(a)
Interpretation: The mechanism for the given reaction should be explained.
Concept Introduction:
Primary carbocation < secondary carbocation < tertiary carbocation
Carbocation: it is carbon ion that bears a positive charge on it.
Leaving group: it is a fragment that leaves substrate with a pair of electrons via heterolytic bond cleavage.
Nucleophile: donates pair of electrons to positively charged substrate resulting in the formation of
Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes the molecule more stable.
IR spectral studies: It is one of the spectroscopic techniques, used to determine the
NMR Spectroscopy: It is one of the spectroscopic techniques that determine the properties of atoms and molecules of a given compound by using nuclear magnetic resonance.
Nuclear Magnetic Resonance: When nuclei of given compound sample is subjected to magnetic field, the nuclei absorb and emit the radiation with respect to strength of the field applied.
(b)
Interpretation: The reactivity for the products formed under given cases are should be explained.
Concept Introduction:
Primary carbocation < secondary carbocation < tertiary carbocation
Carbocation: it is carbon ion that bears a positive charge on it.
Leaving group: it is a fragment that leaves substrate with a pair of electrons via heterolytic bond cleavage.
Nucleophile: donates pair of electrons to positively charged substrate resulting in the formation of chemical bond.
Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes the molecule more stable.
IR spectral studies: It is one of the spectroscopic techniques, used to determine the functional group present in the sample of given compound.
NMR Spectroscopy: It is one of the spectroscopic techniques that determine the properties of atoms and molecules of a given compound by using nuclear magnetic resonance.
Nuclear Magnetic Resonance: When nuclei of given compound sample is subjected to magnetic field, the nuclei absorb and emit the radiation with respect to strength of the field applied.
(c)
Interpretation: The IR spectral studies for the products formed under given cases are should be explained.
Concept Introduction:
Primary carbocation < secondary carbocation < tertiary carbocation
Carbocation: it is carbon ion that bears a positive charge on it.
Leaving group: it is a fragment that leaves substrate with a pair of electrons via heterolytic bond cleavage.
Nucleophile: donates pair of electrons to positively charged substrate resulting in the formation of chemical bond.
Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes the molecule more stable.
IR spectral studies: It is one of the spectroscopic techniques, used to determine the functional group present in the sample of given compound.
NMR Spectroscopy: It is one of the spectroscopic techniques that determine the properties of atoms and molecules of a given compound by using nuclear magnetic resonance.
Nuclear Magnetic Resonance: When nuclei of given compound sample is subjected to magnetic field, the nuclei absorb and emit the radiation with respect to strength of the field applied.
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Chapter 7 Solutions
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