CHEMISTRY:THE CENTRAL SCIEN.+MAST. V.1
14th Edition
ISBN: 9781323866160
Author: Brown, THEODOR
Publisher: PEARSON C
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 9, Problem 45E
For each statement, irldicate whether it is true or false.
a. In order to make a covalent bond, the orbitals on each atom in the bond must overlap,
b. A p orbital on one atom cannot make a bond to an s orbital on another atom
c Lone pairs of electrons on an atom in a molecule influence the shape of a molecule.
d. The Is orbital has a nodal plane
e. The 2P orbital has a nodal plane.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
- What orbital(s) are the lone pairs of electrons on the O atom placed?
- What orbital is the lone pair of electrons on the N atom placed?
- What type of bond(s) are formed between Ca1 – C?
- What type of bond(s) are formed between C = O?
- What type of bond(s) are formed between C – N?
- What type of bond(s) are formed between N – Ca2?
- What type of bond(s) are formed between N – H?
- What is the angle between Ca1 – C = O?
- What is the angle between Ca1 – C – N?
- What is the angle between O = C – N?
- What is the angle between C – N – Ca2?
1. lewis structure of Ethyl thiomethyl ether, CH3SCH2CH3
2. assign the VSEPR model of the central atom3. Value of the corresponding theoretical angle4. classify 3 of the different bonds around the central atom as ionic or covalent5. draw the complete 3-D structure with respect to the central atom (s)6. draw the lewis structure for another mnolecule or species with a different atomic arrangement
Draw the Lewis structure for NH3 . Is the molecule polar or nonpolar? What is the electronic geometry, molecular geometry, and hybridization of nitrogen? Lastly, draw the 3-D structure of the entire molecule.
Chapter 9 Solutions
CHEMISTRY:THE CENTRAL SCIEN.+MAST. V.1
Ch. 9.2 - Consider the following AB3 molecules and ions-...Ch. 9.2 - Prob. 9.1.2PECh. 9.2 - Prob. 9.2.1PECh. 9.2 - Prob. 9.2.2PECh. 9.2 - Prob. 9.3.1PECh. 9.2 - Prob. 9.3.2PECh. 9.3 - Prob. 9.4.1PECh. 9.3 - Determine whether the following molecules are...Ch. 9.5 - Prob. 9.5.1PECh. 9.5 - Prob. 9.5.2PE
Ch. 9.6 - Prob. 9.6.1PECh. 9.6 - Prob. 9.6.2PECh. 9.6 - Prob. 9.7.1PECh. 9.6 - Prob. 9.7.2PECh. 9.7 - Prob. 9.8.1PECh. 9.7 - Prob. 9.8.2PECh. 9.8 - Prob. 9.9.1PECh. 9.8 - Prob. 9.9.2PECh. 9 - Prob. 1DECh. 9 - 9.1 A certain AB4, molecule has a "seesaw" shape...Ch. 9 - Prob. 2ECh. 9 - Prob. 3ECh. 9 - Prob. 4ECh. 9 - Prob. 5ECh. 9 - Prob. 6ECh. 9 - In the hydrocarbon a. What is the hybridization at...Ch. 9 - The drawing below shows the overlap of two hybrid...Ch. 9 - Prob. 9ECh. 9 -
9.10 The following is part of a molecular...Ch. 9 - Prob. 11ECh. 9 - Prob. 12ECh. 9 -
9.13
a. An AB2 molecule is linear. How...Ch. 9 - a. Methane (CH4) and the perchlorate ion (C104-)...Ch. 9 - Prob. 15ECh. 9 - Prob. 16ECh. 9 - Prob. 17ECh. 9 - Prob. 18ECh. 9 - In which of these molecules or ions does the...Ch. 9 - Prob. 20ECh. 9 - How many nonbonding electron pairs are there in...Ch. 9 - Prob. 22ECh. 9 - Prob. 23ECh. 9 - Prob. 24ECh. 9 - Give the electron-domain and molecular geometries...Ch. 9 - Prob. 26ECh. 9 - Prob. 27ECh. 9 - Prob. 28ECh. 9 - Prob. 29ECh. 9 - Prob. 30ECh. 9 - Ammonia, NH3 reacts with incredibly strong bases...Ch. 9 - In which of the following AFn molecules or ions is...Ch. 9 - a. Explain why BrF4 is square planar, whereas...Ch. 9 -
9.34 Name the proper three-dimensional molecule...Ch. 9 - Prob. 35ECh. 9 - Prob. 36ECh. 9 - Prob. 37ECh. 9 - Prob. 38ECh. 9 - a. (a) Is the molecule BF3 polar or nonpolar? b....Ch. 9 - Prob. 40ECh. 9 - Predict whether each of the following molecules is...Ch. 9 - Prob. 42ECh. 9 - Prob. 43ECh. 9 - Prob. 44ECh. 9 - For each statement, irldicate whether it is true...Ch. 9 - Draw sketches illustrating the overlap between the...Ch. 9 - For each statement, indicate whether it is true or...Ch. 9 - Prob. 48ECh. 9 - Prob. 49ECh. 9 - Consider the SC12 molecule. a. What IS the...Ch. 9 - Indicate the hybridization of the central atom in...Ch. 9 - Prob. 52ECh. 9 - Prob. 53ECh. 9 - Prob. 54ECh. 9 - Prob. 55ECh. 9 - Prob. 56ECh. 9 - a. Draw Lewis structures for ethane (C2He),...Ch. 9 - a. Draw Lewis structures for ethane (C2He),...Ch. 9 - Prob. 59ECh. 9 - Ethyl acetate. C4H802, is a fragrant substance...Ch. 9 - Prob. 61ECh. 9 - Prob. 62ECh. 9 - Prob. 63ECh. 9 - Prob. 64ECh. 9 - In the formate ion, HC02- , the carbon atom is the...Ch. 9 - Prob. 66ECh. 9 - Prob. 67ECh. 9 - Prob. 68ECh. 9 - Prob. 69ECh. 9 - a. If you combine two atomic orbitals on two...Ch. 9 - Prob. 71ECh. 9 - Prob. 72ECh. 9 - Prob. 73ECh. 9 - Indicate whether each statement is true or false....Ch. 9 - Prob. 75ECh. 9 - Prob. 76ECh. 9 - Prob. 77ECh. 9 - Prob. 78ECh. 9 - Prob. 79ECh. 9 - Prob. 80ECh. 9 - Determine the electron configurations for CN+, CN,...Ch. 9 - Prob. 82ECh. 9 - Consider the molecular orbitals of the P2...Ch. 9 - The iodine bromide molecule, IBr, is an...Ch. 9 - Prob. 85AECh. 9 - Prob. 86AECh. 9 - Consider the following XF4 ions: PF4, BrF4-,...Ch. 9 -
9.88 Consider the molecule PF4Cl....Ch. 9 - Prob. 89AECh. 9 - Fill in the blank spaces in the following chart....Ch. 9 - Prob. 91AECh. 9 - Prob. 92AECh. 9 - Prob. 93AECh. 9 - Prob. 94AECh. 9 - Prob. 95AECh. 9 - Prob. 96AECh. 9 - Prob. 97AECh. 9 - Prob. 98AECh. 9 - Prob. 99AECh. 9 - Prob. 100AECh. 9 - In ozone, 03, the two oxygen atoms on the ends Of...Ch. 9 - Butadiene, C4H6, is a planar molecule that has the...Ch. 9 - The structure of borazine, B3N3H6, is a...Ch. 9 - Prob. 104AECh. 9 - Prob. 105AECh. 9 - Prob. 106AECh. 9 - Prob. 107AECh. 9 - Prob. 108AECh. 9 - Azo dyes are organic dyes that are used for many...Ch. 9 - a. Using only the valence atomic orbitals of a...Ch. 9 - Carbon monoxide, CO, is isoelectronic to N2. a....Ch. 9 - The energy-level diagram in Figure 9.36 shows that...Ch. 9 - A compound composed of 2.1 29.8%N, and 68.1%O has...Ch. 9 -
9.114 Sulfur tetrafluoride (SR4) reacts slowly...Ch. 9 - Prob. 115IECh. 9 - The molecule 2-butene, C4Hs, can undergo a...Ch. 9 - Prob. 117IECh. 9 - Use average bond enthalpies (Table 8.3 ) to...Ch. 9 - Prob. 119IECh. 9 - Prob. 120IECh. 9 - Prob. 121IECh. 9 - Prob. 122IE
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- How many valence electrons does a neutral a. K atom have? b. C atom? N atom? O atom?arrow_forwardExplain what is wrong with each of the following statements. a. “A bond is a double bond. b. “A bond consists of four electrons, one in each of the four p orbitals involved in the bond. c. “A bond is twice as strong as a bond because it consists of two orbital overlaps insteadof just one.”arrow_forwardConsider the following flat drawing of methane (CH4) . a. What is HCH bond angle implied by this drawing if you assume it is flat? b. Are the electron domains of this flat CH4 spread out as much as possible? c. Use model materials to make a model of CH4 (methane). If you assembled it correctly, thefour bonds (bonding electron domains) of your model will be 109.5° apart. d. In which representation, the drawing above or the model in your hand (circle one) are theH’s of CH4 more spread out around the central carbon? e. Confirm that your model looks like the following drawing. The wedgebond represents a bond coming out of the page, and the dash bondrepresents a bond going into the page f. You will often see methane drawn as if it were flat (like on the previous page). Why is thismisleading, and what is left to the viewer’s imagination when looking at such a drawing?arrow_forward
- When one electron is added to an oxygen molecule, a superoxide ion (O2) is formed. The addition of two electrons gives a peroxide ion (O22) . Removal of an electron from O2 leads to O2+ . (a) Construct the correlation diagram for O2 . (b) Give the valence electron configuration for each of the following species: O2+,O2,O2,O22 . (c) Give the bond order of each species. (d) Predict which species are paramagnetic. (e) Predict the order of increasing bond dissociation energy among the species.arrow_forwardPredict the molecular structure (including bond angles) for each of the following. (See Exercises 25 and 26.) a. ICl5 b. XeC14 c. SeCl6arrow_forwardPart 1 What do each of the following sets of compounds/ions have in common with each other? a) SO3, NO3-, CO32- b) O3,SO2, NO2- Part 2 What do each of the following sets of compounds/ions have in common with each other? a) XeCl4, XeCl2 b) ICl5, TeF4, ICl3, PCl3, SCl2, SeO2arrow_forward
- Consider a molecule AB6, where element A has 6 valence electrons and B has 7 valence electrons. If the ΔEn for each bond = 1.2, predict the shape, bond hybridization and polarity (polar or non-polar) of the molecule. Your answer should follow the format: a) number of total electrons for bonding; b) Steric Number and Lone Pairs; c) name of shape based on the VSEPR chart, d) bond hybridization and e) molecular polarity.arrow_forward1. lewis structure of Vinyl magnesium bromide, CH2CHMgBr 2. assign the VSEPR model of the central atom3. Value of the corresponding theoretical angle4. classify 3 of the different bonds around the central atom as ionic or covalent5. draw the complete 3-D structure with respect to the central atom (s)6. draw the lewis structure for another mnolecule or species with a different atomic arrangementarrow_forwardWhich is the correct electron configuration for B2+ according to the molecular orbital theory? (5B) A. σ1s2 σ*1s2 σ2s2 σ*2s2 σ2pz2 B. σ1s2 σ*1s2 σ2s2 σ*2s2 π2px1 C. σ1s2 σ*1s2 σ2s2 σ*2s2 σ2pz1 D. σ1s2 σ*1s2 σ2s2 σ*2s2 π2px1π2py1arrow_forward
- 1) What is the type of molecule? a. AX2E3 b. AX3E2 c. AX5 d. AX2E2 2) What is the molecular geometry of GL2-? a. Linear b. Trigonal Bypyramidal c. Bent or v-shaped d. Seesaw 3) What is the approx bond angle formed by L-G-L bond if the correct molecular geometry is followed? a. 180° b. 120° c. 109.5° d. 90° 4) Considering that L is more electronegative than G, and the en difference is 0.2, is the molecular polar? 5) What is the formal charge of G? 6) What is the formal charge of the labeled atom? (refer to the blue arrow)arrow_forwardDraw the Lewis structure of CO2 . Is the molecule polar or nonpolar? What is the electronic geometry, molecular geometry, and hybridization of carbon? Lastly, draw the 3-D structure of the entire molecule.arrow_forwardFill in the table. Central atom is listed first. A. Write the number of valence electrons below the formulaB. Draw the Lewis structureC & D. Write the Electron Group Geometry and Molecular Shape NamesE. Write the bond angleF. Write the molecular polarity. "P" for polar and "NP" for nonpolar. SpeciesValenceElectrons(1 pt.) LewisStructure(2 pt.) Electron PairGeometryName(1 pt.) Molecular ShapeName (1 pts.) BondAngle (1 pt.) Molecular Polarity(1 pt.) PO43- NOBr Uploadarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Stoichiometry - Chemistry for Massive Creatures: Crash Course Chemistry #6; Author: Crash Course;https://www.youtube.com/watch?v=UL1jmJaUkaQ;License: Standard YouTube License, CC-BY
Bonding (Ionic, Covalent & Metallic) - GCSE Chemistry; Author: Science Shorts;https://www.youtube.com/watch?v=p9MA6Od-zBA;License: Standard YouTube License, CC-BY
General Chemistry 1A. Lecture 12. Two Theories of Bonding.; Author: UCI Open;https://www.youtube.com/watch?v=dLTlL9Z1bh0;License: CC-BY