? a. H2SO4 ⇌ H+ + HSO4− b. SO42− + H2O ⇌ OH− + HSO4− c. HSO4− + H2O ⇌ OH− + H2SO4 d. HSO4− ⇌ H+ + SO42− e. HSO4− + OH− ⇌ H2O + SO42−arrow_forwardExplain in your own words why reaction (a) would be faster than reaction (b). (a) H+(aq) + Cl¯(aq) --> HCl(aq) (b) H2(g) + Cl2(g) --> 2 HCl(g)arrow_forward
- Can you match best nucleophile / conditions from the list that will give a successful hydrolysis reaction for each electrophile? (there's one best nucleophile / conditions for each electrophile) <List for Nucleophile / condition> a. LiAlH4; hydronium work-up b. PCC c. NaH d. CrO3 e. HOEt f. H3O+ or OH- g. H2O h. NaBH4;hydronium work-up Electrophile 1. Acid chloride 2. Acetic anhydride 3. Ester 4. Amide I'm asking again on bartleby because pther tutor gave me the right answer because I think I didn't make my question clear enough.arrow_forward1. Indicate the direction in which each reaction is favoredarrow_forwardWhich is a stronger acid? Why? CH3 CO OH or CH3 OSO OHarrow_forward
- Which is the stronger acid? a. CH3CH3 or HC CH b. H2C CH2 or HC CH c. H2C CH2 or CH3CH3arrow_forwardFor the Reaction: NH3+ H2O = NH4+ OH- When adding NH3+ phenolphthalien+ HCl What stress is applied and what direction does the equilibrium shift? When adding NH3+ phenolphthalien+ NH4Cl What stress is applied and what direction does the equilibrium shift? When adding NH3+ phenolphthalien+ NaOH What stress is applied and what direction does the equilibrium shift? When adding NH3+ phenolphthalien+ HCl What stress is applied and what direction does the equilibrium shift?arrow_forwardWhich hydrogen in each molecule is more acidic? b. NH3 or H2Oc. HBr or HCld. H2S or H2Oarrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning