ORGANIC CHEMISTRY E-BOOK W/SMARTWORK5
2nd Edition
ISBN: 9780393664034
Author: KARTY
Publisher: NORTON
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter D, Problem D.2P
Interpretation Introduction
Interpretation:
The orbital interaction that illustrates the most significant hyperconjugation interaction in
Concept introduction:
The HOMO is the highest occupied molecular orbital. If the HOMO and LUMO orbitals can interact, then the interaction stabilizes the entire species. The species that contribute to the pertinent HOMO in the interaction is relatively electron-rich. It is the Lewis base or the nucleophile. The species that contribute the pertinent LUMO is relatively electron-poor. It is the Lewis acid or the electrophile.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
(a) Which of the AF3 molecules in Fig. 1 will have a nonzero dipole moment? Explain.
b) Which of the AF4 molecules in Fig. 2 will have a zero dipole moment? Explain.
How many Cs are sp2-hybridized in the molecule shown below? (kindly show explanation or illustration. thank you!)
Choices:
A. 6B. 8C. 10D. 9
In the reaction of CN- + H + → HCN;
1) Which boundary orbitals are used? Draw a diagram and explain according to MOT.
2) Explain the orbital overlaps of the product according to VBT.
3) Determine the point group of the product.
Chapter D Solutions
ORGANIC CHEMISTRY E-BOOK W/SMARTWORK5
Ch. D - Prob. D.1PCh. D - Prob. D.2PCh. D - Prob. D.3PCh. D - Prob. D.4PCh. D - Prob. D.5PCh. D - Prob. D.6PCh. D - Prob. D.7PCh. D - Prob. D.8PCh. D - Prob. D.9PCh. D - Prob. D.10P
Ch. D - Prob. D.11PCh. D - Prob. D.1YTCh. D - Prob. D.2YTCh. D - Prob. D.3YTCh. D - Prob. D.4YTCh. D - Prob. D.5YTCh. D - Prob. D.6YTCh. D - Prob. D.7YTCh. D - Prob. D.8YTCh. D - Prob. D.9YTCh. D - Prob. D.10YTCh. D - Prob. D.11YTCh. D - Prob. D.12YTCh. D - Prob. D.13YTCh. D - Prob. D.14YTCh. D - Prob. D.15YTCh. D - Prob. D.16YT
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- The stable molecular ion H3+ is triangular, with HH distances of 0.87 Å. Sketch the molecule and indicate the region of greatest electron density of the lowest energy MO.arrow_forwardhi, can you solve this ? How many unbonded electrons are found around the nitrogen atom in the electron-point structure representation of the NH2 (-) ion?arrow_forwardI NEED THE ANSWER FOR NUMBER 2. Find the following in the compound :A. Draw the overlapping of orbitalsB. Identify the hybrid orbitalC. Identify the molecular orbitalarrow_forward
- why do you have -k2 in the L.H.S and -(-w)2 in the R.H.S ?arrow_forward1. ionization of Cl2 (Cl2 —> Cl2+ + e-) leads to a shortening of the Cl-Cl distance (199 pm in Cl2, 189 pm in Cl2+), why? 2. why the C-O bond distance is nearly identical in CO (113 pm) and CO+ (112 pm)? 3. Derive the MO diagram of a linear C-H (i.e. one carbon atom bonded to one hydrogen atom). Draw out the MOs for orbitals containing electrons Would you expect C-H to behave as a carbocation, carbanion, or radical? Would removal of one electron from C-H to generate C-H+ increase or decrease the bond length between carbon and hydrogen?arrow_forwardConsider the incomplete orbital representation of O2 , below right. a. Identify which lobes are hybrid orbitals (identify the type) and which lobes arep orbitals. b. Use dotted lines to show any bonds. c. Use up or down arrows to show electron occupation of each hybrid orbital or bond.arrow_forward
- Consider any one of the four identical hybrid orbitals in the 109.5° set. a. What fraction of the clay in this hybrid orbital was originally red (carne from the 2s orbital)? b. What fraction of the clay in this hybrid orbital was originally green (carne from a 2porbital)? c. Explain the name “ s(1/4)p(3/4) hybrid orbital” for each of the four orbitals. d. In fact, each of the four hybrid orbitals in the 109.5° set is called an sp3 -hybrid orbital.Explain the name “ sp3 -hybrid orbital.”arrow_forwardYou hear a student from a nearby group say that “Electron domains repel one another.” Citeevidence from Figure 1.2 to support or refute this statement.arrow_forwardA student draws the picture of ammonia (NH3) in the box below, left, and predicts it will be a flatmolecule with HNH bond angles of exactly 120°. Unfortunately, the student left something out. a. What did the student omit from his drawing? b. What is the actual HNH bond angle of ammonia (based on the draw g above, right)? c. Explain why water, ammonia, and methane (shown below) all have about the same bondangles (close to 109.5°) even though they have different numbers of bonds.arrow_forward
arrow_back_ios
arrow_forward_ios
Recommended textbooks for you
- Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage LearningOrganic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning