Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 3, Problem 7E
Explain what is wrong with each of the following statements.
a. “A
b. “A
c. “A
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
Consider the reaction BF3 + NH3 -> F3B-NH3
(a) Describe the changes in hybridization of the B and N atoms as a result of this reaction.
(b) Describe the shapes of all the reactant molecules with their bond angles.
(c) Draw the overall shape of the product molecule and identify the bond angles around B and N atoms.
(d) What is the name of the bond between B and N.
(e)Describe the bonding orbitals that make the B and F, B and N & N and H bonds in the product molecule.
What hybridization is required for central atoms that have a tetrahedral arrangement of electron pairs? A trigonal planar arrangement of electron pairs? A linear arrangement of electron pairs? How many unhybridized p atomic orbitals are present when a central atom exhibits tetrahedral geometry? Trigonal planar geometry? Linear geometry? What are the unhybridized p atomic orbitals used for?
Consider the SCl2 molecule. (a) What is the electron configuration of an isolated S atom? (b) What is the electron configuration of an isolated Cl atom? (c) What hybrid orbitals should be constructed on the S atom to make the S-Cl bonds in SCl2 ? (d) What valence orbitals if any, remain unhybridized on the S atom in SCL2 ?
Chapter 3 Solutions
Organic Chemistry: A Guided Inquiry
Ch. 3 - Prob. 1CTQCh. 3 - What neutral atom is represented by the electron...Ch. 3 - Prob. 3CTQCh. 3 - Consider any one of the four identical hybrid...Ch. 3 - Prob. 5CTQCh. 3 - Prob. 6CTQCh. 3 - Prob. 7CTQCh. 3 - Prob. 8CTQCh. 3 - Prob. 9CTQCh. 3 - Prob. 10CTQ
Ch. 3 - On the left side of Figure 3.6, label the areas...Ch. 3 - Prob. 12CTQCh. 3 - Prob. 13CTQCh. 3 - Prob. 14CTQCh. 3 - Prob. 15CTQCh. 3 - Now consider the fully formed molecule on the...Ch. 3 - Prob. 1ECh. 3 - Explain why the two molecules below cannot...Ch. 3 - Prob. 3ECh. 3 - Consider the incomplete orbital representation of...Ch. 3 - Consider the following orbital representation of...Ch. 3 - Summarize how one determines the hybridization...Ch. 3 - Explain what is wrong with each of the following...Ch. 3 - Prob. 8ECh. 3 - Prob. 9ECh. 3 - Complete the following tables, and memorize their...Ch. 3 - Draw orbital representations of bonding in water...Ch. 3 - Draw electron configuration diagrams for carbon in...Ch. 3 - Prob. 13E
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Which statement is true concerning molecular orbital (MO) theory? A. Atomic orbitals overlap to form bonds B. Atomic orbitals combine to form both bonding and anti-bonding orbitals C. Atomic orbitals through VSEPR can determine the geometric shapes of molecules D. Atomic orbitals on the same atom combine with each other to make hybrid orbitals.arrow_forward(a) What is the difference between hybrid orbitals and molecular orbitals? (b) How many electrons can be placed into each MO of a molecule? (c) Can antibonding molecular orbitals have electrons in them?arrow_forwardWhat is the bond angle between the 2px, 2py, and 2pz atomic orbitals? What would be the allowable bond angles be if 2p atomic orbitals were combined to make molecular orbitals?arrow_forward
- Draw the molecular orbital (MOs) that results from combining the following atomic orbitals. Recall that, depending on the phases and orientation of the orbitals, you may have: a. constructive overlap to form a bonding orbital b. destructive overlap to form an antibonding orbital c. no overlap (equal amounts constructive and destructive). In this case, write “non-bonding” instead of drawing an orbitalarrow_forwardDraw an orbital picture of propene. The bond between and is formed by the overlap of which types of orbitals? a. sp2 and sp2 b. sp3 and sp3 c. sp2 on Ca and sp3 on Cb d. sp3 on Ca and sp2 on Cb The double bond between and is formed by what? a. two sigma bonds b. two pi bonds c. overlap of a p orbital on Cb with a sp2 orbital on Cc. d. overlap of two p orbitals plus overlap of two sp2 orbitalsarrow_forwardIn the hydrocarbon(a) What is the hybridization at each carbon atom in themolecule? (b) How many s bonds are there in the molecule?(c) How many p bonds? (d) Identify all the 120° bond anglesin the molecule. [Section 9.6]arrow_forward
- Consider the bonding in nitrate ion, NO3. First draw resonance formulas of this ion. Now describe the bonding of this ion in terms of molecular orbitals. (Refer to the delocalized bonding of the ozone molecule described in the text.) Suppose each atom uses sp2 hybrid orbitals. How many molecular orbitals can you form from the 2p orbitals that remain on these atoms? How many of these orbitals will be occupied?arrow_forwardHow are the following similar, and how do they differ? (a) molecular orbitals and molecular orbitals (b) for an atomic orbital and for a molecular orbital (c) bonding orbitals and antibonding orbitalsarrow_forwardGive the expected hybridization of the central atom for the molecules or ions in Exercises 82 and 88 from Chapter 3.arrow_forward
- Lets look more closely at the process of hybridization. (a) What is the relationship between the number of hybrid orbitals produced and the number of atomic orbitals used to create them? (b) Do hybrid atomic orbitals form between different p orbitals without involving 5 orbitals? (c) What is the relationship between the energy of hybrid atomic orbitals and the atomic orbitals from which they are formed?arrow_forwardWhy are d orbitals sometimes used to form hybrid orbitals? Which period of elements does not used orbitals for hybridization? If necessary, which d orbitals (3d, 4d, 5d, or 6d) would sulfur use to form hybrid orbitals requiring d atomic orbitals? Answer the same question for arsenic and for iodine.arrow_forward
arrow_back_ios
arrow_forward_ios
Recommended textbooks for you
Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStax
General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Stoichiometry - Chemistry for Massive Creatures: Crash Course Chemistry #6; Author: Crash Course;https://www.youtube.com/watch?v=UL1jmJaUkaQ;License: Standard YouTube License, CC-BY
Bonding (Ionic, Covalent & Metallic) - GCSE Chemistry; Author: Science Shorts;https://www.youtube.com/watch?v=p9MA6Od-zBA;License: Standard YouTube License, CC-BY
General Chemistry 1A. Lecture 12. Two Theories of Bonding.; Author: UCI Open;https://www.youtube.com/watch?v=dLTlL9Z1bh0;License: CC-BY