Elements Of Physical Chemistry
Elements Of Physical Chemistry
7th Edition
ISBN: 9780198796701
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 7, Problem 7.9P
Interpretation Introduction

Interpretation:

The location for particle present in box of length L at which its probability is found 50 percent of its maximum probability when n is equal to 1 has to be identified.

Concept Introduction:

For a particle in 1D, the wave function is continuous and it is zero outside of the box hence at x values 0 and L its value should be 0. At n=0 wavelengths are positive hence a negative value for n does not exist.

The wave function expression is given as follows,

ψn=Nsin(nπxL)n = 1,2,...here,ψn=wavefunctionN=NormalizationconstantN=(2L)1/2L=lengthofthebox

The wave function is considered to be normalized if the probability of finding the particle in considered domain is equal to 1 and therefore, the integral function of given wave function in considered domain is equal to 1.

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