Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 1, Problem 1.36AP
Interpretation Introduction
Interpretation:
The reason corresponding to the fact that
Concept introduction:
The dipole moment is defined as the charge separation between two atoms in a covalent bond or between two ions in an ionic bond. It is used to determine the polarity of atoms or ions. If the value of dipole moment is zero, then the molecule is said to be non-polar, and if the value of dipole moment is not zero, then the molecule is said to be polar and possess permanent dipole moment.
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The bond between carbon and hydrogen is one of the most important typesof bonds in chemistry. The length of an H¬C bond is approximately 1.1 Å.Based on this distance and differences in electronegativity, do you expect thedipole moment of an individual H¬C bond to be larger or smaller than that ofan H¬I bond?
If the dipole moment of CH3F is 1.847 D and the dipole moment of CD3F is 1.858 D, which is more electronegative: hydrogen or deuterium?
Phosgene, Cl2C=O, has a smaller dipole moment than formaldehyde, H2C=O, even though it contains electronegative chlorine atoms in place of hydrogen. Explain.
Chapter 1 Solutions
Organic Chemistry
Ch. 1 - Prob. 1.1PCh. 1 - Prob. 1.2PCh. 1 - Prob. 1.3PCh. 1 - Prob. 1.4PCh. 1 - Prob. 1.5PCh. 1 - Prob. 1.6PCh. 1 - Prob. 1.7PCh. 1 - Prob. 1.8PCh. 1 - Prob. 1.9PCh. 1 - Prob. 1.10P
Ch. 1 - Prob. 1.11PCh. 1 - Prob. 1.12PCh. 1 - Prob. 1.13PCh. 1 - Prob. 1.14PCh. 1 - Prob. 1.15PCh. 1 - Prob. 1.16PCh. 1 - Prob. 1.17PCh. 1 - Prob. 1.18PCh. 1 - Prob. 1.19PCh. 1 - Prob. 1.20PCh. 1 - Prob. 1.21APCh. 1 - Prob. 1.22APCh. 1 - Prob. 1.23APCh. 1 - Prob. 1.24APCh. 1 - Prob. 1.25APCh. 1 - Prob. 1.26APCh. 1 - Prob. 1.27APCh. 1 - Prob. 1.28APCh. 1 - Prob. 1.29APCh. 1 - Prob. 1.30APCh. 1 - Prob. 1.31APCh. 1 - Prob. 1.32APCh. 1 - Prob. 1.33APCh. 1 - Prob. 1.34APCh. 1 - Prob. 1.35APCh. 1 - Prob. 1.36APCh. 1 - Prob. 1.37APCh. 1 - Prob. 1.38APCh. 1 - Prob. 1.39APCh. 1 - Prob. 1.40APCh. 1 - Prob. 1.41APCh. 1 - Prob. 1.42APCh. 1 - Prob. 1.43APCh. 1 - Prob. 1.44APCh. 1 - Prob. 1.45APCh. 1 - Prob. 1.46APCh. 1 - Prob. 1.47APCh. 1 - Prob. 1.48APCh. 1 - Prob. 1.49AP
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- A neutral molecule is identified as a tetrafluoride, XF4, where X is an unknown atom. If the molocule has a dipole moment of 0.63 D, can you give some possibilities for the identity of X?arrow_forwardExplain why CF4 and Xef4 are nonpolar compounds (have no net dipole moments) while SF4 is polar (has a net dipo le moment). Is CO2 polar? What about COS?arrow_forwardClarify why phosphorus trifluoride (PF3) has dipole mome of 1.03 D, whereas boron trifluoride (BF3) has no dipole moment, p = 0 D (atomic number of B, F, and P are 5,9, and 15, respectively).arrow_forward
- Describe the bonding in the nitrate ion, NO3-. Does this ion have delocalized p bonds?arrow_forwardThere are three possible structures for PCl2F3 with phosphorus as the central atom. Draw them and discuss how measurements of dipole moments could help distinguish among them.arrow_forwardA hypothetical covalent molecule, X–Y, has a dipole moment of 1.12D and a bond length of 101 pm. Calculate the partial charge on a pole of this molecule in terms of e, where e is the charge on an electron.arrow_forward
- Does H2O2 have a dipole moment?arrow_forwardIndicate which structures have dipole moments and show their direction for SF4?arrow_forwardIf the dipole moment of a diatomic molecule is found to be 1.04 D, and its bond length is found to be 124 pm, what is the fractional charge on the atoms of the molecule in Coulombs (C)?arrow_forward
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