Interpretation:
The listed nucleophiles, in the order from the slowest
Concept introduction:
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Chapter 9 Solutions
ORGANIC CHEMISTRY E-BOOK W/SMARTWORK5
- From each pair, select the stronger nucleophile. Q.) CH3SH or CH3S-arrow_forwardRank the nucleophiles in following group in order of increasing nucleophilicity. −OH, Br−, F− (polar aprotic solvent)arrow_forwardWhat are the list of difference between SN1, SN2, E1, and E2? (such as the type of nucleophiles needed, the type of substrates, solvents etc.) When do we know when to use which mechanism? How do we use heat in an elimination reaction?arrow_forward
- From each pair, select the stronger nucleophile. Q.) CH3COO- or OH-arrow_forwardHow will the rate of each of the attach SN2 reactions change if it is carried out in a more polar solvent?arrow_forwardWould the first reaction go through SN2 since both the nucleophile and electrophile are consistent with SN2, even though the solvent is protic? And then the second reaction (with only CH3OH) would go throguh SN1?arrow_forward
- Reactions are impacted by various factors that depend on the mechanism of the reaction.Some of the variables for substitution reactions are: • strength of the nucleophile • concentration of the nucleophile • leaving group ability (i.e., is it a “bad” or a “good” leaving group?In an SN2 reaction, the nucleophile forces the leaving group to leave. (This is the rate-determining step of the reaction.)In an SN1 reaction, the nucleophile does not attack until the leaving group has left. (When the leaving group leaves, this is the rate-determining step of the reaction.) Based on the information provided in this question, which factors would favor an SN2 reaction? a strong nucleophile a good leaving group a high concentration of nucleophilearrow_forwardReactions are impacted by various factors that depend on the mechanism of the reaction.Some of the variables for substitution reactions are: • strength of the nucleophile • concentration of the nucleophile • leaving group ability (i.e., is it a “bad” or a “good” leaving group?In an SN2 reaction, the nucleophile forces the leaving group to leave. (This is the rate-determining step of the reaction.)In an SN1 reaction, the nucleophile does not attack until the leaving group has left. (When the leaving group leaves, this is the rate-determining step of the reaction.) Based on the information provided in this question, which factors would favor an SN2 reaction?Choose one or more: A.a strong nucleophile B.a good leaving group C.a high concentration of nucleophile Based on the information provided in this question, which factors would favor an SN1 reaction?Choose one or more: A.a strong nucleophile B.a good leaving group C.a high concentration…arrow_forwardRank the nucleophiles in following group in order of increasing nucleophilicity. H2O, −OH, CH3CO2-arrow_forward
- For each pair, predict the stronger nucleophile in the SN2 reaction (using an alcohol asthe solvent). Explain your prediction.(a) (CH3CH2)3N or (CH3CH2)2NHarrow_forwardProduct Y is the major product of the reaction sequence below. Which product Y: *arrow_forwardIdentify the stronger nucleophile in the following pair of anions. HO− or Cl− in a polar aprotic solventarrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage LearningEBK A SMALL SCALE APPROACH TO ORGANIC LChemistryISBN:9781305446021Author:LampmanPublisher:CENGAGE LEARNING - CONSIGNMENT