Elements Of Physical Chemistry
Elements Of Physical Chemistry
7th Edition
ISBN: 9780198796701
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 7, Problem 7D.4E
Interpretation Introduction

Interpretation:

The degeneracy for given level 4 and the values of ml have to be identified.

Concept Introduction:

Orbital Angular Momentum (l): It helps to differentiate different shapes of orbitals for given n. For a given n, there are n different shapes of orbitals are present and are denoted as l. Angular momentum quantum number is also known as Azimuthal quantum number. The possible values of angular momentum quantum number between 0and(n-1). If the n is 3, then l values are 0,1and 2 and ml values are 0,+_1and +_2.

The energy of particle with given quantum number is calculated by using the following expression.

E =J22mr2 here,E=energym=mass of particler=distanceJ=rotational quantum number

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