(a)
Interpretation:
For the given substrate, when
Concept introduction:
In an E2 reaction, the base pulls off the proton from the substrate, thus forcing the leaving group to leave. Elimination usually takes place so as to produce the most stable, meaning highly alkyl substituted,
(b)
Interpretation:
For the given substrate, when
Concept introduction:
In an E2 reaction, the base pulls off the proton from the substrate, thus forcing the leaving group to leave. Elimination usually takes place so as to produce the most stable, meaning highly alkyl substituted, alkene. The major elimination product is the one produced by deprotonating the carbon atom initially attached to the fewest hydrogen atoms. In a ring with limited rotation, the leaving group has to be trans to the proton.
(c)
Interpretation:
For the given substrate, when
Concept introduction:
In an E2 reaction, the base pulls off the proton from the substrate, thus forcing the leaving group to leave. Elimination usually takes place so as to produce the most stable, meaning highly alkyl substituted, alkene. The major elimination product is the one produced by deprotonating the carbon atom initially attached to the fewest hydrogen atoms. In a ring with limited rotation, the leaving group has to be trans to the proton.
(d)
Interpretation:
For the given substrate, when
Concept introduction:
In an E2 reaction, the base pulls off the proton from the substrate, thus forcing the leaving group to leave. Elimination usually takes place so as to produce the most stable, meaning highly alkyl substituted, alkene. The major elimination product is the one produced by deprotonating the carbon atom initially attached to the fewest hydrogen atoms. In a ring with limited rotation, the leaving group has to be trans to the proton.
(e)
Interpretation:
For the given substrate, when
Concept introduction:
In an E2 reaction, the base pulls off the proton from the substrate, thus forcing the leaving group to leave. Elimination usually takes place so as to produce the most stable, meaning highly alkyl substituted, alkene. The major elimination product is the one produced by deprotonating the carbon atom initially attached to the fewest hydrogen atoms. In a ring with limited rotation, the leaving group has to be trans to the proton.
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ORGANIC CHEMISTRY E-BOOK W/SMARTWORK5
- Draw a structure for the major product in each of the following reactions.arrow_forwardPlease state if the substrate undergoes a carbocation rearrangement in an SN1 mechanismarrow_forwardDraw the major elimination product that would be obtained from each of the following reactants with a strong base and with a weak base:arrow_forward
- Which one of the substrates can undergo NEITHER SN1 nor SN2 reactions?arrow_forwardDraw the major E2 elimination products from each of the following alkyl halides.arrow_forwardThe compound shown here is the product of a base-catalyzed aldol condensation. Draw the structure of the nonaromatic-containing starting material that is present before the aldol condensation and the aldol addition.arrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning