CHзон насно"CHзH2NCHзНаС.CH 3+CHнсCHзннCHз-CH3Hас2,4-Bis(a.,a-dimethylbe nzyl)phenolLigand 6formaldehydeN,N-dimethylethylenediamine4.0096 g0.9 mL0.66 mL 1H - Ligand 6121110987542ppm71.75-9.4427.2597.240-7.2387.2287.173CO- 7.1637.1527.14012.23\68 L7.1342.167.1277.1190007.0787.0687.0577.046CO- 7.0356.691LO963.3622.2902.2762.042.2612.012.10811.812.0936.1911.76/2.0791.6591.6371.616

Question
Asked Oct 23, 2019
1 views

Using the reaction below and using Ligand 6 to determine the HNMR shown below.

Ligand 6 is a symmetrical Ligand.

Label all the H protons.

CHз
он нас
но
"CHз
H2N
CHз
НаС
.CH 3
+
CH
нс
CHз
н
н
CHз
-CH3
Hас
2,4-Bis(a.,a-dimethylbe nzyl)
phenol
Ligand 6
formaldehyde
N,N-dimethylethylenediamine
4.0096 g
0.9 mL
0.66 mL
help_outline

Image Transcriptionclose

CHз он нас но "CHз H2N CHз НаС .CH 3 + CH нс CHз н н CHз -CH3 Hас 2,4-Bis(a.,a-dimethylbe nzyl) phenol Ligand 6 formaldehyde N,N-dimethylethylenediamine 4.0096 g 0.9 mL 0.66 mL

fullscreen
1H - Ligand 6
12
11
10
9
8
7
5
4
2
ppm
7
1.75
-9.442
7.259
7.240
-7.238
7.228
7.173
CO
- 7.163
7.152
7.140
12.23
\68 L
7.134
2.16
7.127
7.119
000
7.078
7.068
7.057
7.046
CO
- 7.035
6.691
LO
96
3.362
2.290
2.276
2.04
2.261
2.01
2.108
11.81
2.093
6.19
11.76/
2.079
1.659
1.637
1.616
help_outline

Image Transcriptionclose

1H - Ligand 6 12 11 10 9 8 7 5 4 2 ppm 7 1.75 -9.442 7.259 7.240 -7.238 7.228 7.173 CO - 7.163 7.152 7.140 12.23 \68 L 7.134 2.16 7.127 7.119 000 7.078 7.068 7.057 7.046 CO - 7.035 6.691 LO 96 3.362 2.290 2.276 2.04 2.261 2.01 2.108 11.81 2.093 6.19 11.76/ 2.079 1.659 1.637 1.616

fullscreen
check_circle

Expert Answer

Step 1

The labelling of all the pro...

help_outline

Image Transcriptionclose

ChemNMR H Estimation 7.29 7.29 7.22 7.18 7.18 7.22 7.37 7.37 ОН ОН 1.69 169 7.29 7.29 3.66 3.66 7.18 7.18 1.69 169 2.37 6. 37 6.91 6.91 6.94 1,69 1.69 1.69 1.69 N. 2.21 2.21 7,18 7.18 7.18 7.18 7.29 7.29 7.29 7.29 7.22 7.22

fullscreen

Want to see the full answer?

See Solution

Check out a sample Q&A here.

Want to see this answer and more?

Solutions are written by subject experts who are available 24/7. Questions are typically answered within 1 hour.*

See Solution
*Response times may vary by subject and question.
Tagged in

Science

Chemistry

Organic Chemistry

Related Chemistry Q&A

Find answers to questions asked by student like you
Show more Q&A
add
question_answer

Q: Write balanced complete ionic equation for CaS(aq)+CuCl2(aq)→CuS(s)+CaCl2(aq). Express your answer ...

A: Balancing reaction:Balanced reaction is a chemical reaction in which number of atoms for each elemen...

question_answer

Q: What is the total mass of products expected from the combustion of 20.3 g of ethane?

A: Given:Mass of ethane = 20.3 gBalanced chemical reaction of combustion of ethane is given by,

question_answer

Q: catalytic hydrogenation ( or deuteration) adds H2 (or D2) by a syn electrophilic addition. Which ans...

A: The product of syn-addition of D2 to (E)-2-pentene and (Z)-2-pentene is to be determined.

question_answer

Q: whats the difference between a compound and a molecule?

A: Click to see the answer

question_answer

Q: The effusion rate of an unknown gas is found to be 32.5mL/min. Under the identical conditions the ef...

A: First, using Graham’s Law the molar mass of given gas is determined.

question_answer

Q: What is the pH of a buffer that is 0.110 M HPO422 and 0.220 M H2PO4^ 2- at 25°C?

A: Given,The concentration of HPO42- = 0.110 MThe concentration of H2PO4- = 0.220 M

question_answer

Q: Calculate the standard enthalpy change for the reaction at 25 ∘C.    C3H8(g)+5O2(g)⟶3CO2(g)+4H2O(g)

A: Enthalpy change of reaction: The enthalpy change of a reaction is roughly equivalent to the amount o...

question_answer

Q: How many water molecules are in 36 grams of water

A: Given,Mass of water = 36 gMoles of water can be calculated as:

question_answer

Q: F− Express your answer in complete form, in order of increasing orbital. For example, 1s22s2 would ...

A: The atomic number of Fluorine atom is 9.  So, it has nine electrons.  The electronic configuration o...