ORGANIC CHEMISTRY E-BOOK W/SMARTWORK5
2nd Edition
ISBN: 9780393664034
Author: KARTY
Publisher: NORTON
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Chapter D, Problem D.3YT
Interpretation Introduction
Interpretation:
Atomic orbital overlap and MO energy diagram for HO- and HCl is to be constructed. HOMO of HO- and LUMO of HCl is to be determined.
Concept introduction:
The type of hybridization and orbitals contributed by the atoms suggests the type of overlap that will occur between those atoms. This in turn tells about the type of bonding between those atoms. The number of MOs is equal to the number of AOs undergoing mixing.
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Draw an mo diagram for the valence electrons in F2. What is the bond order many sigma and pi bonds are there? What is the HOMO(Highest Occupied Molecular Orbital) and LUMO(Lowest Unoccupied Molecular Orbital)? What is the magnetism of the species?
The unfilled, partial MO diagram of N2− is shown below. Correctly fill electrons into the MO diagram. What isthe bond order of N2−
a) 0.5b) 1.0c) 1.5d) 2.0e) 2.5
a) Construct the molecular orbitals of NO-.
b) Between the molecular HNO and HON, on the basis of your estimation and your answer to part a, which structure is favored?
Chapter D Solutions
ORGANIC CHEMISTRY E-BOOK W/SMARTWORK5
Ch. D - Prob. D.1PCh. D - Prob. D.2PCh. D - Prob. D.3PCh. D - Prob. D.4PCh. D - Prob. D.5PCh. D - Prob. D.6PCh. D - Prob. D.7PCh. D - Prob. D.8PCh. D - Prob. D.9PCh. D - Prob. D.10P
Ch. D - Prob. D.11PCh. D - Prob. D.1YTCh. D - Prob. D.2YTCh. D - Prob. D.3YTCh. D - Prob. D.4YTCh. D - Prob. D.5YTCh. D - Prob. D.6YTCh. D - Prob. D.7YTCh. D - Prob. D.8YTCh. D - Prob. D.9YTCh. D - Prob. D.10YTCh. D - Prob. D.11YTCh. D - Prob. D.12YTCh. D - Prob. D.13YTCh. D - Prob. D.14YTCh. D - Prob. D.15YTCh. D - Prob. D.16YT
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