Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Textbook Question
Chapter 1, Problem 1.59E
Use Figure 1.11 to construct the cyclic rule equivalent of
Does the answer make sense in light of the original partial derivative?
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For the function:
R, a, b - are constant- Write an expression for the derivative of p in relation to v when the other quantities are constant- Write an expression for the derivative of p in relation to T when all other quantities are constant.
Using this limited information, is it possible to solve for delta H and delta S? Or would you need to concretely define one of the variables?
Chapter 1 Solutions
Physical Chemistry
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- What is the value of q at absolute zero? Is it the same for all systems?arrow_forwardUse the ideal gas law to symbolically prove the cyclic rule of partial derivatives.arrow_forwardEvaluate (U/V)T for a van der Waals gas. Use the third expression from Example 4.11 and compare your answer to the answer from the previous exercise.arrow_forward
- Evaluate (U/V)T for an ideal gas. Use the expression from Example 4.11. Does your answer make sense?arrow_forwardRepeat the previous exercise for a gas that follows the Berthelot equation of state see exercise 1.55.arrow_forwardComputers are not supposed to be in very warm rooms. The highest temperature tolerated for maximum performance is 308 K. Express this temperature in C and F.arrow_forward
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