Concept explainers
(a)
Interpretation:
The structure from the given IUPAC name is to be drawn.
Concept introduction:
The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.
Suffix ‘oate’ represents ester as the highest priority group and the prefix in the IUPAC name is the group attached to O atom.
(b)
Interpretation:
The structure from the given IUPAC name is to be drawn.
Concept introduction:
The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.
(c)
Interpretation:
The structure from the given IUPAC name is to be drawn.
Concept introduction:
The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.
(d)
Interpretation:
The structure from the given IUPAC name is to be drawn.
Concept introduction:
The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.
(e)
Interpretation:
The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.
Concept introduction:
The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.
The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of the
Want to see the full answer?
Check out a sample textbook solutionChapter F Solutions
Organic Chemistry: Principles and Mechanisms (Second Edition)
- Draw all possible resonance structures for the antihistamine diphenhydramine, the activeingredient in Benadryl.arrow_forwardWhat product is formed when A is treated with Grubbs catalyst underhigh-dilution conditions? This reaction was a key step in the synthesis ofstemoamide, the naturally occurring amide described in the opening paragraph.arrow_forwardDraw a stepwise mechanism for the following Robinson annulation. This reaction was a key step in a synthesis of the steroid cortisone by R. B. Woodward and co-workers at Harvard University in 1951.arrow_forward
- Devise a synthesis of attached acetal from 1-bromo-2-methylhexane,alcohols (and diols) containing one or two carbons, and any neededinorganic reagents.arrow_forward(−)-Hyoscyamine, an optically active drug used to treat gastrointestinal disorders, is isolated from Atropa belladonna, the deadly nightshade plant, by a basic aqueous extraction procedure. If too much base is used during isolation, optically inactive material is isolated. (a) Explain this result by drawing a stepwise mechanism. (b) Explain why littorine, an isomer isolated from the tailflower plant in Australia, can be obtained optically pure regardless of the amount of base used during isolation.arrow_forwardA key step in the synthesis of the narcotic analgesic meperidine (tradename Demerol) is the conversion of phenylacetonitrile to X. (a) What isthe structure of X? (b) What reactions convert X to meperidine ?arrow_forward
- Devise a synthesis of each compound from aniline (C6H5NH2) as starting material.arrow_forwardDevise a synthesis of each biologically active compound from benzene.arrow_forwardIdentify F in the following reaction sequence. F was converted in several steps to the antidepressant paroxetine (trade name Paxil; see also Problem 9.9).arrow_forward
- draw an efficient synthesis strategy and show all structuresarrow_forwardRank the labeled H atoms in the following compound in order of increasing acidity. (See the attachment)arrow_forwardBromide Bhas normal activity (for a secondary bromide) towards SN1 substitution, but A has much higher reactivity and Chas much lower reactivity.arrow_forward
- Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage LearningOrganic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning